Why electrochemistry lies at the heart of modern technology
This episode of the Physics World Weekly podcast features a conversation with Colm O’Dwyer, who is professor of chemical energy at University College Cork in Ireland and president of the Electrochemical Society.
He talks about the role that electrochemistry plays in the development of modern technologies including batteries, semiconductor chips and pharmaceuticals. O’Dwyer chats about the role that the Electrochemical Society plays in advancing the theory and practice of electrochemistry and solid-state science and technology. He also explains how electrochemists collaborate with scientists and engineers in other fields including physics – and he looks forward to the future of electrochemistry.
This podcast is supported by American Elements. Trusted by researchers and industries the world over, American Elements is helping shape the future of battery and electrochemistry technology.
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1 00:00:07,679 --> 00:00:10,639 Hello, and welcome to this episode of the 2 00:00:10,639 --> 00:00:12,500 Physics World weekly podcast, 3 00:00:12,880 --> 00:00:15,619 which is supported by American Elements. 4 00:00:16,375 --> 00:00:17,835 I'm Hamish Johnston. 5 00:00:18,535 --> 00:00:20,475 In this episode, I'm in conversation 6 00:00:20,935 --> 00:00:22,234 with Colm O'Dwyer, 7 00:00:22,695 --> 00:00:26,475 who is professor of chemical energy at University 8 00:00:26,775 --> 00:00:28,795 College Cork in Ireland 9 00:00:29,390 --> 00:00:31,250 and president of the Electrochemical 10 00:00:31,869 --> 00:00:32,369 Society. 11 00:00:33,149 --> 00:00:35,969 O'Dwyer talks about the role that electrochemistry 12 00:00:36,509 --> 00:00:39,729 plays in the development of modern technologies, 13 00:00:40,350 --> 00:00:41,489 including batteries, 14 00:00:42,225 --> 00:00:44,405 semiconductor chips, and pharmaceuticals. 15 00:00:45,424 --> 00:00:47,984 We also chat about the role that the 16 00:00:47,984 --> 00:00:48,484 Electrochemical 17 00:00:49,104 --> 00:00:53,045 Society plays in advancing the theory and practice 18 00:00:53,265 --> 00:00:54,085 of electrochemistry 19 00:00:54,864 --> 00:00:56,564 and solid state sciences. 20 00:00:57,570 --> 00:00:59,909 We also speak about how electrochemists 21 00:01:00,850 --> 00:01:01,350 collaborate 22 00:01:01,649 --> 00:01:02,549 with scientists 23 00:01:03,010 --> 00:01:03,750 and engineers 24 00:01:04,290 --> 00:01:05,510 in other fields, 25 00:01:05,890 --> 00:01:07,109 including physics. 26 00:01:15,754 --> 00:01:18,814 This episode is supported by American Elements, 27 00:01:19,275 --> 00:01:23,215 the world's leading manufacturer of engineered and advanced 28 00:01:23,435 --> 00:01:23,935 materials. 29 00:01:24,715 --> 00:01:28,015 American Elements is a long standing leader in 30 00:01:28,270 --> 00:01:30,450 electrochemistry and battery technology, 31 00:01:31,390 --> 00:01:32,770 serving in 2001 32 00:01:33,390 --> 00:01:34,209 as materials 33 00:01:34,510 --> 00:01:35,569 lead partner 34 00:01:35,870 --> 00:01:38,609 in the United States Department of Energy's 35 00:01:39,069 --> 00:01:41,170 Solid State Energy Conversion 36 00:01:41,469 --> 00:01:41,969 Alliance, 37 00:01:42,805 --> 00:01:45,144 commonly known as the CICA program, 38 00:01:45,685 --> 00:01:47,545 for the development of efficient 39 00:01:48,165 --> 00:01:50,185 solid oxide fuel cells. 40 00:01:50,644 --> 00:01:53,625 The company was solely responsible for developing, 41 00:01:54,244 --> 00:01:54,744 manufacturing, 42 00:01:55,364 --> 00:01:55,864 testing, 43 00:01:56,320 --> 00:01:57,140 and certifying 44 00:01:57,680 --> 00:02:00,579 novel anodes, cathodes, and electrolytes 45 00:02:01,120 --> 00:02:03,859 for fellow industry partners, Honeywell, 46 00:02:04,400 --> 00:02:05,939 GE, and Siemens. 47 00:02:06,640 --> 00:02:09,775 The company has developed and commercially launched 48 00:02:10,155 --> 00:02:12,414 many new battery cathode, 49 00:02:12,875 --> 00:02:14,814 anode, and electrolyte compositions 50 00:02:15,435 --> 00:02:16,974 in common use today, 51 00:02:17,514 --> 00:02:18,014 including 52 00:02:18,395 --> 00:02:21,455 the low cost nickel cermet anode. 53 00:02:22,340 --> 00:02:25,400 It was the world's 1st company globally 54 00:02:25,699 --> 00:02:27,879 to commercially offer perovskite 55 00:02:28,259 --> 00:02:28,759 cathodes, 56 00:02:29,300 --> 00:02:30,280 such as lanthanum, 57 00:02:30,740 --> 00:02:31,240 strontium, 58 00:02:31,860 --> 00:02:32,360 manganite 59 00:02:32,900 --> 00:02:33,719 in standardized 60 00:02:34,180 --> 00:02:36,680 rheology inks for screen printing. 61 00:02:37,405 --> 00:02:39,665 Trusted by researchers and industries 62 00:02:40,125 --> 00:02:41,344 the world over, 63 00:02:41,805 --> 00:02:44,625 American Elements is helping shape the future 64 00:02:44,925 --> 00:02:46,784 of battery and electrochemistry 65 00:02:47,405 --> 00:02:47,905 technology. 66 00:02:55,819 --> 00:02:58,000 Hi, Colm. Welcome to the podcast. 67 00:02:58,939 --> 00:03:01,739 Hi, Hamish. Glad to be here. So, Colm, 68 00:03:01,739 --> 00:03:03,680 you're the president of the Electrochemical 69 00:03:04,379 --> 00:03:06,715 Society. Can you tell us a bit about 70 00:03:06,715 --> 00:03:07,455 the organization? 71 00:03:08,555 --> 00:03:10,955 Who who are its members? What are its 72 00:03:10,955 --> 00:03:13,055 goals? What's it up to at the moment? 73 00:03:13,915 --> 00:03:15,534 Oh, sure. The Electrochemical 74 00:03:15,915 --> 00:03:16,415 Society 75 00:03:16,715 --> 00:03:19,034 or ECS as as most people know it 76 00:03:19,034 --> 00:03:19,534 as, 77 00:03:20,330 --> 00:03:22,909 is a society of members and a professional 78 00:03:23,050 --> 00:03:25,790 organization. It was founded way back in 1902. 79 00:03:26,650 --> 00:03:27,710 So it's a 122 80 00:03:28,330 --> 00:03:30,810 years old and counting, and it has a 81 00:03:30,810 --> 00:03:33,905 primary mission. It has changed a little over 82 00:03:33,905 --> 00:03:36,465 the years, but it's dedicated to advancing the 83 00:03:36,465 --> 00:03:38,324 theory and practice of electrochemistry 84 00:03:39,425 --> 00:03:42,305 and the solid state sciences and technologies. So 85 00:03:42,305 --> 00:03:45,025 that's the mantra for the society's mission and 86 00:03:45,025 --> 00:03:48,319 its overarching goal. It's headquartered in Pennington, New 87 00:03:48,319 --> 00:03:49,539 Jersey in the US. 88 00:03:50,239 --> 00:03:52,400 But we have a global community of over 89 00:03:52,400 --> 00:03:55,439 8,000 members and tens of thousands of people 90 00:03:55,439 --> 00:03:57,860 who interact with the society at meetings, 91 00:03:58,479 --> 00:03:59,459 journal publications, 92 00:04:00,414 --> 00:04:01,634 and lots more besides. 93 00:04:02,254 --> 00:04:05,294 And the topical interest areas, that's what we 94 00:04:05,294 --> 00:04:07,215 refer to them as. So there's 13 of 95 00:04:07,215 --> 00:04:07,715 those. 96 00:04:08,175 --> 00:04:09,074 And they define 97 00:04:09,694 --> 00:04:10,514 the academic 98 00:04:10,814 --> 00:04:13,634 and industry interface, the topics that the people 99 00:04:14,060 --> 00:04:17,360 would come to meetings to hear talks about, 100 00:04:17,819 --> 00:04:20,560 the topics that would be in the journals, 101 00:04:20,580 --> 00:04:23,500 then and many of our online articles. And 102 00:04:23,500 --> 00:04:24,720 these range from 103 00:04:25,660 --> 00:04:28,324 batteries and fuel cells and electrochemical 104 00:04:28,785 --> 00:04:31,044 energy storage and conversion technologies 105 00:04:31,824 --> 00:04:34,004 through sensors, material sciences, 106 00:04:34,785 --> 00:04:35,285 energy, 107 00:04:35,664 --> 00:04:36,164 electronics, 108 00:04:36,785 --> 00:04:37,764 solid state 109 00:04:38,224 --> 00:04:40,164 chip making and solid state materials 110 00:04:40,544 --> 00:04:41,845 and and the environment. 111 00:04:43,139 --> 00:04:45,060 And it it the the society really is 112 00:04:45,060 --> 00:04:46,040 a hub for 113 00:04:46,500 --> 00:04:47,639 knowledge dissemination, 114 00:04:48,100 --> 00:04:49,879 and that's how I really see it. 115 00:04:50,340 --> 00:04:51,879 Both peer reviewed publications, 116 00:04:52,500 --> 00:04:53,879 like the journal of the Electrochemical 117 00:04:54,180 --> 00:04:56,980 Society is over a century old. It's very, 118 00:04:56,980 --> 00:04:58,759 very well known among the community. 119 00:04:59,435 --> 00:05:00,334 But the core 120 00:05:00,714 --> 00:05:03,375 interaction with all of our members and with, 121 00:05:03,435 --> 00:05:05,855 you know, the public is is our biannual 122 00:05:05,995 --> 00:05:06,495 meetings. 123 00:05:07,435 --> 00:05:10,795 So ECS would hold a spring meeting and 124 00:05:10,795 --> 00:05:12,814 a fall or autumn meeting, 125 00:05:13,829 --> 00:05:16,149 every single year, pretty much every year since 126 00:05:16,149 --> 00:05:16,889 its inception. 127 00:05:17,750 --> 00:05:20,069 And these are very, very well attended, and 128 00:05:20,069 --> 00:05:23,430 that's our core way of bringing everyone in 129 00:05:23,430 --> 00:05:24,649 the community together. 130 00:05:25,534 --> 00:05:26,914 People working on semiconductors, 131 00:05:27,375 --> 00:05:30,334 people working on batteries, and everything in between 132 00:05:30,334 --> 00:05:32,414 all come together in the same place. And 133 00:05:32,414 --> 00:05:33,474 we have an organizational 134 00:05:33,774 --> 00:05:34,274 structure 135 00:05:35,134 --> 00:05:38,094 with an executive committee and many members, and 136 00:05:38,094 --> 00:05:41,776 it's all based on volunteer interaction. So it's 137 00:05:41,776 --> 00:05:45,209 a a nonprofit society, and everyone like me, 138 00:05:45,350 --> 00:05:45,850 colleagues, 139 00:05:46,350 --> 00:05:46,850 and 140 00:05:47,350 --> 00:05:47,850 organizers, 141 00:05:48,389 --> 00:05:48,889 symposia, 142 00:05:49,350 --> 00:05:52,064 and at all levels in society are all 143 00:05:52,464 --> 00:05:55,125 volunteers from from universities and from industry. 144 00:05:55,745 --> 00:05:57,824 I see. And, Carm, I want to ask 145 00:05:57,824 --> 00:05:58,725 you specifically 146 00:05:59,185 --> 00:05:59,685 about, 147 00:06:00,225 --> 00:06:02,805 some of the applications of, electrochemistry 148 00:06:03,264 --> 00:06:04,245 that you've mentioned. 149 00:06:05,024 --> 00:06:06,485 It plays, electrochemistry 150 00:06:06,944 --> 00:06:10,110 that is, plays crucial roles in modern technology, 151 00:06:10,329 --> 00:06:12,269 particularly in the semiconductor 152 00:06:12,729 --> 00:06:14,189 and energy storage 153 00:06:14,569 --> 00:06:15,069 industries. 154 00:06:16,009 --> 00:06:18,349 Can you talk a bit about how electrochemistry 155 00:06:19,209 --> 00:06:20,110 is driving 156 00:06:20,490 --> 00:06:20,990 innovation 157 00:06:21,584 --> 00:06:23,745 in those key sectors. And and maybe, you 158 00:06:23,745 --> 00:06:25,845 know, could you start with semiconductors? 159 00:06:26,305 --> 00:06:26,805 Because 160 00:06:27,185 --> 00:06:29,204 I, you know, I suppose as a physicist, 161 00:06:29,264 --> 00:06:30,564 I wasn't really aware 162 00:06:31,105 --> 00:06:31,504 of, 163 00:06:32,225 --> 00:06:33,605 how much electrochemistry 164 00:06:34,225 --> 00:06:37,500 is used in the semiconductor industries. So could 165 00:06:37,500 --> 00:06:38,800 you talk a bit about that? 166 00:06:39,819 --> 00:06:40,319 Sure. 167 00:06:40,699 --> 00:06:41,199 Electrochemistry 168 00:06:41,660 --> 00:06:43,680 as it as a really broad discipline 169 00:06:44,060 --> 00:06:44,560 is 170 00:06:45,100 --> 00:06:46,639 somewhat hidden behind 171 00:06:47,019 --> 00:06:49,625 some of the processes that happen in all 172 00:06:49,625 --> 00:06:52,204 of semiconductor manufacturing and in modification 173 00:06:53,305 --> 00:06:56,824 and even synthesis of some semiconductor materials. But 174 00:06:56,824 --> 00:06:57,485 it's there. 175 00:06:58,985 --> 00:06:59,884 In classical 176 00:07:00,264 --> 00:07:01,164 chip making, 177 00:07:01,704 --> 00:07:03,990 electro deposition is a key process step. 178 00:07:05,189 --> 00:07:07,669 And that's a that's a core technology and 179 00:07:07,669 --> 00:07:09,849 process in in chip making and then semiconductor 180 00:07:09,990 --> 00:07:12,970 processing and manufacturing. And that's essentially a purely 181 00:07:13,349 --> 00:07:15,449 a classical electrochemical technique 182 00:07:15,990 --> 00:07:17,449 where you have your semiconductor 183 00:07:17,829 --> 00:07:19,944 or your substrate or whatever you want to 184 00:07:19,944 --> 00:07:23,064 deposit on, whether it's patterned, whether it's not 185 00:07:23,064 --> 00:07:23,884 in a solution 186 00:07:24,264 --> 00:07:27,064 containing the the material that you'd eventually want 187 00:07:27,064 --> 00:07:29,545 to deposit. And it's a classical Faraday type 188 00:07:29,545 --> 00:07:31,705 process, and you can control how much of 189 00:07:31,705 --> 00:07:33,964 the material is deposited on the surface 190 00:07:34,639 --> 00:07:36,560 depending on the current you apply and how 191 00:07:36,560 --> 00:07:37,939 long you apply it for. 192 00:07:38,399 --> 00:07:41,060 And that is used in so many different 193 00:07:41,120 --> 00:07:42,259 processes in 194 00:07:42,560 --> 00:07:44,339 electrochemical methods and 195 00:07:44,800 --> 00:07:47,139 techniques, but it's a core process in semiconductor 196 00:07:47,519 --> 00:07:48,099 and manufacturing. 197 00:07:48,479 --> 00:07:49,459 So was etching. 198 00:07:50,104 --> 00:07:52,584 And so you can do etching and pattern 199 00:07:52,584 --> 00:07:55,485 relief and formation within semiconductor processing 200 00:07:55,944 --> 00:07:57,165 in lots of different 201 00:07:57,704 --> 00:07:58,204 semiconductor 202 00:07:58,664 --> 00:07:59,564 based technologies. 203 00:08:00,185 --> 00:08:02,044 But one of the core etching techniques 204 00:08:02,584 --> 00:08:05,164 is either chemical etching in solution, 205 00:08:06,180 --> 00:08:08,740 or you can have electrochemical etching where you'd 206 00:08:08,740 --> 00:08:09,639 like to control 207 00:08:12,019 --> 00:08:13,800 the quality and the smoothness 208 00:08:14,180 --> 00:08:16,019 of the etched features on a on a 209 00:08:16,019 --> 00:08:16,519 very 210 00:08:16,819 --> 00:08:17,319 complex 211 00:08:18,444 --> 00:08:21,084 semiconductor process. And that can also be done, 212 00:08:21,404 --> 00:08:21,904 electrochemically 213 00:08:22,285 --> 00:08:23,024 in solutions. 214 00:08:24,365 --> 00:08:25,964 You can't in in in the in the 215 00:08:25,964 --> 00:08:27,504 realm of compound semiconductors, 216 00:08:27,964 --> 00:08:28,705 then electrochemistry 217 00:08:29,564 --> 00:08:30,064 is 218 00:08:30,490 --> 00:08:33,850 is very interesting and and objectively important here 219 00:08:33,850 --> 00:08:34,350 too. 220 00:08:35,289 --> 00:08:37,389 For example, in solar photovoltaics, 221 00:08:37,929 --> 00:08:39,789 a really good example where you have 222 00:08:40,570 --> 00:08:44,889 binary compounds, ternary compounds, compounds containing 2, 3, 223 00:08:44,889 --> 00:08:46,274 4, or more elements. 224 00:08:47,795 --> 00:08:50,215 When they form their final crystal structure, they're 225 00:08:50,514 --> 00:08:51,335 really active 226 00:08:52,195 --> 00:08:53,495 photovoltaic materials, 227 00:08:53,875 --> 00:08:56,134 and these can be grown using electrodeposition. 228 00:08:57,555 --> 00:09:00,934 And electrochemical growth has this really nice advantage 229 00:09:01,480 --> 00:09:04,200 that the fundamental idea is that the growth 230 00:09:04,200 --> 00:09:07,820 will happen at the interface between one material 231 00:09:07,879 --> 00:09:10,440 and another or between the material and the 232 00:09:10,440 --> 00:09:12,379 substrate that you want to grow it on. 233 00:09:12,600 --> 00:09:14,679 And there has to be an electrical connection 234 00:09:14,679 --> 00:09:17,565 there. So there's charge transfer from 235 00:09:18,424 --> 00:09:19,565 wire up the substrate 236 00:09:19,945 --> 00:09:22,365 and connect it to whatever's happening in solution, 237 00:09:22,424 --> 00:09:24,365 and the material will only grow 238 00:09:24,904 --> 00:09:27,304 where the charge transfer is happening. So you 239 00:09:27,304 --> 00:09:29,884 ensure that you can often have very clean 240 00:09:30,024 --> 00:09:30,524 interfaces 241 00:09:31,350 --> 00:09:33,990 between one material and another that you can 242 00:09:33,990 --> 00:09:34,889 grow iteratively 243 00:09:35,589 --> 00:09:38,950 using electro deposition and electrochemical growth. So it's 244 00:09:38,950 --> 00:09:41,509 very useful for for those materials in solar 245 00:09:41,509 --> 00:09:43,929 affordable takes. And I guess the other, 246 00:09:44,710 --> 00:09:47,394 aspect or the fundamental aspect in 247 00:09:47,855 --> 00:09:50,115 semiconductor processing is metallization. 248 00:09:51,534 --> 00:09:52,674 Now these are for, 249 00:09:53,695 --> 00:09:54,195 conductivity, 250 00:09:54,654 --> 00:09:58,174 wiring within chips, interconnects, they're often referred to. 251 00:09:58,174 --> 00:09:59,794 These are typically done using 252 00:10:01,289 --> 00:10:01,789 vapor 253 00:10:02,409 --> 00:10:04,570 phase methods. But there are ways of doing 254 00:10:04,570 --> 00:10:06,269 it depending on the sizes 255 00:10:06,570 --> 00:10:08,990 of the features or what type of device, 256 00:10:09,289 --> 00:10:11,370 what type of chip you're making, where you 257 00:10:11,370 --> 00:10:13,450 would like to be able to metallize using 258 00:10:13,450 --> 00:10:16,034 electrochemical methods. And so that's often used, 259 00:10:16,514 --> 00:10:17,014 also. 260 00:10:18,034 --> 00:10:20,194 I see. And I suppose in in the 261 00:10:20,194 --> 00:10:22,595 big one for, I suppose, someone like me 262 00:10:22,595 --> 00:10:23,095 who's 263 00:10:23,634 --> 00:10:25,894 naive about, about electrochemistry 264 00:10:26,834 --> 00:10:27,334 is 265 00:10:27,714 --> 00:10:30,115 batteries. And I mean, I'm guessing that a 266 00:10:30,115 --> 00:10:31,014 battery is 267 00:10:31,559 --> 00:10:32,059 is 268 00:10:32,679 --> 00:10:33,500 an electrochemical 269 00:10:33,960 --> 00:10:36,460 device, and lots of electrochemists 270 00:10:36,840 --> 00:10:39,480 around the world are are working very hard 271 00:10:39,480 --> 00:10:40,940 on coming up with 272 00:10:41,399 --> 00:10:45,179 ways of improving batteries and developing new batteries. 273 00:10:45,240 --> 00:10:47,100 So can you talk a bit about 274 00:10:47,445 --> 00:10:49,205 battery research? I know I know it's a 275 00:10:49,205 --> 00:10:51,605 huge field, but maybe if you could pick 276 00:10:51,605 --> 00:10:54,024 out a few highlights at the moment, 277 00:10:54,884 --> 00:10:56,904 that are of interest to electrochemists. 278 00:10:58,565 --> 00:10:59,304 Right. So 279 00:11:00,470 --> 00:11:02,549 at at the moment, it's probably one of 280 00:11:02,549 --> 00:11:03,049 the 281 00:11:03,429 --> 00:11:07,110 core examples of where electrochemistry has really, really 282 00:11:07,110 --> 00:11:11,029 become more familiar to not just scientists outside 283 00:11:11,029 --> 00:11:12,914 of electrochemistry, but to the public too. 284 00:11:14,034 --> 00:11:15,875 And from the inception, I think it would 285 00:11:15,875 --> 00:11:17,334 be the lithium ion battery 286 00:11:17,794 --> 00:11:19,815 that would be the most familiar to 287 00:11:20,674 --> 00:11:21,975 most. Electrochemistry 288 00:11:22,434 --> 00:11:23,334 is the core 289 00:11:24,754 --> 00:11:26,914 process that happens in these. So it's it's 290 00:11:26,914 --> 00:11:28,134 a material science 291 00:11:29,929 --> 00:11:31,230 concept where you have 292 00:11:31,929 --> 00:11:34,970 a electrode that's a positive and electrode that's 293 00:11:34,970 --> 00:11:37,129 negative, and then you have a liquid in 294 00:11:37,129 --> 00:11:37,629 between, 295 00:11:38,009 --> 00:11:41,629 and that forms essentially your your battery system. 296 00:11:42,684 --> 00:11:43,824 To control this, 297 00:11:44,524 --> 00:11:45,024 it's 298 00:11:45,725 --> 00:11:47,504 a purely electrochemical process. 299 00:11:47,804 --> 00:11:49,024 So you can drive 300 00:11:49,565 --> 00:11:52,204 electrons into the battery when you want to 301 00:11:52,204 --> 00:11:54,784 charge it up, and you can have electrons 302 00:11:54,924 --> 00:11:57,360 extracted from the battery when you're discharging it. 303 00:11:57,360 --> 00:11:58,980 So it's either a power source 304 00:11:59,360 --> 00:12:01,459 or an energy storage source. 305 00:12:03,120 --> 00:12:05,279 Lithium ion batteries have come a really long 306 00:12:05,279 --> 00:12:07,539 way since the inception in the late seventies. 307 00:12:07,600 --> 00:12:10,335 But in all of the research and development 308 00:12:10,335 --> 00:12:13,054 that's happened, in parallel with the material science 309 00:12:13,054 --> 00:12:13,554 people, 310 00:12:13,934 --> 00:12:16,674 in parallel with the electrolyte liquid development 311 00:12:17,294 --> 00:12:17,794 people, 312 00:12:19,054 --> 00:12:21,294 everyone working in that space in the main 313 00:12:21,294 --> 00:12:22,355 will use electrochemical 314 00:12:22,735 --> 00:12:24,690 techniques to be able to test how the 315 00:12:24,690 --> 00:12:25,590 battery works, 316 00:12:26,049 --> 00:12:28,289 to prove how it works, to judge how 317 00:12:28,289 --> 00:12:31,009 much energy it stores, what voltage it works 318 00:12:31,009 --> 00:12:33,909 at, how fast you can charge and discharge 319 00:12:34,049 --> 00:12:37,669 this. These are all analyzed using electrochemical techniques 320 00:12:37,809 --> 00:12:38,309 because 321 00:12:38,654 --> 00:12:40,274 they are electrochemical processes. 322 00:12:40,735 --> 00:12:42,815 And it's becoming more and more familiar to 323 00:12:42,815 --> 00:12:44,654 people. And one of the most interesting things 324 00:12:44,654 --> 00:12:46,894 is to listen to people who drive electric 325 00:12:46,894 --> 00:12:47,394 vehicles. 326 00:12:48,975 --> 00:12:49,475 And 327 00:12:50,574 --> 00:12:51,475 the conversations 328 00:12:52,414 --> 00:12:55,070 with someone who buys an electric vehicle, they're 329 00:12:55,070 --> 00:12:57,549 very aware more than I ever imagined. You 330 00:12:57,549 --> 00:12:59,389 know, for someone who doesn't work in this 331 00:12:59,389 --> 00:13:01,170 space in the lab or in industry, 332 00:13:01,870 --> 00:13:04,610 what type of lithium ion battery chemistries exist. 333 00:13:05,714 --> 00:13:07,794 Drivers of some vehicles are very aware of 334 00:13:07,794 --> 00:13:10,674 lithium iron phosphate, which really threw me for 335 00:13:10,674 --> 00:13:13,074 6. I didn't realize people talked about this 336 00:13:13,074 --> 00:13:14,214 in everyday conversation. 337 00:13:14,754 --> 00:13:17,475 They know about NMC batteries. They talk in 338 00:13:17,475 --> 00:13:21,220 kilowatt hours, in kilowatts for charging rates, just 339 00:13:21,220 --> 00:13:24,039 like people used to do for internal combustion 340 00:13:24,100 --> 00:13:26,660 engines, and it's becoming more and more familiar 341 00:13:26,660 --> 00:13:29,460 to people. But there's a lot still happening 342 00:13:29,460 --> 00:13:30,600 in the research side. 343 00:13:31,220 --> 00:13:33,105 Solid state batteries are being developed 344 00:13:33,584 --> 00:13:35,504 really in earnest at the moment, and that's 345 00:13:35,504 --> 00:13:37,764 one of the key developments. These 346 00:13:38,225 --> 00:13:40,245 are slated at least in principle 347 00:13:41,184 --> 00:13:42,804 to be liquid free 348 00:13:43,664 --> 00:13:47,424 with a ceramic type electrolyte between the 2 349 00:13:47,424 --> 00:13:48,485 electrode materials. 350 00:13:48,980 --> 00:13:50,980 They give a high energy density and they're 351 00:13:50,980 --> 00:13:51,720 very lightweight. 352 00:13:52,980 --> 00:13:54,680 You have sodium ion technologies. 353 00:13:55,220 --> 00:13:58,040 They're the sister battery to to lithium ion. 354 00:13:58,100 --> 00:14:02,164 People looking at magnesium ion, zinc air, lithium 355 00:14:02,384 --> 00:14:05,125 sulfur. There's a whole plethora of different 356 00:14:05,504 --> 00:14:06,004 chemistries, 357 00:14:06,384 --> 00:14:08,725 all of which use materials that are probably 358 00:14:08,945 --> 00:14:10,084 more sustainable, 359 00:14:11,184 --> 00:14:12,404 but all of them 360 00:14:13,424 --> 00:14:14,404 need electrochemistry 361 00:14:14,784 --> 00:14:16,200 to understand how they operate, 362 00:14:16,679 --> 00:14:19,340 what goes on inside the system, and electrochemical 363 00:14:19,559 --> 00:14:22,040 methods then to benchmark them and actually work 364 00:14:22,040 --> 00:14:24,299 out how they perform relative to one another 365 00:14:24,519 --> 00:14:26,519 in terms of their applications. So would they 366 00:14:26,519 --> 00:14:27,019 be 367 00:14:28,120 --> 00:14:30,139 a smartwatch type battery chemistry, 368 00:14:30,634 --> 00:14:32,394 or would it be something like a grid 369 00:14:32,394 --> 00:14:35,274 storage buffer type large scale battery, or would 370 00:14:35,274 --> 00:14:37,375 it be a electric vehicle type battery? 371 00:14:37,835 --> 00:14:40,335 Each one has a specific type of internal, 372 00:14:41,115 --> 00:14:42,495 material set requirement, 373 00:14:42,970 --> 00:14:44,110 but they're all electrochemical 374 00:14:45,210 --> 00:14:46,669 energy storage systems 375 00:14:47,289 --> 00:14:49,870 and analyzed using exactly those techniques. 376 00:14:51,049 --> 00:14:53,870 So can can we move, CALM, beyond chips 377 00:14:54,169 --> 00:14:57,309 and energy, which are obviously 2 huge 378 00:14:57,945 --> 00:15:01,625 sectors, industrial sectors. And and maybe can I 379 00:15:01,625 --> 00:15:04,205 ask you to talk about some other technologies 380 00:15:04,504 --> 00:15:06,845 that benefit from advances 381 00:15:07,225 --> 00:15:08,365 in electrochemistry? 382 00:15:10,345 --> 00:15:11,965 I know of I know of some, 383 00:15:12,460 --> 00:15:14,720 outside of the outside of the semiconductor 384 00:15:15,179 --> 00:15:15,679 electrochemistry, 385 00:15:17,500 --> 00:15:20,539 chip manufacturing and batteries, I move into areas 386 00:15:20,539 --> 00:15:23,340 where I'm not so in-depth knowledgeable at all. 387 00:15:23,340 --> 00:15:24,700 But there are some of them that are 388 00:15:24,700 --> 00:15:25,519 really interesting. 389 00:15:26,615 --> 00:15:28,615 One of them, which was a surprise, but 390 00:15:28,615 --> 00:15:30,315 it's it's it's growing 391 00:15:30,695 --> 00:15:32,615 quite a lot, is the use of electric 392 00:15:32,615 --> 00:15:35,815 chemistry in the basic synthesis of organic compounds 393 00:15:35,815 --> 00:15:36,475 in pharmaceuticals. 394 00:15:37,575 --> 00:15:40,054 And so classically, these would have been there's 395 00:15:40,054 --> 00:15:41,195 always a charge 396 00:15:41,809 --> 00:15:45,190 transfer between species when you have chemical reactions 397 00:15:45,250 --> 00:15:45,750 happening. 398 00:15:46,210 --> 00:15:48,610 But what I'm beginning to see is more 399 00:15:48,610 --> 00:15:49,909 more activity in 400 00:15:50,610 --> 00:15:51,990 in using electrochemistry 401 00:15:52,450 --> 00:15:55,029 to control how those reactions happen 402 00:15:55,595 --> 00:15:57,995 and to form organic compounds in a much 403 00:15:57,995 --> 00:16:00,394 faster, much more efficient way in ways that 404 00:16:00,394 --> 00:16:01,054 you need, 405 00:16:01,754 --> 00:16:02,415 you know, 406 00:16:03,115 --> 00:16:05,754 certain types of catalyst to help those process 407 00:16:05,754 --> 00:16:08,955 happen. They can be overcome using electrochemical techniques 408 00:16:08,955 --> 00:16:10,014 because you're bringing 409 00:16:10,409 --> 00:16:13,230 outside power and energy into the system 410 00:16:13,610 --> 00:16:16,409 using current and voltage rather than just using, 411 00:16:16,409 --> 00:16:17,149 for example, 412 00:16:18,329 --> 00:16:20,809 a active or a passive catalyst inside your 413 00:16:20,809 --> 00:16:23,230 chemical reaction. So I find that very interesting, 414 00:16:23,384 --> 00:16:25,544 and I think that will grow in the 415 00:16:25,544 --> 00:16:27,884 use of electrochemistry in in organic 416 00:16:28,424 --> 00:16:29,565 and compound synthesis. 417 00:16:30,745 --> 00:16:32,605 Environmental sensors are another 418 00:16:32,904 --> 00:16:35,065 where we see with colleagues and in in 419 00:16:35,065 --> 00:16:37,804 other projects where electrochemical techniques 420 00:16:38,184 --> 00:16:39,165 are critical 421 00:16:40,129 --> 00:16:42,149 for looking at and developing 422 00:16:42,850 --> 00:16:45,090 new sensors and how they work. So not 423 00:16:45,090 --> 00:16:47,809 just carbon capture, but being able to very 424 00:16:47,809 --> 00:16:48,309 efficiently 425 00:16:49,009 --> 00:16:49,509 measure, 426 00:16:50,769 --> 00:16:53,110 the particulates in the air, nondestructively, 427 00:16:53,730 --> 00:16:54,230 repeatably, 428 00:16:54,684 --> 00:16:57,085 and using very, very cheap but very well 429 00:16:57,085 --> 00:16:59,264 controlled system. These tend to be, 430 00:17:00,125 --> 00:17:00,625 electrochemical 431 00:17:00,925 --> 00:17:03,884 in nature. There's water and food security. So 432 00:17:03,884 --> 00:17:04,705 water treatment 433 00:17:05,325 --> 00:17:06,384 using electrochemical 434 00:17:07,325 --> 00:17:08,384 tags for 435 00:17:09,670 --> 00:17:10,490 food security, 436 00:17:11,190 --> 00:17:11,690 longevity, 437 00:17:12,630 --> 00:17:14,789 assessing whether food is safe or not due 438 00:17:14,789 --> 00:17:15,769 to the electrochemical 439 00:17:16,070 --> 00:17:19,029 detection of certain compounds that remitted from food 440 00:17:19,029 --> 00:17:20,009 as it ages. 441 00:17:20,630 --> 00:17:22,390 And these can all be developed as very, 442 00:17:22,390 --> 00:17:22,890 very, 443 00:17:23,430 --> 00:17:24,105 low cost 444 00:17:24,664 --> 00:17:25,565 and tags, 445 00:17:26,345 --> 00:17:28,904 on food product labels, for example. So that's 446 00:17:28,904 --> 00:17:29,724 really interesting. 447 00:17:30,424 --> 00:17:32,845 But then, of course, you have solar and 448 00:17:33,464 --> 00:17:34,765 green fuel production. 449 00:17:37,079 --> 00:17:38,299 So in developing 450 00:17:38,839 --> 00:17:40,619 hydrogen for the hydrogen economy 451 00:17:41,079 --> 00:17:43,640 as fuel for fuel cells and for many 452 00:17:43,640 --> 00:17:44,380 more applications, 453 00:17:45,160 --> 00:17:47,579 that is an adaption of 454 00:17:48,595 --> 00:17:51,815 simple electrolysis, so splitting of water into hydrogen 455 00:17:52,035 --> 00:17:52,775 and oxygen. 456 00:17:53,235 --> 00:17:56,115 And that classically is an electrochemical type process. 457 00:17:56,115 --> 00:17:57,715 You need energy, so you can take it 458 00:17:57,715 --> 00:17:58,775 from this on. 459 00:17:59,555 --> 00:18:01,394 You can apply a voltage. You can apply 460 00:18:01,394 --> 00:18:03,235 a current. But when you do the voltage 461 00:18:03,235 --> 00:18:05,650 and current and you tackle this problem electrochemically, 462 00:18:05,869 --> 00:18:07,089 you've lots of control. 463 00:18:08,029 --> 00:18:10,210 The rate at which you form the electrolysis, 464 00:18:10,910 --> 00:18:12,369 you can develop materials 465 00:18:12,750 --> 00:18:15,069 that do it much more efficiently, but you 466 00:18:15,069 --> 00:18:16,529 can quantify it electrochemically. 467 00:18:17,815 --> 00:18:20,295 And there's also the possibility too of of 468 00:18:20,295 --> 00:18:20,795 electrochemical, 469 00:18:21,654 --> 00:18:22,154 fertilizer 470 00:18:22,455 --> 00:18:22,955 synthesis. 471 00:18:23,575 --> 00:18:27,035 So really low cost, high volume production of, 472 00:18:28,455 --> 00:18:29,914 fertilizers for agriculture. 473 00:18:31,174 --> 00:18:33,660 And and these can be done by sequestering 474 00:18:33,960 --> 00:18:35,259 gases and other minerals 475 00:18:35,640 --> 00:18:37,180 and forming those compounds, 476 00:18:37,720 --> 00:18:38,460 from electrochemistry 477 00:18:38,759 --> 00:18:41,420 too. It's really interesting, some of these techniques. 478 00:18:41,720 --> 00:18:44,460 It's interesting in a sense that electrochemistry 479 00:18:44,839 --> 00:18:46,779 is driving new ways of looking 480 00:18:47,184 --> 00:18:50,404 at solutions to, you know, problems like this, 481 00:18:50,785 --> 00:18:52,785 creating new products and allowing a way of 482 00:18:52,785 --> 00:18:55,365 analyzing and and and quantifying them. 483 00:18:55,825 --> 00:18:58,144 But they're kind of in all of their 484 00:18:58,144 --> 00:18:59,849 developments, they're really joined at the hip 485 00:19:00,730 --> 00:19:02,669 with other technologies and industries. 486 00:19:03,049 --> 00:19:04,910 So, you know, the it a surge 487 00:19:06,009 --> 00:19:06,750 in electrochemistry 488 00:19:07,369 --> 00:19:08,269 and its application 489 00:19:09,289 --> 00:19:10,589 will always need, 490 00:19:11,609 --> 00:19:14,654 you know, developments in in the chip manufacturing, 491 00:19:16,075 --> 00:19:18,234 and other industries that they're eventually going to 492 00:19:18,234 --> 00:19:19,134 be, you know, 493 00:19:19,674 --> 00:19:21,855 products from these technologies would need. 494 00:19:22,234 --> 00:19:24,315 I see. And and I was hoping now 495 00:19:24,315 --> 00:19:26,154 that we could talk a bit about your 496 00:19:26,154 --> 00:19:27,055 own research. 497 00:19:28,309 --> 00:19:30,890 You have a particular interest in developing 498 00:19:31,269 --> 00:19:32,490 analytical techniques 499 00:19:33,349 --> 00:19:35,930 for the non destructive testing 500 00:19:36,630 --> 00:19:37,369 of batteries 501 00:19:37,829 --> 00:19:39,130 and other electrochemical 502 00:19:39,589 --> 00:19:40,089 systems. 503 00:19:40,785 --> 00:19:43,125 Why is non destructive testing 504 00:19:43,825 --> 00:19:44,325 necessary? 505 00:19:45,184 --> 00:19:47,445 And and what what techniques are you developing? 506 00:19:48,785 --> 00:19:51,025 We we look at a very at a 507 00:19:51,025 --> 00:19:53,285 small part of the of the the bigger 508 00:19:54,225 --> 00:19:55,365 need, I guess. 509 00:19:55,859 --> 00:19:57,799 And part of it is to look at 510 00:19:57,940 --> 00:20:01,140 what happens inside a battery material or indeed 511 00:20:01,140 --> 00:20:01,960 any material. 512 00:20:02,339 --> 00:20:03,859 It doesn't have to be a battery one, 513 00:20:03,859 --> 00:20:05,940 but we look at these because they're they 514 00:20:05,940 --> 00:20:06,440 change 515 00:20:07,779 --> 00:20:08,279 under, 516 00:20:08,740 --> 00:20:09,240 use. 517 00:20:09,875 --> 00:20:12,055 But the basis was to develop a nondestructive 518 00:20:12,434 --> 00:20:15,075 method. So whether you use optics, whether you 519 00:20:15,075 --> 00:20:16,295 use ultrasonics, 520 00:20:16,674 --> 00:20:18,535 or whether you use x rays, 521 00:20:19,075 --> 00:20:19,975 all the different 522 00:20:21,475 --> 00:20:21,975 energies 523 00:20:22,289 --> 00:20:24,230 up across the electromagnetic spectrum, 524 00:20:25,170 --> 00:20:25,910 are typically 525 00:20:26,210 --> 00:20:28,130 are are are being investigated now to see 526 00:20:28,130 --> 00:20:29,430 what happens to these materials 527 00:20:29,890 --> 00:20:31,269 when they when they operate. 528 00:20:31,970 --> 00:20:34,369 And one of the needs is to pin 529 00:20:34,369 --> 00:20:34,869 down 530 00:20:35,650 --> 00:20:36,150 what 531 00:20:37,015 --> 00:20:37,755 really happens 532 00:20:38,295 --> 00:20:40,615 to lithium ion batteries, to give one example, 533 00:20:40,615 --> 00:20:41,755 during their operation. 534 00:20:42,375 --> 00:20:44,134 So if we were to take an electric 535 00:20:44,134 --> 00:20:47,095 vehicle application, for example, so the battery structure 536 00:20:47,095 --> 00:20:48,875 is very well defined. 537 00:20:49,255 --> 00:20:50,694 They know what materials are in it. They 538 00:20:50,694 --> 00:20:52,740 know how to put it together, and it's 539 00:20:52,740 --> 00:20:55,779 developed in a particular type of form factor, 540 00:20:55,779 --> 00:20:57,640 often like a cylinder type battery. 541 00:20:57,940 --> 00:20:59,779 And 100 of these are placed within a 542 00:20:59,779 --> 00:21:01,220 pack and put on the bottom of a 543 00:21:01,380 --> 00:21:02,519 of electric vehicle. 544 00:21:03,299 --> 00:21:03,799 Now 545 00:21:04,195 --> 00:21:06,355 when you operate one of these in Malaysia 546 00:21:06,355 --> 00:21:08,434 and you operate one of these in Northern 547 00:21:08,434 --> 00:21:08,934 Canada, 548 00:21:09,555 --> 00:21:12,295 different requirements happen for the same battery chemistry. 549 00:21:12,434 --> 00:21:15,715 Someone is constantly charging and discharging their cells 550 00:21:15,715 --> 00:21:18,160 in extreme cold, The other in a high 551 00:21:18,160 --> 00:21:19,859 humidity warmer environment. 552 00:21:20,480 --> 00:21:22,799 And people would like to know exactly, you 553 00:21:22,799 --> 00:21:25,539 know, what causes degradation long term. 554 00:21:26,720 --> 00:21:28,980 Is it the voltage? Is it the supercharging? 555 00:21:29,519 --> 00:21:30,580 Is it the temperature? 556 00:21:31,125 --> 00:21:33,945 Are there even materials used in the manufacture 557 00:21:34,005 --> 00:21:36,664 of batteries that are over the long term 558 00:21:37,684 --> 00:21:38,904 causing some degradation? 559 00:21:39,924 --> 00:21:41,125 And one of the ways to look at 560 00:21:41,125 --> 00:21:42,964 this is to do bring that system into 561 00:21:42,964 --> 00:21:44,345 the lab and do it nondestructively 562 00:21:45,179 --> 00:21:47,359 because you'll never find the solution by 563 00:21:47,819 --> 00:21:50,159 opening up the battery and looking at it 564 00:21:50,379 --> 00:21:50,879 afterwards. 565 00:21:51,179 --> 00:21:52,879 They're such a reactive system 566 00:21:53,179 --> 00:21:55,039 that as soon as you pull them apart, 567 00:21:55,099 --> 00:21:56,000 they're no longer 568 00:21:56,700 --> 00:21:57,599 working together. 569 00:21:58,220 --> 00:21:59,599 They're extremely reactive. 570 00:22:00,205 --> 00:22:02,865 And you can get some information from 571 00:22:03,164 --> 00:22:04,305 analyzing the materials, 572 00:22:05,085 --> 00:22:05,825 the composition, 573 00:22:06,525 --> 00:22:08,785 what they were like afterwards compared to before, 574 00:22:09,005 --> 00:22:10,845 but you get a lot more information by 575 00:22:10,845 --> 00:22:13,105 watching what actually happens to the material, 576 00:22:13,589 --> 00:22:16,710 the chemistry, the interfaces, and everything. When you 577 00:22:16,710 --> 00:22:17,210 can 578 00:22:17,669 --> 00:22:19,589 get that information at the same time, you're 579 00:22:19,589 --> 00:22:22,470 watching the electrochemical charging and discharging behavior, and 580 00:22:22,470 --> 00:22:24,549 you can link one to the other during 581 00:22:24,549 --> 00:22:25,289 their operation. 582 00:22:25,855 --> 00:22:27,774 And so this is becoming very interesting. A 583 00:22:27,774 --> 00:22:28,914 lot of, developments 584 00:22:29,214 --> 00:22:31,234 are in the optic space. 585 00:22:32,174 --> 00:22:34,595 So between photonic crystals to, 586 00:22:35,534 --> 00:22:37,634 fiber optics where people are using, 587 00:22:38,750 --> 00:22:42,190 fiber optics inbuilt into the battery cell. So 588 00:22:42,190 --> 00:22:44,130 it monitors the state of charge, 589 00:22:44,589 --> 00:22:46,210 the overall state of health, 590 00:22:46,750 --> 00:22:49,329 changes to the composition of the material, 591 00:22:50,044 --> 00:22:50,704 the electrolytes, 592 00:22:51,005 --> 00:22:53,265 the liquids inside, and doing that nondestructively 593 00:22:53,644 --> 00:22:54,144 optically 594 00:22:54,684 --> 00:22:56,144 at any time that they want. 595 00:22:57,484 --> 00:23:00,605 There's techniques like CT scanning that you would 596 00:23:00,605 --> 00:23:02,220 use in hospitals, for example. 597 00:23:03,179 --> 00:23:05,339 So a CT scan that people would use 598 00:23:05,339 --> 00:23:07,200 for biological system to analyze 599 00:23:07,819 --> 00:23:08,640 or treat, 600 00:23:09,900 --> 00:23:12,859 wounds or growths or whatever medical condition. Like, 601 00:23:12,859 --> 00:23:14,619 you can treat a battery as as that 602 00:23:14,619 --> 00:23:15,679 too. Look at its 603 00:23:16,059 --> 00:23:16,960 state of health. 604 00:23:17,644 --> 00:23:18,144 And 605 00:23:18,524 --> 00:23:21,565 people are using x-ray and CT systems to 606 00:23:21,565 --> 00:23:23,105 look at the material, 607 00:23:23,484 --> 00:23:24,224 the interfaces, 608 00:23:24,764 --> 00:23:27,565 and again, to just get an assessment of 609 00:23:27,565 --> 00:23:29,105 what's happening to the material 610 00:23:29,804 --> 00:23:31,750 at different length scales. So you have high 611 00:23:31,750 --> 00:23:34,170 energy systems looking at very small features, 612 00:23:34,549 --> 00:23:36,710 and you have lower energy systems looking at 613 00:23:36,710 --> 00:23:39,029 the entire battery cell to see, does it 614 00:23:39,029 --> 00:23:40,089 maintain its structure? 615 00:23:40,390 --> 00:23:42,390 Everything from sound waves to X rays are 616 00:23:42,390 --> 00:23:44,950 being used now for for what they call 617 00:23:44,950 --> 00:23:46,089 operando measurements. 618 00:23:46,585 --> 00:23:48,445 Just taking data 619 00:23:48,745 --> 00:23:50,985 on a system that's behaving as it would 620 00:23:50,985 --> 00:23:52,525 in the wild in a sense. 621 00:23:53,225 --> 00:23:56,045 I see. And you're you're mentioning those 622 00:23:57,065 --> 00:23:57,565 myriad 623 00:23:57,865 --> 00:23:58,924 different techniques, 624 00:23:59,600 --> 00:24:02,080 brings me on to my next question very, 625 00:24:02,080 --> 00:24:02,740 very nicely. 626 00:24:03,680 --> 00:24:06,019 So modern science is a collaborative 627 00:24:06,559 --> 00:24:07,059 endeavor. 628 00:24:07,440 --> 00:24:09,700 Can you talk about how electrochemists 629 00:24:10,480 --> 00:24:11,940 are working with physicists, 630 00:24:12,320 --> 00:24:13,460 material scientists, 631 00:24:14,515 --> 00:24:15,095 biologists, and 632 00:24:15,634 --> 00:24:16,454 and other 633 00:24:17,075 --> 00:24:19,095 researchers to advance knowledge? 634 00:24:20,595 --> 00:24:21,954 Well, if you if you were to look 635 00:24:21,954 --> 00:24:23,335 at if you were to look at, 636 00:24:24,035 --> 00:24:24,535 any, 637 00:24:25,795 --> 00:24:26,454 I guess, 638 00:24:26,755 --> 00:24:27,255 modern 639 00:24:28,130 --> 00:24:31,089 technological device from a from anything from electric 640 00:24:31,089 --> 00:24:32,490 vehicle to a phone. A phone will be 641 00:24:32,490 --> 00:24:34,309 a good example, so I'll use this one. 642 00:24:35,809 --> 00:24:37,429 Between the materials, 643 00:24:39,169 --> 00:24:41,569 even organic polymer materials and everything that you 644 00:24:41,569 --> 00:24:43,349 could use in an OLED or an AMOLED 645 00:24:43,625 --> 00:24:46,105 screen for the latest, you know, phones and 646 00:24:46,105 --> 00:24:46,605 smartwatches 647 00:24:47,865 --> 00:24:49,965 through to the chips that are being developed 648 00:24:50,025 --> 00:24:50,525 specifically 649 00:24:50,825 --> 00:24:51,325 for 650 00:24:51,705 --> 00:24:54,605 the use application in handheld device like that. 651 00:24:54,664 --> 00:24:56,984 The battery developments to give you high energy 652 00:24:56,984 --> 00:24:59,005 for a long time at extremely lightweight 653 00:24:59,609 --> 00:25:01,450 and form factors that allow you to be 654 00:25:01,450 --> 00:25:03,309 creative with the shape of the phone. 655 00:25:04,970 --> 00:25:07,230 The materials on the outside, the interconnectivity, 656 00:25:07,849 --> 00:25:10,890 the software, the low power Bluetooth, all the 657 00:25:10,890 --> 00:25:13,630 things that run-in any typical device needs 658 00:25:13,930 --> 00:25:16,634 now more than it ever did before. Everyone 659 00:25:17,015 --> 00:25:17,515 from, 660 00:25:18,615 --> 00:25:21,355 semiconductor physicists looking at display materials. 661 00:25:22,375 --> 00:25:25,035 You have an semiconductor chip manufacturing 662 00:25:25,894 --> 00:25:29,115 in the processing of this, the software development, 663 00:25:29,174 --> 00:25:30,394 the material scientists 664 00:25:30,880 --> 00:25:33,200 in everything from the outer casing to the 665 00:25:33,200 --> 00:25:33,700 screen, 666 00:25:34,079 --> 00:25:36,259 to the components and the chips, and especially 667 00:25:36,319 --> 00:25:38,960 too in the batteries because that's a critical 668 00:25:38,960 --> 00:25:40,660 component now for making everything 669 00:25:42,000 --> 00:25:42,500 mobile 670 00:25:43,039 --> 00:25:43,779 and wireless. 671 00:25:45,444 --> 00:25:45,944 And 672 00:25:46,244 --> 00:25:48,265 even with biologists too, so bioelectrochemical 673 00:25:48,804 --> 00:25:49,304 systems, 674 00:25:49,845 --> 00:25:50,984 especially sensors. 675 00:25:51,605 --> 00:25:53,444 That's growing a lot now where you want 676 00:25:53,444 --> 00:25:54,105 to have, 677 00:25:55,204 --> 00:25:58,085 on skin, sometimes in vitro systems that have 678 00:25:58,085 --> 00:25:59,304 their own power sources. 679 00:25:59,900 --> 00:26:00,799 They can measure, 680 00:26:01,500 --> 00:26:02,000 biological 681 00:26:03,740 --> 00:26:06,940 activity in real time, whether it's electrochemically or 682 00:26:06,940 --> 00:26:08,960 whether it's computationally through semiconductors. 683 00:26:09,900 --> 00:26:11,740 These are being developed, but it's it's so 684 00:26:11,740 --> 00:26:14,299 collaborative now that you can you, in the 685 00:26:14,299 --> 00:26:15,200 main, find 686 00:26:15,875 --> 00:26:19,075 electrochemists, physicists, material sciences, biologists, and more all 687 00:26:19,075 --> 00:26:21,474 working on elements of a single device. And 688 00:26:21,474 --> 00:26:23,335 this is becoming more and more common 689 00:26:23,954 --> 00:26:26,934 as we're beginning to see mobility from 690 00:26:27,394 --> 00:26:29,335 battery and energy storage technologies 691 00:26:30,034 --> 00:26:30,990 mixing with 692 00:26:31,470 --> 00:26:32,210 the semiconductor 693 00:26:32,509 --> 00:26:33,009 industry 694 00:26:33,630 --> 00:26:35,950 for the processing and allowing the device to 695 00:26:35,950 --> 00:26:37,950 actually do what it's supposed to do. And 696 00:26:37,950 --> 00:26:40,130 and, Colm, we've talked a lot about applications, 697 00:26:40,509 --> 00:26:43,069 I suppose, but I wanted to also ask 698 00:26:43,069 --> 00:26:43,809 you about 699 00:26:44,515 --> 00:26:45,015 fundamental 700 00:26:45,394 --> 00:26:46,775 research in electrochemistry. 701 00:26:47,234 --> 00:26:49,954 What are some of the hot topics that 702 00:26:49,954 --> 00:26:50,855 you and your 703 00:26:51,154 --> 00:26:52,115 colleagues are, 704 00:26:52,595 --> 00:26:54,535 are excited about at the moment, 705 00:26:55,315 --> 00:26:57,174 in terms of fundamental work? 706 00:26:58,750 --> 00:27:00,909 Well, in in in some of that I'm 707 00:27:00,909 --> 00:27:03,089 I'm that I'm aware of, 708 00:27:03,630 --> 00:27:05,470 but not working in, but I've I've I've 709 00:27:05,470 --> 00:27:08,369 read some really interesting studies on where 710 00:27:10,029 --> 00:27:10,529 electrochemistry 711 00:27:10,909 --> 00:27:12,434 to some degree is being used. 712 00:27:14,275 --> 00:27:16,835 The most obvious one are in next generation 713 00:27:16,835 --> 00:27:19,095 batteries and the motivation for doing this, 714 00:27:20,195 --> 00:27:22,115 like beyond lithium ion, as we move to 715 00:27:22,115 --> 00:27:24,275 solid state solving the problems of the, of 716 00:27:24,275 --> 00:27:25,470 the solid state batteries. 717 00:27:25,950 --> 00:27:27,409 So getting them to be 718 00:27:27,950 --> 00:27:30,750 industrially viable so you can actually manufacture. There's 719 00:27:30,750 --> 00:27:31,250 lots 720 00:27:31,789 --> 00:27:34,190 of interest in developing the material science, but 721 00:27:34,190 --> 00:27:35,169 also understanding 722 00:27:35,710 --> 00:27:37,089 the fundamental electrochemistry 723 00:27:37,470 --> 00:27:39,950 that happens in a solid material compared to 724 00:27:39,950 --> 00:27:40,964 a liquid material 725 00:27:41,444 --> 00:27:43,865 and how you can get those batteries to 726 00:27:43,924 --> 00:27:44,585 to work. 727 00:27:45,605 --> 00:27:48,484 Sodium ion systems are also electrochemically very interesting. 728 00:27:48,484 --> 00:27:48,984 Started 729 00:27:49,444 --> 00:27:50,984 actually decades ago too, 730 00:27:52,085 --> 00:27:53,924 just a few years after the lithium ion 731 00:27:53,924 --> 00:27:54,240 system. 732 00:27:55,200 --> 00:27:57,279 And it too has its own teething problems 733 00:27:57,279 --> 00:27:59,599 that need to be solved both from material 734 00:27:59,599 --> 00:28:02,319 science, but also from the electrochemical understanding of 735 00:28:02,319 --> 00:28:04,559 why one material behaves in one way with 736 00:28:04,559 --> 00:28:05,059 sodium, 737 00:28:05,679 --> 00:28:08,480 but so differently than the same material behaves 738 00:28:08,480 --> 00:28:09,220 with lithium. 739 00:28:10,164 --> 00:28:12,404 And why exactly that is, and how you 740 00:28:12,404 --> 00:28:14,105 exploit it and improve it. 741 00:28:14,964 --> 00:28:16,644 And beyond that, there are, 742 00:28:17,125 --> 00:28:19,765 redox flow batteries or another form of batteries 743 00:28:19,765 --> 00:28:20,585 which are 744 00:28:21,125 --> 00:28:23,045 not as well known, I guess, among the 745 00:28:23,045 --> 00:28:23,545 public, 746 00:28:24,404 --> 00:28:27,639 but they are a very, very large scale 747 00:28:27,639 --> 00:28:29,019 energy storage system. 748 00:28:29,639 --> 00:28:31,480 So to give you an example here, this 749 00:28:31,480 --> 00:28:33,740 is an electrochemical process also, 750 00:28:34,119 --> 00:28:35,500 but it uses reduction 751 00:28:36,119 --> 00:28:39,480 and oxidation processes in 2 huge vats of 752 00:28:39,480 --> 00:28:40,835 liquid. So you can 753 00:28:41,294 --> 00:28:43,694 imagine a water storage facility where you have 754 00:28:43,694 --> 00:28:45,954 100 and 100 of 1000 of liters. 755 00:28:46,414 --> 00:28:48,654 And these types of batteries would store the 756 00:28:48,654 --> 00:28:52,034 energy for an island community, for example. 757 00:28:52,759 --> 00:28:54,679 And they could be transported on ships, and 758 00:28:54,679 --> 00:28:56,679 the electrolyte is just flushed out of 1 759 00:28:56,679 --> 00:28:58,700 tank, and a fresh one is replaced. 760 00:28:59,240 --> 00:29:01,799 And an entire Ireland or an island culture 761 00:29:01,799 --> 00:29:05,879 could exist on completely green electrochemical battery storage 762 00:29:05,879 --> 00:29:08,139 technology that you just need to replace liquids. 763 00:29:08,279 --> 00:29:09,555 It's very, very efficient. 764 00:29:10,174 --> 00:29:13,394 C o two mediation, I think fertilizer production 765 00:29:14,654 --> 00:29:17,634 and controlling contaminants in the atmosphere. But fertilizer 766 00:29:17,775 --> 00:29:18,275 production 767 00:29:19,615 --> 00:29:20,115 is 768 00:29:20,654 --> 00:29:24,115 necessary for agriculture, but it's so important for 769 00:29:24,450 --> 00:29:25,589 our entire existence. 770 00:29:26,690 --> 00:29:28,950 Food production, the quality of soils, 771 00:29:29,569 --> 00:29:31,109 measuring these, developing 772 00:29:31,649 --> 00:29:35,750 very green sustainable fertilizer production from electrochemical processes 773 00:29:35,890 --> 00:29:37,589 rather than pure chemical processes. 774 00:29:38,855 --> 00:29:41,414 That's, I think, not just very interesting from 775 00:29:41,414 --> 00:29:42,554 a fundamental electrochemical 776 00:29:42,855 --> 00:29:44,634 point of view, but it's extremely important. 777 00:29:46,375 --> 00:29:47,514 But some of the more, 778 00:29:48,855 --> 00:29:52,619 esoteric or at least early stage fundamental blue 779 00:29:52,619 --> 00:29:53,119 sky, 780 00:29:54,299 --> 00:29:55,279 work in electrochemistry, 781 00:29:56,460 --> 00:29:59,440 there's interfaces between liquids where you can grow 782 00:29:59,740 --> 00:30:03,259 biological species. You can grow photoactive species at 783 00:30:03,259 --> 00:30:06,634 the interface between 2 liquids completely from electrochemical 784 00:30:06,855 --> 00:30:07,355 needs. 785 00:30:08,055 --> 00:30:09,515 And then you have bioelectrochemistry 786 00:30:10,055 --> 00:30:12,315 interactions, which I find very interesting, 787 00:30:13,095 --> 00:30:15,355 especially when you mix it with automation 788 00:30:16,055 --> 00:30:16,875 and discovery. 789 00:30:17,320 --> 00:30:18,140 So there are, 790 00:30:18,920 --> 00:30:20,140 people working in, 791 00:30:21,640 --> 00:30:24,539 chemical synthesis for using artificial intelligence 792 00:30:25,400 --> 00:30:26,299 and robots 793 00:30:26,920 --> 00:30:27,660 to do 794 00:30:28,039 --> 00:30:30,279 what it would take 100 and 100 of 795 00:30:30,279 --> 00:30:30,734 chemists 796 00:30:31,214 --> 00:30:33,535 over thousands of hours to do in just 797 00:30:33,535 --> 00:30:36,015 a fraction of the time. So they're analyzing 798 00:30:36,015 --> 00:30:36,674 the literature, 799 00:30:38,255 --> 00:30:41,295 developing a synthetic process, and being able to 800 00:30:41,295 --> 00:30:41,795 run 801 00:30:42,174 --> 00:30:44,835 hundreds of parallel experiments all automatically 802 00:30:46,000 --> 00:30:48,179 reproducing certain compounds and discovering 803 00:30:48,480 --> 00:30:51,539 completely new ones without any human interaction. 804 00:30:52,400 --> 00:30:56,319 This will eventually transition, I believe, to an 805 00:30:56,319 --> 00:30:57,059 an electrochemical 806 00:30:57,599 --> 00:30:59,919 synthesis and discovery where you now not just 807 00:30:59,919 --> 00:31:00,900 mixing chemicals, 808 00:31:01,544 --> 00:31:04,744 but the automated AI controlled robotic systems will 809 00:31:04,744 --> 00:31:07,224 start to control the voltage and the current 810 00:31:07,224 --> 00:31:08,684 just to give you those extra, 811 00:31:09,625 --> 00:31:11,085 control variables for, 812 00:31:11,865 --> 00:31:12,365 synthesis. 813 00:31:14,105 --> 00:31:17,460 So that there there's some very interesting things 814 00:31:17,460 --> 00:31:19,240 happening in in electrochemistry 815 00:31:19,700 --> 00:31:21,080 outside of the fundamentals 816 00:31:21,779 --> 00:31:23,320 that are, I guess, 817 00:31:24,339 --> 00:31:27,059 the important underpinning to, you know, understanding for 818 00:31:27,059 --> 00:31:28,839 the technologies that we're gonna develop. 819 00:31:29,375 --> 00:31:31,055 I see. And so it sounds to me 820 00:31:31,055 --> 00:31:32,674 like you're very positive 821 00:31:33,455 --> 00:31:34,515 about the future 822 00:31:34,815 --> 00:31:36,035 of electrochemistry. 823 00:31:36,575 --> 00:31:38,755 I'm guessing that you would encourage 824 00:31:39,535 --> 00:31:40,575 students to, 825 00:31:41,215 --> 00:31:42,975 to sign up and do a degree in 826 00:31:42,975 --> 00:31:44,275 chemistry and pursue 827 00:31:44,700 --> 00:31:46,079 a career in electrochemistry? 828 00:31:46,940 --> 00:31:47,919 Lots of opportunities? 829 00:31:48,779 --> 00:31:51,019 There are. And what I really wish is 830 00:31:51,019 --> 00:31:53,599 that, you know, as as someone who uses 831 00:31:53,659 --> 00:31:54,159 electrochemistry, 832 00:31:56,140 --> 00:31:58,319 on a daily basis, even for 833 00:31:58,815 --> 00:32:01,394 even for studies that are not classically electrochemical. 834 00:32:02,414 --> 00:32:04,255 You know, I mean, for batteries, but for 835 00:32:04,255 --> 00:32:04,755 semiconductor 836 00:32:05,454 --> 00:32:07,794 material. The electric it it's so fundamentally 837 00:32:08,095 --> 00:32:08,595 useful. 838 00:32:09,375 --> 00:32:12,335 But I think objectively important now given that 839 00:32:12,335 --> 00:32:12,990 so much 840 00:32:13,549 --> 00:32:16,190 between our our devices and wireless devices, but 841 00:32:16,190 --> 00:32:18,929 also from an environmental perspective and the transition 842 00:32:18,990 --> 00:32:21,329 to a greener, like, electric future. 843 00:32:22,109 --> 00:32:22,609 Electrochemistry 844 00:32:23,069 --> 00:32:25,005 is not just a sub 845 00:32:25,565 --> 00:32:28,684 set of a chemical degree. It's becoming more 846 00:32:28,684 --> 00:32:29,585 and more important. 847 00:32:30,525 --> 00:32:31,025 And 848 00:32:31,724 --> 00:32:34,684 short answer is yes. I definitely would with 849 00:32:34,684 --> 00:32:36,865 the huge caveat is that 850 00:32:37,420 --> 00:32:40,140 we still, in a lot of chemistry degrees, 851 00:32:40,140 --> 00:32:41,119 do not have 852 00:32:41,500 --> 00:32:44,000 a strong enough emphasis on 853 00:32:44,299 --> 00:32:45,119 the electrochemical 854 00:32:45,500 --> 00:32:46,720 part of those degrees. 855 00:32:47,820 --> 00:32:50,240 So the I think there's room for for 856 00:32:51,095 --> 00:32:53,115 looking at classical chemistry 857 00:32:53,815 --> 00:32:55,734 degrees, looking at the area in which the 858 00:32:55,734 --> 00:32:58,715 universities are based, seeing what industries are there, 859 00:32:59,174 --> 00:33:02,055 and, you know, comparing to physics for which 860 00:33:02,055 --> 00:33:03,195 for decades has 861 00:33:03,849 --> 00:33:06,409 has had degrees which are not just called 862 00:33:06,409 --> 00:33:06,909 physics. 863 00:33:07,289 --> 00:33:09,690 You have applied physics degrees, you have industrial 864 00:33:09,690 --> 00:33:11,230 physics degrees, you have 865 00:33:11,769 --> 00:33:14,190 an astronomy and astrophysics purely 866 00:33:14,569 --> 00:33:17,069 of of degrees in in some universities. 867 00:33:17,615 --> 00:33:18,515 And I think, you know, 868 00:33:19,215 --> 00:33:21,295 in in the US, you you you you 869 00:33:21,455 --> 00:33:24,174 it's rarer to find a pure chemistry course 870 00:33:24,174 --> 00:33:26,515 that doesn't have chemical engineering 871 00:33:27,134 --> 00:33:27,634 or 872 00:33:28,095 --> 00:33:28,595 biochemistry 873 00:33:29,055 --> 00:33:31,295 in build with this. And I think, especially 874 00:33:31,295 --> 00:33:31,955 in Europe, 875 00:33:32,460 --> 00:33:33,359 there is a chance 876 00:33:33,900 --> 00:33:34,799 to broaden, 877 00:33:36,140 --> 00:33:38,140 the way we look at chemistry degrees and 878 00:33:38,140 --> 00:33:39,919 and start to bring electrochemistry 879 00:33:40,220 --> 00:33:43,259 as a core topic in undergraduate degrees where 880 00:33:43,259 --> 00:33:44,640 it's very rarely done 881 00:33:45,224 --> 00:33:46,664 with the level that I think it will 882 00:33:46,664 --> 00:33:47,805 need for the future. 883 00:33:48,904 --> 00:33:51,144 Well, that's great, Colin. Thanks so much for, 884 00:33:51,384 --> 00:33:54,265 for coming on the podcast and talking about, 885 00:33:55,065 --> 00:33:56,365 all things electrochemistry. 886 00:33:57,065 --> 00:33:57,384 And, 887 00:33:57,865 --> 00:33:59,244 we we wish you well 888 00:33:59,559 --> 00:34:01,580 your tenure at the Electrochemical 889 00:34:02,039 --> 00:34:04,599 Society as well. Thank you very much, Hamish. 890 00:34:04,599 --> 00:34:06,119 It was really interesting to chat to you 891 00:34:06,119 --> 00:34:06,779 about this. 892 00:34:14,405 --> 00:34:16,244 I'm afraid that's all the time we have 893 00:34:16,244 --> 00:34:19,284 for this week's podcast, which is supported by 894 00:34:19,284 --> 00:34:20,505 American Elements. 895 00:34:21,204 --> 00:34:22,744 Thanks to Colm O'Dwyer 896 00:34:23,125 --> 00:34:25,144 for his insights into electrochemistry, 897 00:34:26,164 --> 00:34:27,625 and thanks to our producer, 898 00:34:28,199 --> 00:34:28,940 Fred Iles. 899 00:34:29,559 --> 00:34:31,420 We'll be back again next week.