044 - Improving fire safety of battery systems with Ofodike Ezekoye

Fire Science Show

Since Episode 6, the fire safety of battery systems was not very much visible in the show - a good time to change that! And we do this with a  true legend of fire safety - Ofodike Ezekoye. In the last year, I have learnt a lot about battery systems, which did not make me more afraid. Entirely opposite - the more I know, the more confident I am in fire science and engineers finding solutions for any outstanding issues with this emerging technology. In this episode, we go through the challenges at different scales of the battery system - from the chemistry of cathode, anode and electrolyte, through challenges in manufacturing and quality control, battery management systems up to the scale of whole off-grid systems. Each presents unique challenges. Each is a place of ongoing innovation. 

But the most important, IMHO, is to look at the threat holistically. Even if we remove all the intrinsic dangers of energy storage, the batteries may still be there when a fire starts for other reasons... We may be able to contain the 'thermal' threats, but are we looking for solutions to the smoke? And what to do with billions of already existing batteries that we deal with everywhere in our lives... All these questions got answered here, so you don't want to miss this episode!

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The Fire Science Show is produced by the Fire Science Media in collaboration with OFR Consultants. Thank you to the podcast sponsor for their continuous support towards our mission.

2022-03-30 58 min Transcript

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Transcript

WEBVTT

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Hello, everybody.

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Welcome to the Fire Science Show session 44.

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The legend after legend.

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I'm pretty blessed with the guests in lineup, in the podcast in the last weeks.

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And it's not a other today.

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Enough to say that my today's guests along with, , Professor Babrauskas  and Professor Horn alltogether they've published.

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almost 500.

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Academic papers.

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And I find that insane as an academic.

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Anyway, let's go with the big reveal quickly.

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My today's guest is professor Ofodike Ezekoye From the University of Texas at Austin.

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And DK is an expert in battery fire safety.

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And I cannot imagine a better place working on the fire safety of lithium-ion batteries than.

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And university of Texas Austin where the thing actually got kind of invented where professor John Goodenough Is lecturing and, yeah, he actually got the Nobel prize for inventing this type of battery.

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So.

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Great place to study battery, fire safety and the great research and going in there.

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I went into this interview with some tough questions about the safety of battery, his thermal runaways and things like that.

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But in fact, it ended up as quite reassuring talk with a good friend.

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About what's there to find out how complexity strikes at this.

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Again.

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And how smart people are battling for the safety of batteries.

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I think we've ended up with.

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Quite well-rounded.

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Discussion covering.

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Many many aspects of the battery fire safety.

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And I can tell you I'm I'm reassured I am a little less scared now.

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And more optimists.

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Towards a new solutions that will come for the safety of this technology.

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And yeah, knowing that the batteries are as a hot topic for the podcast as the wood in fire . I'm absolutely certain, I don't need to hype this anymore and that I already go to your attention and trust me.

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If you enjoy listening scientists who are absolutely passionate about what they're doing they're happy and enthusiastic about the research and about sharing it with everyone else.

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This is an episode for you.

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So I really hope you enjoy.

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So let's not prolong this anymore.

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Let's spend in show and jump into the episode.

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Hello everybody.

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I'm here today with Professor DK Ezekoye.

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Hello, DK.

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Great to have you in the show.

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Thank you.

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Welcome.

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Looking forward to it.

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I'm even more before the show, you told me that, for the cold chilly Texas, winters, you were thinking about building up some PV installation and batteries.

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Aren't you scared of that?

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Absolutely not.

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I am an advocate of this type of technology of, electrification generally, and certainly in terms of, battery systems.

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And so, last year, February, uh, we had a winter event here in Austin, which took out our electricity and, took out quite a bit of, infrastructure issues in, in terms of utilities.

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Even before then, I was very much planning on getting a photo-voltaic, panels and also battery energy storage.

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And so that obviously just in my mind, it's solidified the need to do this.

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And for all of us to, in some sense,  capability on hand for a renewable energy generation and storage.

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So I'm very much looking forward to it.

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And as I said earlier, , my reasons to do what I do are to improve the overall safety of these types of systems.

00:04:04.510 --> 00:04:07.031
So it's not, , an indictment of the systems.

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It's not say that the systems themselves are, somehow intrinsically unsafe.

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It's just that, we need to improve the overall safety of these systems.

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So more of us can comfortably use them.

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that sounds like not a bad task you've set for yourself.

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I find the word safety quite a difficult in this matter, you know, because, I look into Internet, the net people are terrified of the technology.

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Like literally terrified to the level, uh, where we're banning in many countries, electrical vehicles in the car parks, and, in Poland we had a nice movement where they formated.

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Mandatory to provide, sufficient electrical power to power, at least a plug-in hybrid,  every parking spot in your car park, and this law was put in place.

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So the buildings are now built with these types of installations, but now the fear has came here now, as we have these installations, we are thinking maybe we should ban the electric vehicles in the car parks.

00:05:07.788 --> 00:05:12.738
So it's kind of crazy that we've went all the way to invest in this.

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And now, because of fear, not facts, not science, not proof because of fear.

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We are rethinking that will not me and the government.

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Then not I'm in no way connected to them, but, uh, I would despise this connection.

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Anyway, uh, this safety, you what makes this battery system feel unsafe to people people are not scared of gasoline with heat of combustion of 46 megajoules per kilogram, which you contain like 50 liters on American, it would be like 20 gallons your car.

00:05:48.661 --> 00:05:52.675
Why we are not scared of riding on this bomb and we're scared of battery.

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What made us do that?

00:05:54.156 --> 00:05:55.932
oh, you know, that's a, great question.

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And.

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The issue in general, it's the risk perception versus actual risk.

00:06:01.302 --> 00:06:09.060
And we, in general, as humans are horrible with really understanding risk but risk perception is easy.

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And so with probably any new technology and especially with the way that we get information these days, that it's very easy to trigger, very irrational fears.

00:06:21.997 --> 00:06:32.894
And it's in some sense, and maybe I'm guilty of it too, because of just, the fact that we research it might make people think, oh my gosh, these systems are unsafe.

00:06:33.163 --> 00:06:35.141
Well, everything is unsafe, right?

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this is part of the issue.

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There's nothing that is absolutely safe.

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Well, that's entropy man.

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Right.

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Right.

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So the way, the only way that we can solve some of the really unsafe things, climate change global warming is to use renewable energy and to use energy storage.

00:06:54.536 --> 00:07:04.074
That is the way that we're going to deal with some of these, incredibly unsafe situations that we should be afraid of and fearful of.

00:07:04.403 --> 00:07:21.713
And from that perspective, I think that there's a responsibility for technologists who are working in the safety area to be very clear about why the circumstances and issues in which we're looking at safety of particular systems.

00:07:21.894 --> 00:07:31.824
And again, it's not that these things are, it's not, fear-mongering, it's not that these things are always unsafe and that we should, as a society, stay away from these types of technologies.

00:07:31.824 --> 00:07:34.163
But in fact, it's that, how do we.

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incentivize or move forward in terms of these technologies?

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Because we're improving the overall safety of these systems.

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And so I'd like to think about the work that I do in the battery area as.

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Create safer systems, trying to understand these systems better so that we can design against failures because failures to just happen.

00:07:55.314 --> 00:08:02.117
And we've seen the improvements in safety of, internal combustion engines over the last hundred years.

00:08:02.357 --> 00:08:09.706
Uh, we could argue that when they were first introduced, I mean, a lot of the safety systems that we take for granted now certainly were not implemented there.

00:08:09.836 --> 00:08:21.411
So why wouldn't we expect that there would be improvements in safety for whether it's electric vehicles or electric, storage systems within homes, within businesses at utility sites?

00:08:21.411 --> 00:08:24.831
So the goal of course, is to overall improve safety.

00:08:24.891 --> 00:08:28.040
And there's just so little data that currently exists.

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But I think that between the research and unfortunately incidents that occur, we're going to improve the overall safety of these.

00:08:36.251 --> 00:08:42.892
In fact, if you would look at it at the societal level, I'm obviously not a, not such a researcher.

00:08:42.892 --> 00:08:46.731
I think you're not either, but you've experienced blackouts last winter.

00:08:46.731 --> 00:08:47.032
Right.

00:08:47.091 --> 00:08:48.086
Uh, and, No.

00:08:48.086 --> 00:08:56.905
Yeah, this type of grid where everyone has a battery, for themselves, that would be probably a life changing experience at that moment.

00:08:56.905 --> 00:08:59.231
There, the, absolutely.

00:08:59.596 --> 00:09:13.706
uh, how big the benefit of this technology can be, it Oh yeah, And you, you've mentioned the energy generation and storage, like of the new, new types of fuels we're using, uh, wind solar, they're periodic at best and exactly.

00:09:13.706 --> 00:09:15.379
if you're nasty to them, Yeah.

00:09:16.269 --> 00:09:16.509
you yeah.

00:09:16.563 --> 00:09:19.443
need, you need to way to store that we need to solve that.

00:09:20.195 --> 00:09:26.918
I also observed this movement that the buildings should be like net zero or possibly positive energy generation.

00:09:26.918 --> 00:09:34.479
Like would be great if you're building the create more energy than it consumes, that would be the best building and like that exists today.

00:09:35.168 --> 00:09:37.828
And so it's something we would like.

00:09:38.129 --> 00:09:43.484
And again, it's something we're afraid of, you know, it's it's, you cannot have both, have to decide.

00:09:43.851 --> 00:09:49.501
and the more I learn about the systems, the less I am afraid of them.

00:09:49.501 --> 00:09:52.501
And I think that's probably the correct direction.

00:09:52.711 --> 00:09:55.710
Well, I guess oh, no, I completely agree.

00:09:55.769 --> 00:10:00.309
And so, part of it is how do we take industry?

00:10:00.309 --> 00:10:07.809
How do we take manufacturers from a position of being afraid of even acknowledging that there are safety concerns?

00:10:08.855 --> 00:10:15.125
To a point of acknowledgement of those safety concerns and with a goal of improvement.

00:10:15.424 --> 00:10:30.274
And so it's a delicate balance that they have to walk because if on the one hand they talk about safety concerns in their systems, and then it feeds into this perceived risk and perceived safety fears of the general public.

00:10:30.575 --> 00:10:31.384
Exactly.

00:10:31.384 --> 00:10:45.099
So that's, so from their perspective, and we've talked to, you know, lots of industrial concerns, about, well, we'd like to help you understand the safety of your battery systems and why battery systems.

00:10:45.099 --> 00:10:54.698
I mean, from again, the system level, whether to containerize battery system, to whether it's a particular type of appliance and the.

00:10:55.330 --> 00:11:00.397
Response you typically get is our systems are safe and there are no problems with our system.

00:11:00.756 --> 00:11:04.417
And as a researcher, who's looking at some of these safety issues.

00:11:04.537 --> 00:11:14.586
We know that's not true, that they can't possibly always be safe there considerations for I, the one I always think about is listen, fires have happened forever.

00:11:14.586 --> 00:11:16.326
Fire is always going to happen.

00:11:16.326 --> 00:11:20.799
Whether we go to space, whether we're on the sea, fire follows us.

00:11:20.879 --> 00:11:23.210
and so fires will happen.

00:11:23.480 --> 00:11:29.210
And the issue is that energy storage systems will be somewhere where a fire occurs.

00:11:29.210 --> 00:11:42.583
It may not be the cause of the fire, but it will be somewhere where a fire occurs, given that what can we do to make sure that your system doesn't add to the consequences of that fire that we know is going to occur?

00:11:42.764 --> 00:11:44.894
So, and so that's sometimes.

00:11:45.719 --> 00:12:05.172
Makes them feel a little bit better because it's an awareness that we're not saying that it's their system necessarily, that's the cause of the problem, but that we as researchers and safety science, and in particular on fire issues, we have a wearness about the frequency and intensity consequences of fire generally.

00:12:05.442 --> 00:12:13.091
And we understand how other fuel packages can get involved in, can exacerbate the fire consequences and fire impacts.

00:12:13.302 --> 00:12:19.432
So we're trying to help them in some sense, alleviate some of these consequences, some of these negative consequences.

00:12:19.552 --> 00:12:28.995
So it's a delicate balance then of taking manufacturers and having them acknowledge issues and try and improve the safety of their systems.

00:12:29.315 --> 00:12:38.615
making sure that the general public understands that the systems are generally safe and this is in fact, the future and providing guidance to regulators and.

00:12:39.365 --> 00:13:06.341
Permit authorities having jurisdiction, who are decision makers about how to sort of balance this and in their sense of, how do we PR you know, your example, how do we allow EVs in parking garages with the best available safety systems today and what are going to be improvements in safety systems tomorrow, and how do we retrofit or move those forward?

00:13:06.981 --> 00:13:11.361
That, that sort of, that's a, it's a lot of, it's a lot of work that we have to do for that, huh?

00:13:11.849 --> 00:13:17.729
Yeah, it seems so it seems like a roadmap to safety is needed or maybe even not to safety.

00:13:17.729 --> 00:13:25.351
Like it's a roadmap to improve from position A to position B to  position C, doesn't mean that  position A  is unsafe.

00:13:25.371 --> 00:13:27.501
It's just position B can be safer, right?

00:13:27.761 --> 00:13:28.121
Yes.

00:13:28.192 --> 00:13:34.761
be calling it a road to safety that we are unsafe in some way at this point, which may not necessarily be true.

00:13:35.255 --> 00:13:36.692
For me, a very way.

00:13:37.273 --> 00:13:45.878
As someone looking around, at this field, which is very alien to me, I'm like, I did a lot of things in, in compartment fires.

00:13:45.888 --> 00:13:47.227
I've burned buildings.

00:13:47.317 --> 00:13:48.548
I've did a lot of smoke.

00:13:48.561 --> 00:13:50.541
but men batteries are alien to me.

00:13:50.600 --> 00:13:51.410
They are alien.

00:13:51.561 --> 00:13:52.850
I don't understand them.

00:13:54.591 --> 00:13:57.230
I know they have power and they serve my laptop.

00:13:57.890 --> 00:14:00.053
but, I'm not an expert on that.

00:14:00.053 --> 00:14:07.941
So I wondered We probably need solutions on all levels, but the level of complexity of this thing is really huge.

00:14:08.380 --> 00:14:22.008
you have the level of chemistry your kathode, anode and I know that the fluid inside, the chemical compounds and reactions that happen inside the battery, have the battery itself as a single cell, element, a single pouch.

00:14:22.668 --> 00:14:29.327
is an ecosystem on its own with its heat transfer with its with its capacity, right?

00:14:29.658 --> 00:14:35.567
Then you start merging them together, creating an environment when you've connected multiple of the.

00:14:36.227 --> 00:14:38.477
Not necessarily, well, you changed the risk.

00:14:38.538 --> 00:14:46.280
The question is how much do you, did you just add all the risk of them or have you created a system with exponentially higher risk than the cell individually?

00:14:46.760 --> 00:14:51.823
then again, I've also learned that, don't just put a bunch of them into a car.

00:14:51.823 --> 00:14:53.653
You need a system that manages them.

00:14:53.653 --> 00:15:08.734
So need to build a compartment for them or, or some, some case in which they're stalled, which is the technology need the battery management system that makes sure they're operating at the correct parameters that manages the charging and discharging and so on.

00:15:09.274 --> 00:15:15.508
then you, you have the whole system which would be a car, a building, or the benefactor of the energy of this system.

00:15:16.018 --> 00:15:26.583
you have this many level of complexities and I see Potential challenges and, also, but then will, opportunities for improving the safety at each of these levels.

00:15:26.583 --> 00:15:33.418
So please tell me at what level you act and do you think, biggest improvements can come from?

00:15:34.107 --> 00:15:40.163
Which someone can see, the one you act oh, so, I love what you just said for a lot of reasons.

00:15:40.163 --> 00:15:42.923
And it goes back to a little bit of what we were saying before.

00:15:43.917 --> 00:15:47.876
Technology in general and technological systems are getting more complex.

00:15:47.937 --> 00:15:50.366
So that's something that's absolutely occurring.

00:15:50.817 --> 00:15:55.136
The pace at which these things are changing and evolving is increasing.

00:15:55.197 --> 00:15:56.277
The rate is increasing.

00:15:56.277 --> 00:15:59.126
So we're getting increasing complexity.

00:15:59.157 --> 00:16:04.586
We're getting increasing complexity faster, and we are on the safety side.

00:16:04.586 --> 00:16:13.244
We're in some sense, the, boundaries, the, reigns to try to make sure that we manage the overall safety of these incredibly complex systems.

00:16:13.724 --> 00:16:35.326
And so these battery systems are one of the first, I'm not saying to say that the only, but they're one of the early sort of testing systems for us as safety, technologists, safety, engineers, safety profession, to try to really figure out how do we, allow this transition to occur in a way that makes sense.

00:16:35.777 --> 00:16:36.163
So.

00:16:36.188 --> 00:16:44.298
I see myself as really trying to impact the life safety and property protection issues associated with batteries.

00:16:44.719 --> 00:16:50.749
And the issue though becomes that I feel to do that appropriately inadequately.

00:16:50.839 --> 00:17:01.139
I need to understand this system because of the complexity that you mentioned, as an academic, I benefit from working with really smart people who can teach me about these systems.

00:17:01.139 --> 00:17:08.088
So my, sort of goal is to learn about this and to communicate this and to improve the overall safety of these systems.

00:17:08.814 --> 00:17:10.884
I, we can't do these things alone.

00:17:10.884 --> 00:17:13.901
We, as we discussed, we work in communities.

00:17:14.320 --> 00:17:15.820
we tell stories, we talk.

00:17:16.090 --> 00:17:28.340
And so from that perspective I've asked my students and my collaborators, how to bring me up to speed in terms of our research, by looking at things as sort of.

00:17:29.016 --> 00:17:34.169
Far from what I do as for example, electrical circuit modeling of cells.

00:17:34.259 --> 00:17:39.598
So I want to understand fundamentally how does a battery work?

00:17:39.659 --> 00:18:24.093
And so, uh, I've had students working on, uh, pseudo two D models of cells, of circuit models of cells, of all sorts of different models of cells, so that I can understand the electrical performance of cells and what issues cell researchers are interested in for that, that gives me some insight into what the challenges are at that scale and from a modeling perspective, because that's going to be important as we start to think about multiple cells or as we start to think about even layers of the sort of, uh, single layer cell systems, then at like increasing complexity, then we ask questions about what happens if we have cell failure?

00:18:24.123 --> 00:18:25.083
How do we think of.

00:18:25.613 --> 00:18:31.343
Electrical performance as for example, initiating thermal considerations.

00:18:31.343 --> 00:18:50.633
And so just even in the normal cycling of a cell there's heat generation, and we appreciate that, we know that now the question is can this heat generation itself iManage or is there some possibility of it cascading into a thermal and thermal chemical reaction rate that would occur.

00:18:50.932 --> 00:18:53.002
And so understanding that is important.

00:18:53.063 --> 00:19:03.982
And again, I'm not a chemist, but how do we think about parameterizing low order models that can allow us to understand how this reaction process occurs?

00:19:04.282 --> 00:19:12.803
Again, with an eye at consequence scale at largest largest scales for us, which might be the building or container or the electric vehicle.

00:19:13.853 --> 00:19:18.728
And so now again, Understanding, for example, cell to cell propagation.

00:19:18.728 --> 00:19:28.199
Now it's a little bit looking more like what we normally do in terms of heat, transfer, physics, mass transfer issues, solid fire Yeah, exactly.

00:19:28.469 --> 00:19:29.128
Exactly.

00:19:29.128 --> 00:19:35.068
So it's looking more like what we do, but it's a parameterization of the kinetics associated with that.

00:19:35.489 --> 00:19:36.209
I would argue.

00:19:36.209 --> 00:19:44.159
That's not that different from what we, as fire scientists, researchers have done for decades in terms of looking at condensed phase systems.

00:19:44.429 --> 00:19:47.608
My gosh, condensed phase, any condensed systems, incredibly complex.

00:19:47.608 --> 00:19:51.719
I say, Hey, talk about wood or polyurethane or anything.

00:19:51.838 --> 00:19:53.308
And you tell me that that's simple.

00:19:53.338 --> 00:19:59.048
That's there's nothing simple about understanding the degradation of these condensed phase systems.

00:19:59.424 --> 00:20:07.278
now with all the decades and number of researchers, who've put so much energy and intellectual effort into that.

00:20:07.519 --> 00:20:11.019
We have a better understanding of how these systems degrade and.

00:20:11.824 --> 00:20:24.334
Both in terms of the toxicity in terms of the energy release rates, in terms of all these factors, what happens with these complex engineered systems, like Polyurethane now, and we've devised tools.

00:20:24.364 --> 00:20:26.554
You had Vyto Babrauskas on earlier.

00:20:26.794 --> 00:20:32.673
We've devised tools to characterize and measure the energy release rate of the systems.

00:20:32.763 --> 00:20:35.314
The, again, the toxicity chemicals, et cetera.

00:20:36.094 --> 00:20:41.157
We haven't developed that to the same extent for a new technology.

00:20:41.428 --> 00:20:41.824
Like.

00:20:42.096 --> 00:20:47.625
a lithium-ion cell, there are tools out there, but maybe we don't understand them or wavy.

00:20:47.625 --> 00:20:52.726
We haven't fashioned them into a way to really understand some of the issues in terms of propagation.

00:20:52.726 --> 00:20:57.705
And we're in the early days of characterizing and really understanding those types of details.

00:20:58.096 --> 00:21:06.135
But arguably once we do understand that and we're able to parameterize these lower order models, then we can think about what propagation looks like.

00:21:06.135 --> 00:21:08.296
What rate of gas release looks like?

00:21:08.596 --> 00:21:12.465
What rate of energy release looks like for these types of components.

00:21:12.826 --> 00:21:15.645
And then we stitch it together at the higher level.

00:21:15.945 --> 00:21:21.976
Now you said also that the complexity is not just associated with the cells and that's absolutely true.

00:21:22.246 --> 00:21:29.002
The complexity is that it's a system and it's a software based system, which is increasingly true.

00:21:29.363 --> 00:21:31.373
So there's a battery management system.

00:21:31.373 --> 00:21:35.692
There are all sorts of other protection systems often.

00:21:36.558 --> 00:21:41.066
Some chip or in some sort of logic sequence that's associated with that.

00:21:41.425 --> 00:21:43.465
And unfortunately bugs can occur.

00:21:43.575 --> 00:21:49.553
You can buy a BMS for as cheap as $15, and you get what you pay for.

00:21:49.762 --> 00:22:01.645
So there are really strong battery management systems that no matter how, flawed a particular cell might be, that can overcome the flaws of cell.

00:22:02.125 --> 00:22:04.300
it and Yeah.

00:22:04.330 --> 00:22:05.290
Yeah, exactly.

00:22:05.290 --> 00:22:17.070
They can balance out some of the issues between poorly performing cells and better performing cells because natural variability exists in terms of sort of cells from a manufacturing perspective or otherwise.

00:22:17.580 --> 00:22:35.611
And then on top of it, we may have other components in the system, whether it's an inverter or other sort of traditional electrical mechanical systems, any of these can possibly fail on top of it because of failures, we have sensors.

00:22:35.641 --> 00:22:39.661
And so the sensors could initiate some sort of activity.

00:22:40.288 --> 00:22:44.758
one would say that, oh, that would be crazy for a sensor system to initiate.

00:22:45.183 --> 00:22:59.104
an intervention that might cause additional failures, but I think we've seen that even in the battery space where, oh, misdiagnosis of say smoke, the smoke could have been outside of the battery container.

00:22:59.193 --> 00:23:10.921
So a smoke detector could trigger intervention, for example, a water spray that could damage the cells and then lead to a cascading propagation.

00:23:11.280 --> 00:23:15.181
And so without again, naming names, things like this have occurred.

00:23:15.451 --> 00:23:27.240
So, as we think about these very complex systems, maybe B issue really is that we have to rethink how we, analyze safety for very complex systems.

00:23:27.240 --> 00:23:32.280
And maybe we're really learning with these battery systems.

00:23:32.310 --> 00:23:37.906
And this is the template by which our profession evolves in terms of understanding safety.

00:23:38.240 --> 00:23:45.891
I'm not even sort of, I know nothing about fusion, but every week there's another article that, yeah.

00:23:46.643 --> 00:23:51.784
that there are improvements and pathways towards workable fusion reactors.

00:23:52.864 --> 00:23:54.273
Somebody's got to protect.

00:23:54.453 --> 00:23:58.473
So we already protect nuclear reactors as a community.

00:23:58.503 --> 00:24:10.923
So the new, the nuclear industry uses fire and safety professionals to ensure that these incredibly complex systems don't catastrophic fail.

00:24:11.534 --> 00:24:19.827
we're going to have increasingly spaceports and we're going to have rocket systems and all the complexity associated with the fuels there.

00:24:20.532 --> 00:24:23.083
And we're going to be the ones asked to manage them.

00:24:23.373 --> 00:24:30.519
we think about the, there was a recently a large warehouse fire in the U S warehouses aren't supposed to burn, right.

00:24:30.519 --> 00:24:51.999
We, you know, we have all sorts of fire protection systems in place that should protect against them, but it's with the increasing complexity of all these systems that, you know, maybe we sort of, the piecemeal approaches to protection and the research associated with thinking about protection for these complex systems that it has to evolve also.

00:24:52.179 --> 00:24:56.378
And I know that you're doing a lot of work in terms of characterization of complex systems.

00:24:56.378 --> 00:25:04.598
And you know, whether it's, again, did, you said building scales buildings are increasingly complex systems with software controls, HVAC system sensor systems.

00:25:04.818 --> 00:25:05.538
It's insane.

00:25:05.568 --> 00:25:05.749
Yeah.

00:25:06.429 --> 00:25:07.058
It's incredible.

00:25:07.058 --> 00:25:07.358
Isn't it?

00:25:07.826 --> 00:25:08.195
Yeah.

00:25:08.266 --> 00:25:14.205
It's, I'm very safe about my war job with this complexity increase.

00:25:15.296 --> 00:25:21.223
I wanted also, going back to this, issue of fear and, safety, A failure is a failure.

00:25:21.253 --> 00:25:23.443
Not every failure is a catastrophe.

00:25:24.284 --> 00:25:34.624
I wondered if maybe we could try characterize what distinguishes a failure that could be acceptable or, negligent.

00:25:35.334 --> 00:25:41.794
From a failure that, turns into, first page of a newspaper, we've seen these videos.

00:25:41.794 --> 00:25:44.913
Uh, there was a video in the Shanghai with a huge fire.

00:25:45.423 --> 00:25:48.483
was a video of Chinese buses catching fire.

00:25:48.990 --> 00:25:56.009
there was a, this ship that burned down plenty of fancy cars for Americans, which you will not get.

00:25:56.670 --> 00:25:58.035
It's a shame when that's right.

00:25:59.700 --> 00:26:01.275
you, are going to ride Okay.

00:26:02.279 --> 00:26:05.775
now, Those aren't safe either.

00:26:05.775 --> 00:26:07.214
You know, you can get kicked by a horse.

00:26:09.230 --> 00:26:21.171
I would claim it's also rich people vehicle and that's, but yeah, What's the scenario when this fire of a battery system becomes catastrophical, what is the cause of such a fire?

00:26:21.621 --> 00:26:25.161
I know a phrase thermal runaway, and, it sounds scary.

00:26:25.161 --> 00:26:32.990
And, uh, I guess the videos have shown that, but how does, uh, a failure of a cell become a catastrophe good.

00:26:33.141 --> 00:26:33.411
Okay.

00:26:33.441 --> 00:26:37.760
So maybe first of all, we talk about possible failures of cells.

00:26:37.881 --> 00:26:43.221
And so, um, a cell itself could fail because of challenges in manufacturing.

00:26:43.521 --> 00:26:52.387
what's interesting is that, my university, university of Texas, uh, A long history of sort of excellence in, battery materials.

00:26:52.417 --> 00:26:59.137
And so we have distinguished, we have a Nobel Laureate with distinguished researchers who were working on the battery materials issues.

00:26:59.621 --> 00:27:08.651
there's a big step up between sort of designing and envisioning what the right battery materials are and the actual manufacturing of batteries.

00:27:08.980 --> 00:27:19.020
And so a couple of years ago, few years ago, we decided that we were going to embark on, an exercise to develop a battery fabrication of prototyping facility.

00:27:19.441 --> 00:27:23.855
And, I was fortunate enough be involved and I'm still involved in that process.

00:27:24.184 --> 00:27:36.407
And so, what I've learned about that is, is that battery manufacturing is A) really hard, there is limited metrology and in some sense, quality control there.

00:27:37.472 --> 00:27:45.982
The us government has finally realized that battery manufacturing is a strategically important national interest.

00:27:45.982 --> 00:27:53.192
So it's something that absolutely needs to be done because we're increasingly relying on these types of technologies.

00:27:53.673 --> 00:28:16.076
So learning about that has pointed out to me that very small mistakes can occur in terms of the manufacturing that would perhaps not immediately recognize in any kind of cell testing, but could have long term consequences when a cell is supposed to last years, for example, so thousands of cycles.

00:28:16.451 --> 00:28:30.056
well, I think when we're, when we were talking about battery manufacturing, I don't know if everyone realizes it, but we were talking about quantities manufactured at the same time, all.

00:28:30.211 --> 00:28:37.141
a line of battery produces like hundreds Oh, the few seconds oh, absolutely.

00:28:37.280 --> 00:28:47.698
quicker than, uh, machine gun in terms of Oh, it's So, here it's not a quality control where you would take every cell and put it into a on, say, oh, this cell is okay.

00:28:47.698 --> 00:28:50.738
No, we're talking about it's a printing press.

00:28:50.738 --> 00:28:52.897
Literally it it's a, it is a printing.

00:28:52.958 --> 00:28:54.788
It looks like a printing press.

00:28:55.057 --> 00:28:57.038
There's roll to roll technology.

00:28:57.038 --> 00:28:58.298
You're absolutely right.

00:28:58.298 --> 00:29:05.597
Everybody should watch, go to YouTube and take a look at a battery manufacturing facility in terms of how it's operating.

00:29:05.617 --> 00:29:12.008
So And so with manufacturing them, I can imagine even a small issues at random.

00:29:12.008 --> 00:29:17.951
Like every yes, you get the one that goes wrong, but yes, five minutes.

00:29:17.951 --> 00:29:18.280
Right.

00:29:18.851 --> 00:29:19.901
yes, no, no.

00:29:19.901 --> 00:29:22.300
You're you're so you're, you're hitting the exact points.

00:29:22.300 --> 00:29:22.601
Is that.

00:29:23.577 --> 00:29:33.028
Defects can happen when you're producing these types of large numbers and even with really good quality control, some things will slip by that may have a problem.

00:29:33.057 --> 00:29:33.478
Okay.

00:29:33.718 --> 00:29:37.201
Now, a particular cell might have that type of defect in it.

00:29:37.494 --> 00:29:43.644
otherwise a cell, could go into failure because of what we talked about before the battery management system.

00:29:43.644 --> 00:29:52.234
So one of the things that the battery management system is trying to do is it's trying to balance, for example, between all the different cells, in a battery.

00:29:52.234 --> 00:30:08.926
So again, when we talk about a battery, a battery is comprised of cells and these are individual cells and these cells can be as small as, a milli amp hour or so a hundred million amp hour or so, or as large as a hundred amp power.

00:30:08.926 --> 00:30:11.567
So, which, you know, we we've looked at and tested.

00:30:11.987 --> 00:30:17.836
. From that perspective, there's a scale range in terms of the energy storage associated with a given cell.

00:30:18.497 --> 00:30:23.297
a large cell failing has very different consequences from a small cell failing.

00:30:23.567 --> 00:30:31.186
And now the battery management system is trying to balance between the different cells and whether it's in parallel or series configurations.

00:30:31.517 --> 00:30:47.616
And, there is the possibility for example, that because the cells are not identical, that you might over time overcharge over discharge, any particular cell in the string of cells that comprise the battery and that could lead to failures.

00:30:47.616 --> 00:30:50.946
And those failures could be, for example, something like an overcharge that might occur.

00:30:51.336 --> 00:30:59.993
And so in terms of the overcharge that might be occurring, for lithium ion cells, you can get plating of the lithium metal because it's a transport issue, such a tray.

00:31:00.023 --> 00:31:04.673
So transport limitations of the ability of intercalated.

00:31:05.423 --> 00:31:14.693
Lithium ions into these active materials could cause something like a plating process to occur as this lithium played in this lithium metal occurring.

00:31:14.693 --> 00:31:21.634
For example, on the anode side, then you would get the possibility of dendrites forming.

00:31:21.683 --> 00:31:23.993
And these are again, just whiskers.

00:31:23.993 --> 00:31:41.237
If you think about them like that metal whiskers that could penetrate across the separator, which is trying to keep the, the electrical charges away from each other, if you will, from certain having sort of spontaneous discharge and then that could lead to a short circuit.

00:31:41.750 --> 00:31:47.339
so operationally one could get a failure to occur in terms of manufacturing.

00:31:47.430 --> 00:32:09.916
One could imagine that there's a failure that occurs and certainly in terms of mechanical damage, whether it's a belt bending process, Crash of a vehicle that causes a mechanical failure and, that bending, for example, puts elements the anode closer to the cathode or tears, the separator, or punctures, the separator.

00:32:10.217 --> 00:32:16.513
And then you can have a short that's formed because of this mechanical failure process.

00:32:16.930 --> 00:32:18.759
and then of course there's environmental failure.

00:32:18.759 --> 00:32:21.670
So we, again talk about the fact that fires occur.

00:32:21.700 --> 00:32:34.997
We know the fires occur, so, a high temperature environment could lead to the degradation of whether it's the separator, within the particular cell or two, reactions occurring, with.

00:32:35.499 --> 00:32:43.174
The, cell itself, and those could lead to this sort of cascading failure of all these different reactions.

00:32:43.174 --> 00:32:46.744
And that's the process that we talk about in terms of thermal runaway.

00:32:46.954 --> 00:32:50.734
So a single cell failure will occur.

00:32:51.694 --> 00:32:54.664
Single cells will fail from any number of reasons.

00:32:54.994 --> 00:32:59.930
And as you say, The issue becomes what is management of single cell failure look like?

00:33:00.220 --> 00:33:11.470
, and there are design professionals who are increasingly tasked to understand how to manage single cell failures, either through a heat transfer mechanisms.

00:33:11.936 --> 00:33:17.493
so, what kind of flows would we direct around a single cell or around the arrangement of cells?

00:33:17.493 --> 00:33:20.173
So that if a  single cell failure occurred, it doesn't cascade.

00:33:20.584 --> 00:33:22.894
, in terms of compartmentalization, as you mentioned.

00:33:22.894 --> 00:33:31.953
So are there whether it's facing materials or other types of materials that one could layer into the systems to manage the heat transfer?

00:33:32.703 --> 00:33:39.094
Now that management heat transfer is complex because as we said before, just normal cycling of a cell causes the cell to heat up.

00:33:39.273 --> 00:33:45.433
So there is you think of it as a diode on under certain conditions, under normal operating conditions.

00:33:45.433 --> 00:33:46.784
I'm going to get heat out of the cell.

00:33:47.424 --> 00:34:00.204
and manage the overall system in terms of that heat transfer under abnormal operation conditions for a single cell, I may want to isolate that cell, so I will let that cell burn away, but I don't want it to cascade to the other cells.

00:34:00.384 --> 00:34:07.694
So,  people and organizations are designing, developing, I should say design tools and it's not just CFD.

00:34:07.694 --> 00:34:09.315
It could be resistance network.

00:34:09.344 --> 00:34:18.148
It could be other types of tools that would now be increasingly used to design the safety systems and protection systems.

00:34:18.298 --> 00:34:22.559
Oftentimes we think about it really as a thermal protection systems for batteries.

00:34:22.889 --> 00:34:23.248
Okay.

00:34:23.369 --> 00:34:26.278
So batteries, single cells can fail.

00:34:26.818 --> 00:34:42.528
There are design professionals, whether it's an electric vehicle company or at a, an integrator developing for, onsite protection at a utility or at a big box, Uh, retail outlet, et cetera.

00:34:42.757 --> 00:34:44.192
these protection systems.

00:34:44.521 --> 00:34:54.335
Now having said that hopefully those protection systems are still able to manage single or two or three cell failures.

00:34:54.762 --> 00:35:05.824
I would say that there's a push there had been a push to going to larger cell capacities because of economies of scale and for all sorts of good reasons,, for electric vehicles.

00:35:05.824 --> 00:35:11.369
So people were saying, okay, well, let's go with, 94 amp hour cells or larger capacity cells.

00:35:11.878 --> 00:35:16.498
Those are harder to manage both thermally and otherwise in terms of failure.

00:35:16.768 --> 00:35:23.869
So in some sense, we know there are vehicle companies, a lot of them came out of Silicon valley that leverage what happened.

00:35:24.603 --> 00:35:29.643
Laptops and portable electronics that have much smaller capacity cells.

00:35:30.027 --> 00:35:33.336
and so these are whether it's 18650, 2170.

00:35:33.476 --> 00:35:40.766
So there are the smaller cell capacities and different formats that other companies have said, well, you know what?

00:35:40.797 --> 00:35:42.956
We can manage and control these better.

00:35:43.257 --> 00:35:47.137
Now there challenges in terms of, you know, having so many small cells.

00:35:47.137 --> 00:35:50.257
So there's probably some happy medium that, EV.

00:35:50.257 --> 00:36:01.367
.companies and others are going to think about in terms of, dense enough and high enough energy density and large enough cells, but not too large, that it becomes a control issue later on.

00:36:01.726 --> 00:36:02.027
Okay.

00:36:02.117 --> 00:36:15.773
So landscape wise, there has to be this idea then that there is some sweet spot in terms of size of cells that can be controlled so that if and when a failure occurs, it can be managed.

00:36:15.773 --> 00:36:17.454
So it doesn't cascade and propagate.

00:36:18.623 --> 00:36:30.277
Now I'm interested in that, but again, I say, well, if they don't do their job perfectly in quotes, um, we're still going to get larger scale propagation.

00:36:30.306 --> 00:36:35.166
And when we get larger scale propagation, we can get a whole module that fails.

00:36:35.827 --> 00:36:37.327
What are the impacts of that?

00:36:37.657 --> 00:36:39.456
Now it's kind of interesting.

00:36:39.456 --> 00:36:41.396
So, , probably you say the same thing.

00:36:41.423 --> 00:36:51.014
When I teach my fire science class, one of the first things we talk about is that the thing that sort of kills people most in fires is not the heat and fire.

00:36:51.014 --> 00:36:51.704
It's a smoke.

00:36:52.454 --> 00:37:00.965
So, I think that in some sense, we overthink the thermal issues associated with battery failures and under think.

00:37:01.657 --> 00:37:09.788
Toxicological impacts of it or the cascade of battery failures to other fuel packets.

00:37:09.907 --> 00:37:14.347
And then to really the thing that we're afraid of, or I'm afraid of, which is the smoke.

00:37:14.677 --> 00:37:23.887
So I think that connecting the dots between, okay, cell failure, what gases are released, what are the issues in terms of toxicity?

00:37:24.458 --> 00:37:32.708
How would this impede people in terms of egress or otherwise, what are the secondary fuel packages that could be involved in this failure?

00:37:33.157 --> 00:37:35.168
How do we understand that cascade?

00:37:35.228 --> 00:37:41.047
What are the ignition issues and how do we think about what the life safety implications of that might be?

00:37:41.347 --> 00:37:47.514
That's I think that's where I want to be clear and really sort of hammer on it and, and.

00:37:48.101 --> 00:37:49.327
that's that's a strong one, man.

00:37:49.356 --> 00:37:50.257
That's that's a good one.

00:37:50.657 --> 00:37:51.528
You're right.

00:37:52.309 --> 00:38:04.860
that's probably the biggest challenge I had when I started playing with, electric vehicle fires and trying to answer the doubts of people related about the car parks and electric fires goes.

00:38:04.889 --> 00:38:16.427
I, when I'm talking about, traditional fires, if you can call um, that you have this, let's say rule of thumb, tenability criteria,    uh, visibility of 10 meters is let's say acceptable.

00:38:16.427 --> 00:38:21.739
You know, what amount of suit that, is, you know, the soot yield of your source.

00:38:22.219 --> 00:38:23.210
can figure that out.

00:38:23.210 --> 00:38:45.445
You can find the plausible answer, if I want to do, electrical fire,  One thing that I noticed is they will have a completely different, uh, heat release rate curve and correct me if I wrong, but it looks like not, exponential is like logarithmic is like very, very sharp.

00:38:45.474 --> 00:38:50.215
It's not a huge release and suddenly dresses by, by a factor of 10 or 20.

00:38:50.215 --> 00:38:52.204
That, that's what I saw, from the measurements.

00:38:52.204 --> 00:38:55.775
And that's what you see in videos when there's like nothing, nothing, nothing, and the huge flame.

00:38:56.188 --> 00:38:57.525
Uh, so we figured that out.

00:38:57.945 --> 00:39:22.192
And we can in a way account for that by, making a very quick, uh, heat release rate, in our simulations, if we traditionally gave four minutes of fire growth to reach a one and a half megawatts of a car simulate a car fire in the car park, traditionally, as we did in past on TNO experimental results from many years ago, for electric vehicle, okay, let's start the simulation with one megawatt initially.

00:39:22.222 --> 00:39:25.612
Like goes from zero to one megawatt immediately.

00:39:26.501 --> 00:39:27.702
course I'm making an error.

00:39:27.731 --> 00:39:32.315
Of course I'm far away a reality, but who in fire science is not.

00:39:32.505 --> 00:39:36.289
so, but yeah, but then that's a way to solve it.

00:39:36.289 --> 00:39:36.559
Yeah.

00:39:36.768 --> 00:39:40.318
But then again, emissions, like do I account what's my.

00:39:41.119 --> 00:39:46.539
What's my, I didn't, I can't even call it a soot yiel what's my smoke yield.

00:39:47.128 --> 00:39:48.778
yeah, I think that's important.

00:39:49.389 --> 00:39:50.949
And, and, how bad is that?

00:39:51.188 --> 00:39:52.168
Am I still Yes.

00:39:52.219 --> 00:39:57.681
10 meters visibility or, will I be very dead seeing for these 10 meters at this point?

00:39:58.119 --> 00:40:05.472
that so frightening because I, I don't even have a good idea how to make it up.

00:40:05.711 --> 00:40:09.222
Like it did with the you know, I love that.

00:40:09.655 --> 00:40:10.074
Work.

00:40:10.074 --> 00:40:15.898
That's been, the RISE folks have done in terms of the battery space and vehicle fire space.

00:40:16.168 --> 00:40:29.675
So when the shipboard fire just a curve, one of the things I wanted to talk to about to my class about was, um, well, let's look at the heat release rate from an ICE versus a, , battery electric vehicle.

00:40:30.155 --> 00:40:33.869
And when we looked at the data sets and I said, okay, let's here.

00:40:34.119 --> 00:40:36.088
I'm showing you the heat release rates.

00:40:36.429 --> 00:40:40.239
they were all between say five and seven megawatt peaks.

00:40:40.628 --> 00:40:44.467
And I said, okay, tell me which one you're more concerned about.

00:40:44.827 --> 00:40:55.050
And we looked at it and we looked at it and we looked at it and we thought, yeah, they look a hell of a lot of like, you know, it's very difficult to discern sort of the one that I'd be more afraid of.

00:40:55.440 --> 00:41:02.650
And so when you think about all the fuel involved in a vehicle, um, lot of stuff.

00:41:02.681 --> 00:41:09.641
That's not necessarily battery and there's lot of stuff to be afraid of that has nothing to do with the battery.

00:41:09.820 --> 00:41:13.090
So now the question in my mind then becomes, okay.

00:41:13.181 --> 00:41:14.951
And I like to think about it this way.

00:41:15.300 --> 00:41:17.190
, we all know that smoke is bad.

00:41:17.251 --> 00:41:22.081
Smoke is bad when fires occur, but are some smoke situation worse.

00:41:22.291 --> 00:41:30.931
So are there things that are being produced toxicity wise than might be worse because there is a battery involved and here's the thing.

00:41:31.081 --> 00:41:34.380
I don't know what the answer to that question is, but I'd like to know.

00:41:34.411 --> 00:41:50.327
And that's what I'd like to put effort into and it's, it impacts obviously, occupants, but it really dramatically also impacts the fire service because when they're fighting these fires, they are intimately involved.

00:41:50.387 --> 00:41:52.827
So while yes, but they're on S CBAs.

00:41:52.858 --> 00:41:53.577
They're on air.

00:41:54.057 --> 00:41:55.197
Yes they are.

00:41:55.347 --> 00:41:56.295
But when you go.

00:41:56.735 --> 00:42:07.956
less than a hundred meters away, you see all sorts of firefighters congregating around equipment and otherwise without air packs on what's happening to them.

00:42:08.226 --> 00:42:11.945
, are there issues in terms of the, over the, is there change?

00:42:11.976 --> 00:42:19.085
I don't, I'm not saying there is, is there a change in the overall toxicity of the smoke because of the amount of batteries that have been involved in it?

00:42:19.405 --> 00:42:33.570
In the U S we just saw an incident, we've seen a few incidents now, and we've seen it around the world where, there have been, evacuation orders that have been placed when fires that included large amounts of lithium-ion batteries were occurred.

00:42:33.869 --> 00:42:37.519
And all those required is it really just, is it essentially a regular.

00:42:38.614 --> 00:42:44.378
Or is there something much worse or different about those, plumes that we need to think about?

00:42:44.378 --> 00:42:58.382
So, there's so many different aspects of this, and again, we're not trying to say that no batteries intrinsically and just are such a bad technology and we should not be going in this direction, but it's a clarification.

00:42:58.382 --> 00:43:05.161
So we understand better when they can be used, how they can be used and how to improve it.

00:43:05.402 --> 00:43:07.521
And just talk about, just, you know, I'm rambling.

00:43:07.521 --> 00:43:10.237
I'm sorry, it's this that's the point of a podcast.

00:43:10.802 --> 00:43:11.041
yeah.

00:43:11.041 --> 00:43:17.588
We're, we're at a pub and, um, I'm drinking my coffee and just given an opportunity, ramble.

00:43:17.648 --> 00:43:28.494
Um, but you, you think about something you think about something else that I, I think that, there has been a lot of fear about which is a flame retardant chemistries.

00:43:28.885 --> 00:43:29.304
Okay.

00:43:29.664 --> 00:43:31.195
So flame retardant.

00:43:31.460 --> 00:43:40.380
have been, you know, in quotes, thrown under the bus as, and some of your guests on this podcast hate flame retards.

00:43:40.389 --> 00:43:41.670
I'm not going to name any names.

00:43:42.280 --> 00:43:44.829
but they say that they don't really do anything.

00:43:44.829 --> 00:43:50.730
And for the, the harm that they potentially have, that it's not worth putting them in place.

00:43:51.266 --> 00:44:05.090
Now, if you look at a airplane, I don't think anybody in terms of safety systems for planes in terms of, you know, the seats and et cetera, we'll say, oh, let's take out the flame retardant because we know that time is critical in those situations.

00:44:05.090 --> 00:44:06.440
And it's incredibly important.

00:44:06.949 --> 00:44:15.260
And then arguably, because of the complexity of flame tardy chemistries, they have gotten much, much better over the last 30, 40 years.

00:44:15.260 --> 00:44:19.010
It's enormous improvements in terms of their overall safety.

00:44:19.143 --> 00:44:19.413
So.

00:44:19.905 --> 00:44:25.485
Has research been important here in terms of identifying the potential issues and problems with it?

00:44:25.635 --> 00:44:26.565
Absolutely.

00:44:26.565 --> 00:44:31.574
I say, has the industry responded by making safer flame retardants?

00:44:31.844 --> 00:44:32.894
Absolutely.

00:44:33.045 --> 00:44:47.295
So I think that the same issue has to happen in terms of why we look at batteries that maybe the first few sort of ways that people put together, battery protection systems really inadequate, but something had to be done.

00:44:47.894 --> 00:44:54.195
And it's incumbent on researchers to understand what the limitations and issues associated with.

00:44:54.195 --> 00:45:07.378
The safety of these systems are point them out and allow industry and other organizations to respond, to require and improve the overall safety of these systems.

00:45:07.617 --> 00:45:12.898
So I think, I think that there were analogies and there are ways that we're going to move along this.

00:45:13.532 --> 00:45:14.603
Yeah, on them.

00:45:14.603 --> 00:45:27.597
What you said, that's the one thing that scares me, the longevity of this technology that, even if we figure out, if you go tomorrow and figure out your noble price, awards the technology to make batteries fireproof or something, Yeah.

00:45:27.632 --> 00:45:42.454
just going to be the new batteries while we have already millions of electric vehicles on the roads old batteries, you know, and from my perspective, people come to me and ask, we design a car parks for electric vehicles from now?

00:45:42.454 --> 00:45:46.833
And I tell them years ago, when you designed the car park, you designed it for electric vehicles.

00:45:46.833 --> 00:45:47.614
He just didn't know.

00:45:47.940 --> 00:45:49.500
and that's not the choice we make.

00:45:49.954 --> 00:46:10.568
so, have to deal  uh, with this in a smart way, not only with the newly produced,  well maybe if you're a manufacturer, you probably are responsible for what you're on the fracture, but us as a safety engineers, delivering safety to the we're also responsible about what's around and how to manage that.

00:46:10.568 --> 00:46:18.110
And I really wonder if there are ways we, manage that or do we just have to hope this, things replaced themselves.

00:46:18.351 --> 00:46:27.164
However, I also read somewhere lately that, the rates of fires in electric vehicles were remarkably low, uh, that there was some insurers claim.

00:46:27.614 --> 00:46:34.110
don't know if how much truth is in that, but it was very, if that is true, that would be very, very nice.

00:46:34.110 --> 00:46:39.599
Maybe you have some knowledge about the statistics of, vehicle battery fires in general.

00:46:40.639 --> 00:46:42.019
oh gosh, I wish I did.

00:46:42.170 --> 00:46:52.516
, uh, you know, every paper we write about that we, point to, other people's papers and it all sort of leads to one paper essentially about what failure rates look like.

00:46:52.637 --> 00:46:56.206
Uh, but like you said, I think insurers are increasingly getting information.

00:46:56.206 --> 00:46:59.836
I mean, we're just as the population and number of electric vehicles has come up.

00:47:00.166 --> 00:47:04.967
They seem to be much safer than, internal combustion engine vehicles in terms of fires.

00:47:04.967 --> 00:47:12.027
I mean, I think that's becoming quite clear that they are less prone to fires than, internal combustion engine vehicles.

00:47:12.356 --> 00:47:15.833
And so now it's like, okay, we're on the right path.

00:47:15.833 --> 00:47:16.914
And that's a good thing.

00:47:17.304 --> 00:47:20.034
There's something else that you said there was really, I thought it was really interesting.

00:47:20.034 --> 00:47:24.704
It's just, you everybody and their grandmother is looking at, what's the next battery technology.

00:47:24.704 --> 00:47:30.673
And so whenever I talked to, protection type companies, I said, well, what about solid state batteries?

00:47:30.673 --> 00:47:34.693
Aren't those supposed to get rid of sort of the safety problems associated?

00:47:35.114 --> 00:47:42.197
And I said, listen, we're increasingly getting higher energy density and higher power density in all these battery systems.

00:47:43.322 --> 00:47:50.402
When failure occurs and the failure does not have to be associated with the cell itself because of all the reasons that you and I've just talked about.

00:47:50.702 --> 00:47:57.632
If there's a fire and your battery is involved with it, how does it contribute or impact that fire evolution?

00:47:57.632 --> 00:47:58.831
So that's question number one.

00:47:59.342 --> 00:47:59.702
Okay.

00:48:00.152 --> 00:48:06.141
Even with solid state batteries, there are so many problems right now with all safety.

00:48:06.141 --> 00:48:09.059
I just read something recently about, there's an electric vehicle company.

00:48:09.059 --> 00:48:11.998
They said we have solid state batteries in our vehicle.

00:48:12.568 --> 00:48:13.739
The range is no different.

00:48:13.739 --> 00:48:19.382
In fact, it's less range than, uh, liquid solvent-based, electrolyte, batteries.

00:48:20.192 --> 00:48:27.119
And it still has the sort of standard electrolyte materials in it because the solid state electric.

00:48:27.838 --> 00:48:29.309
It's brittle it cracks.

00:48:29.338 --> 00:48:30.628
There are all sorts of problems with it.

00:48:30.628 --> 00:48:37.498
So it's really a mixture of the sort of conventional electrolytes and the solid state electrolyte, if you will.

00:48:37.768 --> 00:48:45.958
And so, there's probably a decade before really this just real implementation in this.

00:48:45.958 --> 00:49:01.592
When I talked to, the battery manufacturing people, and even then, as you said, the conventional batteries are commodity and are relatively inexpensive, and those will dominate in a lot of markets and in a lot of applications.

00:49:01.831 --> 00:49:17.989
So in some sense, we're going to be challenged with managing safety systems for new and evolving battery systems, as well as the old systems where, these large companies have dumped billions of dollars into manufacturing capability for these conventional systems.

00:49:17.989 --> 00:49:20.012
So we just have to keep working.

00:49:20.012 --> 00:49:20.101
Yes.

00:49:20.882 --> 00:49:46.829
but after this talk, I'm fascinated because now I see that, though the cell may be an old technology, it a new compartment, giving it a new battery management system, giving it, access to some new, uh, safety features, like active systems that, that could, uh, react it, it Yeah, improve their safety, despite it being, another technology from, uh, from ancient times, like 2013.

00:49:46.829 --> 00:49:47.068
Right.

00:49:48.239 --> 00:49:48.599
So.

00:49:49.898 --> 00:49:50.369
that's right.

00:49:50.798 --> 00:49:51.449
That's it?

00:49:51.628 --> 00:49:53.668
That is your spot on ancient times.

00:49:53.668 --> 00:49:54.119
Indeed.

00:49:55.139 --> 00:49:55.518
Yeah.

00:49:55.648 --> 00:49:57.018
And, and w one more thing.

00:49:57.594 --> 00:49:59.795
also mentioned this smoke, as a problem.

00:49:59.795 --> 00:50:04.784
And I often run into this issue discussing the problem with people.

00:50:05.324 --> 00:50:08.295
like, man, these fires are huge.

00:50:08.668 --> 00:50:10.289
their temperature is insane.

00:50:10.289 --> 00:50:11.909
Like, okay, that's, that's always nice.

00:50:12.389 --> 00:50:12.929
That's great.

00:50:13.628 --> 00:50:16.768
they, they will like destroy the concrete building.

00:50:16.768 --> 00:50:20.789
They burn so ferocious and they can burn for two days and I'm like, holy shit.

00:50:20.789 --> 00:50:28.931
That's like a, that's a noble price because you broke conservation of energy and mass, like, uh, so it's, either.

00:50:29.112 --> 00:50:38.422
And my experience with people who test the batteries is like, if it burns quickly and fiercefully, that's actually okay, because That's a good thing.

00:50:38.742 --> 00:50:44.532
that's, that's the best thing that's going to happen in the Oh, did gosh, you're saying you're so hot.

00:50:44.681 --> 00:50:45.192
It's funny.

00:50:45.192 --> 00:50:47.981
We just had a conversation with our local fire department.

00:50:47.981 --> 00:50:52.599
They were talking about electric vehicle fire and say, Hey, what you know is this really true?

00:50:52.599 --> 00:50:55.688
We need to apply in quotes, copious amounts of water.

00:50:55.719 --> 00:50:56.978
I said, Hey, you know what?

00:50:57.099 --> 00:51:01.608
I think, again, vehicle company X said this, and I really agree with it.

00:51:01.909 --> 00:51:03.978
if there's not an exposure that you're worrying about.

00:51:04.492 --> 00:51:14.101
Let the damn thing burn and let it burn quickly, let it burn quickly so that you don't have to babysit it forever so that you do get rid of all the stuff.

00:51:14.197 --> 00:51:14.766
stay in it.

00:51:14.811 --> 00:51:15.661
Yeah, that's true.

00:51:15.692 --> 00:51:16.021
That's right.

00:51:16.021 --> 00:51:16.382
You got it.

00:51:16.411 --> 00:51:29.358
You got it's exposures and those exposures, not just thermal exposures, it's thermal and emissions exposures, but it's really, it's managing exposures, but the way we might think about it as the safest batteries, a burnt battery.

00:51:29.509 --> 00:51:34.369
So if we can burn it, we're good.

00:51:35.208 --> 00:51:40.931
We no longer have a problem, you know, Hey, which I'm not even gonna speak to the fact that is one of the challenges.

00:51:40.931 --> 00:51:45.938
Is that when an electric vehicle or one of these appliances burn, there are a lot of cells in there dead.

00:51:46.414 --> 00:51:47.182
Go off.

00:51:47.472 --> 00:51:48.443
It's your point too?

00:51:48.443 --> 00:51:52.552
You said that she said, okay, if five cells go off, isn't that safe?

00:51:52.612 --> 00:52:00.083
Well, it's safe for somebody, but it might be safe, unsafe for somebody else who has to get those five cells out or manage that battery.

00:52:00.083 --> 00:52:04.012
Now that several cells have failed in it and others are compromised.

00:52:04.012 --> 00:52:08.182
So we don't know how compromised the other cells are.

00:52:08.182 --> 00:52:10.583
And that becomes a longer-term issue.

00:52:10.583 --> 00:52:14.827
But that's, there's going to be a whole industry that comes up to deal and manage with those issues.

00:52:15.467 --> 00:52:18.166
burns batteries is very difficult.

00:52:18.197 --> 00:52:19.146
Uh, Yeah.

00:52:19.547 --> 00:52:32.536
tell you how we do it, but I can just say that I would just, I can just say that, that having, having, uh, you know, fire resistance furnaces a lot in some things like, I like it.

00:52:32.597 --> 00:52:32.987
yeah.

00:52:32.987 --> 00:52:33.407
like it.

00:52:33.407 --> 00:52:34.067
I agree with you.

00:52:34.157 --> 00:52:34.817
I agree with you.

00:52:34.954 --> 00:52:37.733
when we, when you do this battery tests, like the rule is Yeah.

00:52:37.748 --> 00:52:39.007
leave them there for a week.

00:52:39.007 --> 00:52:52.275
And, uh, after a week there's, they're more or less, it would be very awkward if Uh, happened the week after and on the exact day, when you chose to pick it up, I would act, I would then consider it an act of God and I would just live with it.

00:52:54.014 --> 00:53:02.818
So that's, that's, the point of view, but, it should that, burns batteries, safer battery yeah, the unburned one.

00:53:03.628 --> 00:53:04.148
absolutely.

00:53:04.257 --> 00:53:06.871
discussed this with respondent, Yes.

00:53:06.992 --> 00:53:08.371
They need to know.

00:53:08.402 --> 00:53:10.291
There are two kinds of threads.

00:53:10.291 --> 00:53:17.041
They will be exposed to one being a huge fire to which they are used to word.

00:53:17.041 --> 00:53:18.041
The challenge Okay.

00:53:18.061 --> 00:53:21.211
toxicology because the fire will be there as they know it.

00:53:21.572 --> 00:53:28.442
It's just gonna to be a little different chemical composition of the smoke in which Yes, yes, anyway.

00:53:28.842 --> 00:53:29.862
yes, exactly.

00:53:30.108 --> 00:53:35.994
that's option a and option B if something weird is happening, it's, it's puffing, it's, Yes.

00:53:36.264 --> 00:53:40.692
smoking his gun that that's a completely different scenario.

00:53:41.112 --> 00:53:48.492
And then maybe I can imagine where you would have to isolate this vehicle or this battery, even four days.

00:53:49.052 --> 00:53:49.322
yeah.

00:53:49.382 --> 00:53:51.001
And let's say option C.

00:53:51.001 --> 00:53:53.882
And so, whether it's confined or unconfined becomes the issue.

00:53:53.882 --> 00:53:57.179
And so, we go to the surprise arson incident and other incidents.

00:53:57.179 --> 00:54:01.500
It's just that, I conventionally have dealt with non pre-mixed flames.

00:54:01.530 --> 00:54:04.146
I deal with, you know, natural burning systems.

00:54:04.329 --> 00:54:07.269
but in another life I did work on premixed lengths.

00:54:07.269 --> 00:54:11.199
And so the, the challenges becomes that explosions can occur.

00:54:11.199 --> 00:54:17.650
I mean, so we're not just, we're not just, so when does this thing becomes under ventilated, if it's confined, it's becomes under ventilated.

00:54:18.465 --> 00:54:24.925
The products are not just CEO that we might see in normal, under ventilated combustion systems.

00:54:25.105 --> 00:54:27.744
We had hydrogen and we have hydrocarbons in there.

00:54:28.135 --> 00:54:31.045
And so the explosion hazard is real.

00:54:31.045 --> 00:54:39.295
And so we have to start thinking about explosion protection in a serious way for our confined or partially confined battery systems.

00:54:40.023 --> 00:54:42.519
I know the last one we did blew up.

00:54:42.875 --> 00:54:44.494
Yes, yes, yes.

00:54:44.570 --> 00:54:46.677
Nah, but  wow man.

00:54:46.719 --> 00:54:48.010
it's an hour already.

00:54:48.099 --> 00:54:49.344
I told you like Yeah.

00:54:49.389 --> 00:54:53.385
presentations are boring and long, but when I write, oh, this is great.

00:54:53.469 --> 00:54:54.416
like, it's good.

00:54:54.416 --> 00:54:55.197
So quickly.

00:54:55.681 --> 00:54:56.492
This is great.

00:54:56.907 --> 00:54:57.976
Any famous last words?

00:54:59.731 --> 00:55:00.722
This was a lot of fun.

00:55:00.916 --> 00:55:04.853
uh, no, but seriously, let's, let's close it up  with some statements.

00:55:04.853 --> 00:55:07.853
So I think I share your mindsets.

00:55:07.943 --> 00:55:10.463
I'm not scared of this technology.

00:55:11.364 --> 00:55:25.570
It's a new technology, relatively new, we're on the front of making it safer, which does not mean it's unsafe and there's lots of smart people working on it and, trying to, make it better.

00:55:25.630 --> 00:55:26.079
Right.

00:55:26.304 --> 00:55:26.753
hopeful.

00:55:26.813 --> 00:55:27.414
I am.

00:55:27.414 --> 00:55:28.313
I'm very hopeful.

00:55:28.313 --> 00:55:31.324
I think that you, you summed it up perfectly.

00:55:31.777 --> 00:55:36.967
we're moving into, there's nothing we can do to change this trajectory.

00:55:36.967 --> 00:55:41.603
I don't think because it's incredibly required and, we're just trying to improve it.

00:55:41.634 --> 00:55:42.083
That's all.

00:55:42.083 --> 00:55:51.449
So I'm, I'm very hopeful that all of the effort that you and others and, we're all trying to collectively do in this space.

00:55:51.469 --> 00:55:53.329
we'll create safer systems.

00:55:53.679 --> 00:55:54.369
Yeah, man.

00:55:54.369 --> 00:55:54.789
Thanks.

00:55:54.860 --> 00:55:56.469
This was, this was excellent.

00:55:56.500 --> 00:55:57.519
I thought she was going to be excellent.

00:55:58.070 --> 00:56:02.893
He didn't believe that Ah, this is I really enjoyed it.

00:56:02.893 --> 00:56:12.043
It was a great pleasure having you in the fire sane show and I'm sure I'm going to see you here again, I hope to I hope so you in Austin as well.

00:56:12.463 --> 00:56:13.983
Uh, that would be wonderful.

00:56:14.014 --> 00:56:15.034
That would be wonderful.

00:56:15.072 --> 00:56:24.945
th there's supposedly some pickle challenge, posed was the better way to eat a pickle like Polish way, super sour or Texas way fried.

00:56:25.184 --> 00:56:28.244
So we were going to settle that in the battle.

00:56:29.409 --> 00:56:31.239
And it should be, it should be an Austin.

00:56:31.239 --> 00:56:32.679
We'll we'll do it in Austin.

00:56:32.679 --> 00:56:33.820
We'll do in Warsaw.

00:56:34.059 --> 00:56:34.849
We'll do it all over.

00:56:36.135 --> 00:56:36.974
Thank you so much.

00:56:37.545 --> 00:56:37.844
thanks.

00:56:37.960 --> 00:56:38.409
Absolutely.

00:56:38.409 --> 00:56:39.280
Thank you for doing this.

00:56:39.769 --> 00:56:40.960
See you around Take care.

00:56:41.199 --> 00:56:41.530
Goodbye.

00:56:42.422 --> 00:56:43.112
And that's it.

00:56:43.413 --> 00:56:44.373
Hope you've liked this.

00:56:44.822 --> 00:56:48.963
I've spent one hour talking to DK and he's my best friend now.

00:56:49.503 --> 00:56:50.822
It was an amazing episode.

00:56:50.882 --> 00:56:52.893
So enthusiastic, so happy about.

00:56:52.967 --> 00:56:56.864
The research he's doing and so optimistic towards the future.

00:56:56.954 --> 00:56:59.293
And I think that's what I really needed.

00:56:59.804 --> 00:57:02.744
And optimistic view towards the fire.

00:57:02.744 --> 00:57:05.563
See future of lithium-ion battery technology.

00:57:05.914 --> 00:57:08.884
Because it is a part of our future.

00:57:09.393 --> 00:57:10.773
Whether we like it or not.

00:57:10.893 --> 00:57:14.193
And, and it's great that smart people are working.

00:57:14.224 --> 00:57:17.088
To make this technology as safe as possible.

00:57:17.688 --> 00:57:21.797
And as we mentioned in the episode, It does not mean it's not safe.

00:57:22.458 --> 00:57:28.728
It means we are still seeking solutions, how to tackle problems better, how to identify problems better.

00:57:29.057 --> 00:57:33.318
How to apply solutions at many layers of the protection within the battery.

00:57:34.157 --> 00:57:35.447
And with all this.

00:57:35.867 --> 00:57:36.827
Just make it.

00:57:37.128 --> 00:57:38.507
Better more accessible.

00:57:38.958 --> 00:57:41.782
.

00:57:38.958 --> 00:57:42.952
Easier to replace, easier fire risk perspective.

00:57:43.431 --> 00:57:48.101
So I hope you've enjoyed this optimistic view on batteries.

00:57:48.132 --> 00:57:51.402
And you can share this with all of your friends who are.

00:57:51.577 --> 00:57:54.128
A little scared of the technology.

00:57:54.847 --> 00:57:58.177
And maybe they will give a little more enthusiastic about it.

00:57:58.688 --> 00:58:00.728
And with this optimistic.

00:58:00.998 --> 00:58:03.298
accent I would love to close this episode.

00:58:03.809 --> 00:58:06.059
Thank you so much for being here and listening.

00:58:06.628 --> 00:58:08.849
And I hope to see you next week.

00:58:08.909 --> 00:58:11.489
Another great interview coming your way next Wednesday.

00:58:11.969 --> 00:58:12.418
Cheers.

00:58:12.478 --> 00:58:12.748
Bye.

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