044 - Improving fire safety of battery systems with Ofodike Ezekoye
Since Episode 6, the fire safety of battery systems was not very much visible in the show - a good time to change that! And we do this with a true legend of fire safety - Ofodike Ezekoye. In the last year, I have learnt a lot about battery systems, which did not make me more afraid. Entirely opposite - the more I know, the more confident I am in fire science and engineers finding solutions for any outstanding issues with this emerging technology. In this episode, we go through the challenges at different scales of the battery system - from the chemistry of cathode, anode and electrolyte, through challenges in manufacturing and quality control, battery management systems up to the scale of whole off-grid systems. Each presents unique challenges. Each is a place of ongoing innovation.
But the most important, IMHO, is to look at the threat holistically. Even if we remove all the intrinsic dangers of energy storage, the batteries may still be there when a fire starts for other reasons... We may be able to contain the 'thermal' threats, but are we looking for solutions to the smoke? And what to do with billions of already existing batteries that we deal with everywhere in our lives... All these questions got answered here, so you don't want to miss this episode!
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WEBVTT 00:00:00.758 --> 00:00:01.417 Hello, everybody. 00:00:01.417 --> 00:00:03.787 Welcome to the Fire Science Show session 44. 00:00:04.238 --> 00:00:05.527 The legend after legend. 00:00:05.557 --> 00:00:10.598 I'm pretty blessed with the guests in lineup, in the podcast in the last weeks. 00:00:11.108 --> 00:00:13.430 And it's not a other today. 00:00:13.577 --> 00:00:21.998 Enough to say that my today's guests along with, , Professor Babrauskas and Professor Horn alltogether they've published. 00:00:20.768 --> 00:00:21.998 almost 500. 00:00:22.161 --> 00:00:23.060 Academic papers. 00:00:23.091 --> 00:00:25.580 And I find that insane as an academic. 00:00:26.192 --> 00:00:29.102 Anyway, let's go with the big reveal quickly. 00:00:29.346 --> 00:00:35.985 My today's guest is professor Ofodike Ezekoye From the University of Texas at Austin. 00:00:36.405 --> 00:00:40.515 And DK is an expert in battery fire safety. 00:00:40.996 --> 00:00:45.496 And I cannot imagine a better place working on the fire safety of lithium-ion batteries than. 00:00:45.716 --> 00:01:00.109 And university of Texas Austin where the thing actually got kind of invented where professor John Goodenough Is lecturing and, yeah, he actually got the Nobel prize for inventing this type of battery. 00:01:00.649 --> 00:01:01.069 So. 00:01:01.371 --> 00:01:06.432 Great place to study battery, fire safety and the great research and going in there. 00:01:06.876 --> 00:01:14.587 I went into this interview with some tough questions about the safety of battery, his thermal runaways and things like that. 00:01:15.126 --> 00:01:19.621 But in fact, it ended up as quite reassuring talk with a good friend. 00:01:20.162 --> 00:01:25.902 About what's there to find out how complexity strikes at this. 00:01:25.932 --> 00:01:26.382 Again. 00:01:26.712 --> 00:01:30.432 And how smart people are battling for the safety of batteries. 00:01:30.981 --> 00:01:32.272 I think we've ended up with. 00:01:32.498 --> 00:01:33.539 Quite well-rounded. 00:01:33.778 --> 00:01:35.549 Discussion covering. 00:01:35.938 --> 00:01:38.519 Many many aspects of the battery fire safety. 00:01:38.519 --> 00:01:43.558 And I can tell you I'm I'm reassured I am a little less scared now. 00:01:44.009 --> 00:01:46.138 And more optimists. 00:01:46.649 --> 00:01:50.912 Towards a new solutions that will come for the safety of this technology. 00:01:51.149 --> 00:02:03.512 And yeah, knowing that the batteries are as a hot topic for the podcast as the wood in fire . I'm absolutely certain, I don't need to hype this anymore and that I already go to your attention and trust me. 00:02:04.141 --> 00:02:16.489 If you enjoy listening scientists who are absolutely passionate about what they're doing they're happy and enthusiastic about the research and about sharing it with everyone else. 00:02:16.998 --> 00:02:18.709 This is an episode for you. 00:02:18.769 --> 00:02:20.299 So I really hope you enjoy. 00:02:20.929 --> 00:02:22.429 So let's not prolong this anymore. 00:02:22.489 --> 00:02:24.709 Let's spend in show and jump into the episode. 00:02:48.639 --> 00:02:49.389 Hello everybody. 00:02:49.399 --> 00:02:52.389 I'm here today with Professor DK Ezekoye. 00:02:52.389 --> 00:02:53.169 Hello, DK. 00:02:53.229 --> 00:02:54.818 Great to have you in the show. 00:02:55.066 --> 00:02:55.540 Thank you. 00:02:56.308 --> 00:02:56.949 Welcome. 00:02:56.998 --> 00:02:57.989 Looking forward to it. 00:02:58.341 --> 00:03:07.800 I'm even more before the show, you told me that, for the cold chilly Texas, winters, you were thinking about building up some PV installation and batteries. 00:03:07.860 --> 00:03:09.121 Aren't you scared of that? 00:03:11.200 --> 00:03:12.371 Absolutely not. 00:03:12.627 --> 00:03:20.200 I am an advocate of this type of technology of, electrification generally, and certainly in terms of, battery systems. 00:03:20.561 --> 00:03:33.300 And so, last year, February, uh, we had a winter event here in Austin, which took out our electricity and, took out quite a bit of, infrastructure issues in, in terms of utilities. 00:03:33.651 --> 00:03:41.373 Even before then, I was very much planning on getting a photo-voltaic, panels and also battery energy storage. 00:03:41.674 --> 00:03:46.653 And so that obviously just in my mind, it's solidified the need to do this. 00:03:46.653 --> 00:03:54.463 And for all of us to, in some sense, capability on hand for a renewable energy generation and storage. 00:03:54.644 --> 00:03:56.683 So I'm very much looking forward to it. 00:03:56.931 --> 00:04:04.510 And as I said earlier, , my reasons to do what I do are to improve the overall safety of these types of systems. 00:04:04.510 --> 00:04:07.031 So it's not, , an indictment of the systems. 00:04:07.031 --> 00:04:11.480 It's not say that the systems themselves are, somehow intrinsically unsafe. 00:04:11.760 --> 00:04:15.131 It's just that, we need to improve the overall safety of these systems. 00:04:15.131 --> 00:04:17.050 So more of us can comfortably use them. 00:04:17.415 --> 00:04:20.302 that sounds like not a bad task you've set for yourself. 00:04:20.942 --> 00:04:30.076 I find the word safety quite a difficult in this matter, you know, because, I look into Internet, the net people are terrified of the technology. 00:04:30.076 --> 00:04:43.108 Like literally terrified to the level, uh, where we're banning in many countries, electrical vehicles in the car parks, and, in Poland we had a nice movement where they formated. 00:04:43.857 --> 00:04:55.699 Mandatory to provide, sufficient electrical power to power, at least a plug-in hybrid, every parking spot in your car park, and this law was put in place. 00:04:55.699 --> 00:05:07.428 So the buildings are now built with these types of installations, but now the fear has came here now, as we have these installations, we are thinking maybe we should ban the electric vehicles in the car parks. 00:05:07.788 --> 00:05:12.738 So it's kind of crazy that we've went all the way to invest in this. 00:05:12.738 --> 00:05:18.309 And now, because of fear, not facts, not science, not proof because of fear. 00:05:18.309 --> 00:05:21.908 We are rethinking that will not me and the government. 00:05:21.908 --> 00:05:27.622 Then not I'm in no way connected to them, but, uh, I would despise this connection. 00:05:27.851 --> 00:05:48.661 Anyway, uh, this safety, you what makes this battery system feel unsafe to people people are not scared of gasoline with heat of combustion of 46 megajoules per kilogram, which you contain like 50 liters on American, it would be like 20 gallons your car. 00:05:48.661 --> 00:05:52.675 Why we are not scared of riding on this bomb and we're scared of battery. 00:05:52.675 --> 00:05:53.964 What made us do that? 00:05:54.156 --> 00:05:55.932 oh, you know, that's a, great question. 00:05:56.142 --> 00:05:56.502 And. 00:05:57.612 --> 00:06:01.093 The issue in general, it's the risk perception versus actual risk. 00:06:01.302 --> 00:06:09.060 And we, in general, as humans are horrible with really understanding risk but risk perception is easy. 00:06:09.449 --> 00:06:21.846 And so with probably any new technology and especially with the way that we get information these days, that it's very easy to trigger, very irrational fears. 00:06:21.997 --> 00:06:32.894 And it's in some sense, and maybe I'm guilty of it too, because of just, the fact that we research it might make people think, oh my gosh, these systems are unsafe. 00:06:33.163 --> 00:06:35.141 Well, everything is unsafe, right? 00:06:35.146 --> 00:06:36.107 this is part of the issue. 00:06:36.137 --> 00:06:38.956 There's nothing that is absolutely safe. 00:06:39.404 --> 00:06:40.829 Well, that's entropy man. 00:06:41.697 --> 00:06:42.266 Right. 00:06:42.326 --> 00:06:42.687 Right. 00:06:42.687 --> 00:06:54.507 So the way, the only way that we can solve some of the really unsafe things, climate change global warming is to use renewable energy and to use energy storage. 00:06:54.536 --> 00:07:04.074 That is the way that we're going to deal with some of these, incredibly unsafe situations that we should be afraid of and fearful of. 00:07:04.403 --> 00:07:21.713 And from that perspective, I think that there's a responsibility for technologists who are working in the safety area to be very clear about why the circumstances and issues in which we're looking at safety of particular systems. 00:07:21.894 --> 00:07:31.824 And again, it's not that these things are, it's not, fear-mongering, it's not that these things are always unsafe and that we should, as a society, stay away from these types of technologies. 00:07:31.824 --> 00:07:34.163 But in fact, it's that, how do we. 00:07:34.629 --> 00:07:38.408 incentivize or move forward in terms of these technologies? 00:07:38.858 --> 00:07:41.649 Because we're improving the overall safety of these systems. 00:07:41.649 --> 00:07:46.298 And so I'd like to think about the work that I do in the battery area as. 00:07:47.574 --> 00:07:55.043 Create safer systems, trying to understand these systems better so that we can design against failures because failures to just happen. 00:07:55.314 --> 00:08:02.117 And we've seen the improvements in safety of, internal combustion engines over the last hundred years. 00:08:02.357 --> 00:08:09.706 Uh, we could argue that when they were first introduced, I mean, a lot of the safety systems that we take for granted now certainly were not implemented there. 00:08:09.836 --> 00:08:21.411 So why wouldn't we expect that there would be improvements in safety for whether it's electric vehicles or electric, storage systems within homes, within businesses at utility sites? 00:08:21.411 --> 00:08:24.831 So the goal of course, is to overall improve safety. 00:08:24.891 --> 00:08:28.040 And there's just so little data that currently exists. 00:08:28.071 --> 00:08:35.691 But I think that between the research and unfortunately incidents that occur, we're going to improve the overall safety of these. 00:08:36.251 --> 00:08:42.892 In fact, if you would look at it at the societal level, I'm obviously not a, not such a researcher. 00:08:42.892 --> 00:08:46.731 I think you're not either, but you've experienced blackouts last winter. 00:08:46.731 --> 00:08:47.032 Right. 00:08:47.091 --> 00:08:48.086 Uh, and, No. 00:08:48.086 --> 00:08:56.905 Yeah, this type of grid where everyone has a battery, for themselves, that would be probably a life changing experience at that moment. 00:08:56.905 --> 00:08:59.231 There, the, absolutely. 00:08:59.596 --> 00:09:13.706 uh, how big the benefit of this technology can be, it Oh yeah, And you, you've mentioned the energy generation and storage, like of the new, new types of fuels we're using, uh, wind solar, they're periodic at best and exactly. 00:09:13.706 --> 00:09:15.379 if you're nasty to them, Yeah. 00:09:16.269 --> 00:09:16.509 you yeah. 00:09:16.563 --> 00:09:19.443 need, you need to way to store that we need to solve that. 00:09:20.195 --> 00:09:26.918 I also observed this movement that the buildings should be like net zero or possibly positive energy generation. 00:09:26.918 --> 00:09:34.479 Like would be great if you're building the create more energy than it consumes, that would be the best building and like that exists today. 00:09:35.168 --> 00:09:37.828 And so it's something we would like. 00:09:38.129 --> 00:09:43.484 And again, it's something we're afraid of, you know, it's it's, you cannot have both, have to decide. 00:09:43.851 --> 00:09:49.501 and the more I learn about the systems, the less I am afraid of them. 00:09:49.501 --> 00:09:52.501 And I think that's probably the correct direction. 00:09:52.711 --> 00:09:55.710 Well, I guess oh, no, I completely agree. 00:09:55.769 --> 00:10:00.309 And so, part of it is how do we take industry? 00:10:00.309 --> 00:10:07.809 How do we take manufacturers from a position of being afraid of even acknowledging that there are safety concerns? 00:10:08.855 --> 00:10:15.125 To a point of acknowledgement of those safety concerns and with a goal of improvement. 00:10:15.424 --> 00:10:30.274 And so it's a delicate balance that they have to walk because if on the one hand they talk about safety concerns in their systems, and then it feeds into this perceived risk and perceived safety fears of the general public. 00:10:30.575 --> 00:10:31.384 Exactly. 00:10:31.384 --> 00:10:45.099 So that's, so from their perspective, and we've talked to, you know, lots of industrial concerns, about, well, we'd like to help you understand the safety of your battery systems and why battery systems. 00:10:45.099 --> 00:10:54.698 I mean, from again, the system level, whether to containerize battery system, to whether it's a particular type of appliance and the. 00:10:55.330 --> 00:11:00.397 Response you typically get is our systems are safe and there are no problems with our system. 00:11:00.756 --> 00:11:04.417 And as a researcher, who's looking at some of these safety issues. 00:11:04.537 --> 00:11:14.586 We know that's not true, that they can't possibly always be safe there considerations for I, the one I always think about is listen, fires have happened forever. 00:11:14.586 --> 00:11:16.326 Fire is always going to happen. 00:11:16.326 --> 00:11:20.799 Whether we go to space, whether we're on the sea, fire follows us. 00:11:20.879 --> 00:11:23.210 and so fires will happen. 00:11:23.480 --> 00:11:29.210 And the issue is that energy storage systems will be somewhere where a fire occurs. 00:11:29.210 --> 00:11:42.583 It may not be the cause of the fire, but it will be somewhere where a fire occurs, given that what can we do to make sure that your system doesn't add to the consequences of that fire that we know is going to occur? 00:11:42.764 --> 00:11:44.894 So, and so that's sometimes. 00:11:45.719 --> 00:12:05.172 Makes them feel a little bit better because it's an awareness that we're not saying that it's their system necessarily, that's the cause of the problem, but that we as researchers and safety science, and in particular on fire issues, we have a wearness about the frequency and intensity consequences of fire generally. 00:12:05.442 --> 00:12:13.091 And we understand how other fuel packages can get involved in, can exacerbate the fire consequences and fire impacts. 00:12:13.302 --> 00:12:19.432 So we're trying to help them in some sense, alleviate some of these consequences, some of these negative consequences. 00:12:19.552 --> 00:12:28.995 So it's a delicate balance then of taking manufacturers and having them acknowledge issues and try and improve the safety of their systems. 00:12:29.315 --> 00:12:38.615 making sure that the general public understands that the systems are generally safe and this is in fact, the future and providing guidance to regulators and. 00:12:39.365 --> 00:13:06.341 Permit authorities having jurisdiction, who are decision makers about how to sort of balance this and in their sense of, how do we PR you know, your example, how do we allow EVs in parking garages with the best available safety systems today and what are going to be improvements in safety systems tomorrow, and how do we retrofit or move those forward? 00:13:06.981 --> 00:13:11.361 That, that sort of, that's a, it's a lot of, it's a lot of work that we have to do for that, huh? 00:13:11.849 --> 00:13:17.729 Yeah, it seems so it seems like a roadmap to safety is needed or maybe even not to safety. 00:13:17.729 --> 00:13:25.351 Like it's a roadmap to improve from position A to position B to position C, doesn't mean that position A is unsafe. 00:13:25.371 --> 00:13:27.501 It's just position B can be safer, right? 00:13:27.761 --> 00:13:28.121 Yes. 00:13:28.192 --> 00:13:34.761 be calling it a road to safety that we are unsafe in some way at this point, which may not necessarily be true. 00:13:35.255 --> 00:13:36.692 For me, a very way. 00:13:37.273 --> 00:13:45.878 As someone looking around, at this field, which is very alien to me, I'm like, I did a lot of things in, in compartment fires. 00:13:45.888 --> 00:13:47.227 I've burned buildings. 00:13:47.317 --> 00:13:48.548 I've did a lot of smoke. 00:13:48.561 --> 00:13:50.541 but men batteries are alien to me. 00:13:50.600 --> 00:13:51.410 They are alien. 00:13:51.561 --> 00:13:52.850 I don't understand them. 00:13:54.591 --> 00:13:57.230 I know they have power and they serve my laptop. 00:13:57.890 --> 00:14:00.053 but, I'm not an expert on that. 00:14:00.053 --> 00:14:07.941 So I wondered We probably need solutions on all levels, but the level of complexity of this thing is really huge. 00:14:08.380 --> 00:14:22.008 you have the level of chemistry your kathode, anode and I know that the fluid inside, the chemical compounds and reactions that happen inside the battery, have the battery itself as a single cell, element, a single pouch. 00:14:22.668 --> 00:14:29.327 is an ecosystem on its own with its heat transfer with its with its capacity, right? 00:14:29.658 --> 00:14:35.567 Then you start merging them together, creating an environment when you've connected multiple of the. 00:14:36.227 --> 00:14:38.477 Not necessarily, well, you changed the risk. 00:14:38.538 --> 00:14:46.280 The question is how much do you, did you just add all the risk of them or have you created a system with exponentially higher risk than the cell individually? 00:14:46.760 --> 00:14:51.823 then again, I've also learned that, don't just put a bunch of them into a car. 00:14:51.823 --> 00:14:53.653 You need a system that manages them. 00:14:53.653 --> 00:15:08.734 So need to build a compartment for them or, or some, some case in which they're stalled, which is the technology need the battery management system that makes sure they're operating at the correct parameters that manages the charging and discharging and so on. 00:15:09.274 --> 00:15:15.508 then you, you have the whole system which would be a car, a building, or the benefactor of the energy of this system. 00:15:16.018 --> 00:15:26.583 you have this many level of complexities and I see Potential challenges and, also, but then will, opportunities for improving the safety at each of these levels. 00:15:26.583 --> 00:15:33.418 So please tell me at what level you act and do you think, biggest improvements can come from? 00:15:34.107 --> 00:15:40.163 Which someone can see, the one you act oh, so, I love what you just said for a lot of reasons. 00:15:40.163 --> 00:15:42.923 And it goes back to a little bit of what we were saying before. 00:15:43.917 --> 00:15:47.876 Technology in general and technological systems are getting more complex. 00:15:47.937 --> 00:15:50.366 So that's something that's absolutely occurring. 00:15:50.817 --> 00:15:55.136 The pace at which these things are changing and evolving is increasing. 00:15:55.197 --> 00:15:56.277 The rate is increasing. 00:15:56.277 --> 00:15:59.126 So we're getting increasing complexity. 00:15:59.157 --> 00:16:04.586 We're getting increasing complexity faster, and we are on the safety side. 00:16:04.586 --> 00:16:13.244 We're in some sense, the, boundaries, the, reigns to try to make sure that we manage the overall safety of these incredibly complex systems. 00:16:13.724 --> 00:16:35.326 And so these battery systems are one of the first, I'm not saying to say that the only, but they're one of the early sort of testing systems for us as safety, technologists, safety, engineers, safety profession, to try to really figure out how do we, allow this transition to occur in a way that makes sense. 00:16:35.777 --> 00:16:36.163 So. 00:16:36.188 --> 00:16:44.298 I see myself as really trying to impact the life safety and property protection issues associated with batteries. 00:16:44.719 --> 00:16:50.749 And the issue though becomes that I feel to do that appropriately inadequately. 00:16:50.839 --> 00:17:01.139 I need to understand this system because of the complexity that you mentioned, as an academic, I benefit from working with really smart people who can teach me about these systems. 00:17:01.139 --> 00:17:08.088 So my, sort of goal is to learn about this and to communicate this and to improve the overall safety of these systems. 00:17:08.814 --> 00:17:10.884 I, we can't do these things alone. 00:17:10.884 --> 00:17:13.901 We, as we discussed, we work in communities. 00:17:14.320 --> 00:17:15.820 we tell stories, we talk. 00:17:16.090 --> 00:17:28.340 And so from that perspective I've asked my students and my collaborators, how to bring me up to speed in terms of our research, by looking at things as sort of. 00:17:29.016 --> 00:17:34.169 Far from what I do as for example, electrical circuit modeling of cells. 00:17:34.259 --> 00:17:39.598 So I want to understand fundamentally how does a battery work? 00:17:39.659 --> 00:18:24.093 And so, uh, I've had students working on, uh, pseudo two D models of cells, of circuit models of cells, of all sorts of different models of cells, so that I can understand the electrical performance of cells and what issues cell researchers are interested in for that, that gives me some insight into what the challenges are at that scale and from a modeling perspective, because that's going to be important as we start to think about multiple cells or as we start to think about even layers of the sort of, uh, single layer cell systems, then at like increasing complexity, then we ask questions about what happens if we have cell failure? 00:18:24.123 --> 00:18:25.083 How do we think of. 00:18:25.613 --> 00:18:31.343 Electrical performance as for example, initiating thermal considerations. 00:18:31.343 --> 00:18:50.633 And so just even in the normal cycling of a cell there's heat generation, and we appreciate that, we know that now the question is can this heat generation itself iManage or is there some possibility of it cascading into a thermal and thermal chemical reaction rate that would occur. 00:18:50.932 --> 00:18:53.002 And so understanding that is important. 00:18:53.063 --> 00:19:03.982 And again, I'm not a chemist, but how do we think about parameterizing low order models that can allow us to understand how this reaction process occurs? 00:19:04.282 --> 00:19:12.803 Again, with an eye at consequence scale at largest largest scales for us, which might be the building or container or the electric vehicle. 00:19:13.853 --> 00:19:18.728 And so now again, Understanding, for example, cell to cell propagation. 00:19:18.728 --> 00:19:28.199 Now it's a little bit looking more like what we normally do in terms of heat, transfer, physics, mass transfer issues, solid fire Yeah, exactly. 00:19:28.469 --> 00:19:29.128 Exactly. 00:19:29.128 --> 00:19:35.068 So it's looking more like what we do, but it's a parameterization of the kinetics associated with that. 00:19:35.489 --> 00:19:36.209 I would argue. 00:19:36.209 --> 00:19:44.159 That's not that different from what we, as fire scientists, researchers have done for decades in terms of looking at condensed phase systems. 00:19:44.429 --> 00:19:47.608 My gosh, condensed phase, any condensed systems, incredibly complex. 00:19:47.608 --> 00:19:51.719 I say, Hey, talk about wood or polyurethane or anything. 00:19:51.838 --> 00:19:53.308 And you tell me that that's simple. 00:19:53.338 --> 00:19:59.048 That's there's nothing simple about understanding the degradation of these condensed phase systems. 00:19:59.424 --> 00:20:07.278 now with all the decades and number of researchers, who've put so much energy and intellectual effort into that. 00:20:07.519 --> 00:20:11.019 We have a better understanding of how these systems degrade and. 00:20:11.824 --> 00:20:24.334 Both in terms of the toxicity in terms of the energy release rates, in terms of all these factors, what happens with these complex engineered systems, like Polyurethane now, and we've devised tools. 00:20:24.364 --> 00:20:26.554 You had Vyto Babrauskas on earlier. 00:20:26.794 --> 00:20:32.673 We've devised tools to characterize and measure the energy release rate of the systems. 00:20:32.763 --> 00:20:35.314 The, again, the toxicity chemicals, et cetera. 00:20:36.094 --> 00:20:41.157 We haven't developed that to the same extent for a new technology. 00:20:41.428 --> 00:20:41.824 Like. 00:20:42.096 --> 00:20:47.625 a lithium-ion cell, there are tools out there, but maybe we don't understand them or wavy. 00:20:47.625 --> 00:20:52.726 We haven't fashioned them into a way to really understand some of the issues in terms of propagation. 00:20:52.726 --> 00:20:57.705 And we're in the early days of characterizing and really understanding those types of details. 00:20:58.096 --> 00:21:06.135 But arguably once we do understand that and we're able to parameterize these lower order models, then we can think about what propagation looks like. 00:21:06.135 --> 00:21:08.296 What rate of gas release looks like? 00:21:08.596 --> 00:21:12.465 What rate of energy release looks like for these types of components. 00:21:12.826 --> 00:21:15.645 And then we stitch it together at the higher level. 00:21:15.945 --> 00:21:21.976 Now you said also that the complexity is not just associated with the cells and that's absolutely true. 00:21:22.246 --> 00:21:29.002 The complexity is that it's a system and it's a software based system, which is increasingly true. 00:21:29.363 --> 00:21:31.373 So there's a battery management system. 00:21:31.373 --> 00:21:35.692 There are all sorts of other protection systems often. 00:21:36.558 --> 00:21:41.066 Some chip or in some sort of logic sequence that's associated with that. 00:21:41.425 --> 00:21:43.465 And unfortunately bugs can occur. 00:21:43.575 --> 00:21:49.553 You can buy a BMS for as cheap as $15, and you get what you pay for. 00:21:49.762 --> 00:22:01.645 So there are really strong battery management systems that no matter how, flawed a particular cell might be, that can overcome the flaws of cell. 00:22:02.125 --> 00:22:04.300 it and Yeah. 00:22:04.330 --> 00:22:05.290 Yeah, exactly. 00:22:05.290 --> 00:22:17.070 They can balance out some of the issues between poorly performing cells and better performing cells because natural variability exists in terms of sort of cells from a manufacturing perspective or otherwise. 00:22:17.580 --> 00:22:35.611 And then on top of it, we may have other components in the system, whether it's an inverter or other sort of traditional electrical mechanical systems, any of these can possibly fail on top of it because of failures, we have sensors. 00:22:35.641 --> 00:22:39.661 And so the sensors could initiate some sort of activity. 00:22:40.288 --> 00:22:44.758 one would say that, oh, that would be crazy for a sensor system to initiate. 00:22:45.183 --> 00:22:59.104 an intervention that might cause additional failures, but I think we've seen that even in the battery space where, oh, misdiagnosis of say smoke, the smoke could have been outside of the battery container. 00:22:59.193 --> 00:23:10.921 So a smoke detector could trigger intervention, for example, a water spray that could damage the cells and then lead to a cascading propagation. 00:23:11.280 --> 00:23:15.181 And so without again, naming names, things like this have occurred. 00:23:15.451 --> 00:23:27.240 So, as we think about these very complex systems, maybe B issue really is that we have to rethink how we, analyze safety for very complex systems. 00:23:27.240 --> 00:23:32.280 And maybe we're really learning with these battery systems. 00:23:32.310 --> 00:23:37.906 And this is the template by which our profession evolves in terms of understanding safety. 00:23:38.240 --> 00:23:45.891 I'm not even sort of, I know nothing about fusion, but every week there's another article that, yeah. 00:23:46.643 --> 00:23:51.784 that there are improvements and pathways towards workable fusion reactors. 00:23:52.864 --> 00:23:54.273 Somebody's got to protect. 00:23:54.453 --> 00:23:58.473 So we already protect nuclear reactors as a community. 00:23:58.503 --> 00:24:10.923 So the new, the nuclear industry uses fire and safety professionals to ensure that these incredibly complex systems don't catastrophic fail. 00:24:11.534 --> 00:24:19.827 we're going to have increasingly spaceports and we're going to have rocket systems and all the complexity associated with the fuels there. 00:24:20.532 --> 00:24:23.083 And we're going to be the ones asked to manage them. 00:24:23.373 --> 00:24:30.519 we think about the, there was a recently a large warehouse fire in the U S warehouses aren't supposed to burn, right. 00:24:30.519 --> 00:24:51.999 We, you know, we have all sorts of fire protection systems in place that should protect against them, but it's with the increasing complexity of all these systems that, you know, maybe we sort of, the piecemeal approaches to protection and the research associated with thinking about protection for these complex systems that it has to evolve also. 00:24:52.179 --> 00:24:56.378 And I know that you're doing a lot of work in terms of characterization of complex systems. 00:24:56.378 --> 00:25:04.598 And you know, whether it's, again, did, you said building scales buildings are increasingly complex systems with software controls, HVAC system sensor systems. 00:25:04.818 --> 00:25:05.538 It's insane. 00:25:05.568 --> 00:25:05.749 Yeah. 00:25:06.429 --> 00:25:07.058 It's incredible. 00:25:07.058 --> 00:25:07.358 Isn't it? 00:25:07.826 --> 00:25:08.195 Yeah. 00:25:08.266 --> 00:25:14.205 It's, I'm very safe about my war job with this complexity increase. 00:25:15.296 --> 00:25:21.223 I wanted also, going back to this, issue of fear and, safety, A failure is a failure. 00:25:21.253 --> 00:25:23.443 Not every failure is a catastrophe. 00:25:24.284 --> 00:25:34.624 I wondered if maybe we could try characterize what distinguishes a failure that could be acceptable or, negligent. 00:25:35.334 --> 00:25:41.794 From a failure that, turns into, first page of a newspaper, we've seen these videos. 00:25:41.794 --> 00:25:44.913 Uh, there was a video in the Shanghai with a huge fire. 00:25:45.423 --> 00:25:48.483 was a video of Chinese buses catching fire. 00:25:48.990 --> 00:25:56.009 there was a, this ship that burned down plenty of fancy cars for Americans, which you will not get. 00:25:56.670 --> 00:25:58.035 It's a shame when that's right. 00:25:59.700 --> 00:26:01.275 you, are going to ride Okay. 00:26:02.279 --> 00:26:05.775 now, Those aren't safe either. 00:26:05.775 --> 00:26:07.214 You know, you can get kicked by a horse. 00:26:09.230 --> 00:26:21.171 I would claim it's also rich people vehicle and that's, but yeah, What's the scenario when this fire of a battery system becomes catastrophical, what is the cause of such a fire? 00:26:21.621 --> 00:26:25.161 I know a phrase thermal runaway, and, it sounds scary. 00:26:25.161 --> 00:26:32.990 And, uh, I guess the videos have shown that, but how does, uh, a failure of a cell become a catastrophe good. 00:26:33.141 --> 00:26:33.411 Okay. 00:26:33.441 --> 00:26:37.760 So maybe first of all, we talk about possible failures of cells. 00:26:37.881 --> 00:26:43.221 And so, um, a cell itself could fail because of challenges in manufacturing. 00:26:43.521 --> 00:26:52.387 what's interesting is that, my university, university of Texas, uh, A long history of sort of excellence in, battery materials. 00:26:52.417 --> 00:26:59.137 And so we have distinguished, we have a Nobel Laureate with distinguished researchers who were working on the battery materials issues. 00:26:59.621 --> 00:27:08.651 there's a big step up between sort of designing and envisioning what the right battery materials are and the actual manufacturing of batteries. 00:27:08.980 --> 00:27:19.020 And so a couple of years ago, few years ago, we decided that we were going to embark on, an exercise to develop a battery fabrication of prototyping facility. 00:27:19.441 --> 00:27:23.855 And, I was fortunate enough be involved and I'm still involved in that process. 00:27:24.184 --> 00:27:36.407 And so, what I've learned about that is, is that battery manufacturing is A) really hard, there is limited metrology and in some sense, quality control there. 00:27:37.472 --> 00:27:45.982 The us government has finally realized that battery manufacturing is a strategically important national interest. 00:27:45.982 --> 00:27:53.192 So it's something that absolutely needs to be done because we're increasingly relying on these types of technologies. 00:27:53.673 --> 00:28:16.076 So learning about that has pointed out to me that very small mistakes can occur in terms of the manufacturing that would perhaps not immediately recognize in any kind of cell testing, but could have long term consequences when a cell is supposed to last years, for example, so thousands of cycles. 00:28:16.451 --> 00:28:30.056 well, I think when we're, when we were talking about battery manufacturing, I don't know if everyone realizes it, but we were talking about quantities manufactured at the same time, all. 00:28:30.211 --> 00:28:37.141 a line of battery produces like hundreds Oh, the few seconds oh, absolutely. 00:28:37.280 --> 00:28:47.698 quicker than, uh, machine gun in terms of Oh, it's So, here it's not a quality control where you would take every cell and put it into a on, say, oh, this cell is okay. 00:28:47.698 --> 00:28:50.738 No, we're talking about it's a printing press. 00:28:50.738 --> 00:28:52.897 Literally it it's a, it is a printing. 00:28:52.958 --> 00:28:54.788 It looks like a printing press. 00:28:55.057 --> 00:28:57.038 There's roll to roll technology. 00:28:57.038 --> 00:28:58.298 You're absolutely right. 00:28:58.298 --> 00:29:05.597 Everybody should watch, go to YouTube and take a look at a battery manufacturing facility in terms of how it's operating. 00:29:05.617 --> 00:29:12.008 So And so with manufacturing them, I can imagine even a small issues at random. 00:29:12.008 --> 00:29:17.951 Like every yes, you get the one that goes wrong, but yes, five minutes. 00:29:17.951 --> 00:29:18.280 Right. 00:29:18.851 --> 00:29:19.901 yes, no, no. 00:29:19.901 --> 00:29:22.300 You're you're so you're, you're hitting the exact points. 00:29:22.300 --> 00:29:22.601 Is that. 00:29:23.577 --> 00:29:33.028 Defects can happen when you're producing these types of large numbers and even with really good quality control, some things will slip by that may have a problem. 00:29:33.057 --> 00:29:33.478 Okay. 00:29:33.718 --> 00:29:37.201 Now, a particular cell might have that type of defect in it. 00:29:37.494 --> 00:29:43.644 otherwise a cell, could go into failure because of what we talked about before the battery management system. 00:29:43.644 --> 00:29:52.234 So one of the things that the battery management system is trying to do is it's trying to balance, for example, between all the different cells, in a battery. 00:29:52.234 --> 00:30:08.926 So again, when we talk about a battery, a battery is comprised of cells and these are individual cells and these cells can be as small as, a milli amp hour or so a hundred million amp hour or so, or as large as a hundred amp power. 00:30:08.926 --> 00:30:11.567 So, which, you know, we we've looked at and tested. 00:30:11.987 --> 00:30:17.836 . From that perspective, there's a scale range in terms of the energy storage associated with a given cell. 00:30:18.497 --> 00:30:23.297 a large cell failing has very different consequences from a small cell failing. 00:30:23.567 --> 00:30:31.186 And now the battery management system is trying to balance between the different cells and whether it's in parallel or series configurations. 00:30:31.517 --> 00:30:47.616 And, there is the possibility for example, that because the cells are not identical, that you might over time overcharge over discharge, any particular cell in the string of cells that comprise the battery and that could lead to failures. 00:30:47.616 --> 00:30:50.946 And those failures could be, for example, something like an overcharge that might occur. 00:30:51.336 --> 00:30:59.993 And so in terms of the overcharge that might be occurring, for lithium ion cells, you can get plating of the lithium metal because it's a transport issue, such a tray. 00:31:00.023 --> 00:31:04.673 So transport limitations of the ability of intercalated. 00:31:05.423 --> 00:31:14.693 Lithium ions into these active materials could cause something like a plating process to occur as this lithium played in this lithium metal occurring. 00:31:14.693 --> 00:31:21.634 For example, on the anode side, then you would get the possibility of dendrites forming. 00:31:21.683 --> 00:31:23.993 And these are again, just whiskers. 00:31:23.993 --> 00:31:41.237 If you think about them like that metal whiskers that could penetrate across the separator, which is trying to keep the, the electrical charges away from each other, if you will, from certain having sort of spontaneous discharge and then that could lead to a short circuit. 00:31:41.750 --> 00:31:47.339 so operationally one could get a failure to occur in terms of manufacturing. 00:31:47.430 --> 00:32:09.916 One could imagine that there's a failure that occurs and certainly in terms of mechanical damage, whether it's a belt bending process, Crash of a vehicle that causes a mechanical failure and, that bending, for example, puts elements the anode closer to the cathode or tears, the separator, or punctures, the separator. 00:32:10.217 --> 00:32:16.513 And then you can have a short that's formed because of this mechanical failure process. 00:32:16.930 --> 00:32:18.759 and then of course there's environmental failure. 00:32:18.759 --> 00:32:21.670 So we, again talk about the fact that fires occur. 00:32:21.700 --> 00:32:34.997 We know the fires occur, so, a high temperature environment could lead to the degradation of whether it's the separator, within the particular cell or two, reactions occurring, with. 00:32:35.499 --> 00:32:43.174 The, cell itself, and those could lead to this sort of cascading failure of all these different reactions. 00:32:43.174 --> 00:32:46.744 And that's the process that we talk about in terms of thermal runaway. 00:32:46.954 --> 00:32:50.734 So a single cell failure will occur. 00:32:51.694 --> 00:32:54.664 Single cells will fail from any number of reasons. 00:32:54.994 --> 00:32:59.930 And as you say, The issue becomes what is management of single cell failure look like? 00:33:00.220 --> 00:33:11.470 , and there are design professionals who are increasingly tasked to understand how to manage single cell failures, either through a heat transfer mechanisms. 00:33:11.936 --> 00:33:17.493 so, what kind of flows would we direct around a single cell or around the arrangement of cells? 00:33:17.493 --> 00:33:20.173 So that if a single cell failure occurred, it doesn't cascade. 00:33:20.584 --> 00:33:22.894 , in terms of compartmentalization, as you mentioned. 00:33:22.894 --> 00:33:31.953 So are there whether it's facing materials or other types of materials that one could layer into the systems to manage the heat transfer? 00:33:32.703 --> 00:33:39.094 Now that management heat transfer is complex because as we said before, just normal cycling of a cell causes the cell to heat up. 00:33:39.273 --> 00:33:45.433 So there is you think of it as a diode on under certain conditions, under normal operating conditions. 00:33:45.433 --> 00:33:46.784 I'm going to get heat out of the cell. 00:33:47.424 --> 00:34:00.204 and manage the overall system in terms of that heat transfer under abnormal operation conditions for a single cell, I may want to isolate that cell, so I will let that cell burn away, but I don't want it to cascade to the other cells. 00:34:00.384 --> 00:34:07.694 So, people and organizations are designing, developing, I should say design tools and it's not just CFD. 00:34:07.694 --> 00:34:09.315 It could be resistance network. 00:34:09.344 --> 00:34:18.148 It could be other types of tools that would now be increasingly used to design the safety systems and protection systems. 00:34:18.298 --> 00:34:22.559 Oftentimes we think about it really as a thermal protection systems for batteries. 00:34:22.889 --> 00:34:23.248 Okay. 00:34:23.369 --> 00:34:26.278 So batteries, single cells can fail. 00:34:26.818 --> 00:34:42.528 There are design professionals, whether it's an electric vehicle company or at a, an integrator developing for, onsite protection at a utility or at a big box, Uh, retail outlet, et cetera. 00:34:42.757 --> 00:34:44.192 these protection systems. 00:34:44.521 --> 00:34:54.335 Now having said that hopefully those protection systems are still able to manage single or two or three cell failures. 00:34:54.762 --> 00:35:05.824 I would say that there's a push there had been a push to going to larger cell capacities because of economies of scale and for all sorts of good reasons,, for electric vehicles. 00:35:05.824 --> 00:35:11.369 So people were saying, okay, well, let's go with, 94 amp hour cells or larger capacity cells. 00:35:11.878 --> 00:35:16.498 Those are harder to manage both thermally and otherwise in terms of failure. 00:35:16.768 --> 00:35:23.869 So in some sense, we know there are vehicle companies, a lot of them came out of Silicon valley that leverage what happened. 00:35:24.603 --> 00:35:29.643 Laptops and portable electronics that have much smaller capacity cells. 00:35:30.027 --> 00:35:33.336 and so these are whether it's 18650, 2170. 00:35:33.476 --> 00:35:40.766 So there are the smaller cell capacities and different formats that other companies have said, well, you know what? 00:35:40.797 --> 00:35:42.956 We can manage and control these better. 00:35:43.257 --> 00:35:47.137 Now there challenges in terms of, you know, having so many small cells. 00:35:47.137 --> 00:35:50.257 So there's probably some happy medium that, EV. 00:35:50.257 --> 00:36:01.367 .companies and others are going to think about in terms of, dense enough and high enough energy density and large enough cells, but not too large, that it becomes a control issue later on. 00:36:01.726 --> 00:36:02.027 Okay. 00:36:02.117 --> 00:36:15.773 So landscape wise, there has to be this idea then that there is some sweet spot in terms of size of cells that can be controlled so that if and when a failure occurs, it can be managed. 00:36:15.773 --> 00:36:17.454 So it doesn't cascade and propagate. 00:36:18.623 --> 00:36:30.277 Now I'm interested in that, but again, I say, well, if they don't do their job perfectly in quotes, um, we're still going to get larger scale propagation. 00:36:30.306 --> 00:36:35.166 And when we get larger scale propagation, we can get a whole module that fails. 00:36:35.827 --> 00:36:37.327 What are the impacts of that? 00:36:37.657 --> 00:36:39.456 Now it's kind of interesting. 00:36:39.456 --> 00:36:41.396 So, , probably you say the same thing. 00:36:41.423 --> 00:36:51.014 When I teach my fire science class, one of the first things we talk about is that the thing that sort of kills people most in fires is not the heat and fire. 00:36:51.014 --> 00:36:51.704 It's a smoke. 00:36:52.454 --> 00:37:00.965 So, I think that in some sense, we overthink the thermal issues associated with battery failures and under think. 00:37:01.657 --> 00:37:09.788 Toxicological impacts of it or the cascade of battery failures to other fuel packets. 00:37:09.907 --> 00:37:14.347 And then to really the thing that we're afraid of, or I'm afraid of, which is the smoke. 00:37:14.677 --> 00:37:23.887 So I think that connecting the dots between, okay, cell failure, what gases are released, what are the issues in terms of toxicity? 00:37:24.458 --> 00:37:32.708 How would this impede people in terms of egress or otherwise, what are the secondary fuel packages that could be involved in this failure? 00:37:33.157 --> 00:37:35.168 How do we understand that cascade? 00:37:35.228 --> 00:37:41.047 What are the ignition issues and how do we think about what the life safety implications of that might be? 00:37:41.347 --> 00:37:47.514 That's I think that's where I want to be clear and really sort of hammer on it and, and. 00:37:48.101 --> 00:37:49.327 that's that's a strong one, man. 00:37:49.356 --> 00:37:50.257 That's that's a good one. 00:37:50.657 --> 00:37:51.528 You're right. 00:37:52.309 --> 00:38:04.860 that's probably the biggest challenge I had when I started playing with, electric vehicle fires and trying to answer the doubts of people related about the car parks and electric fires goes. 00:38:04.889 --> 00:38:16.427 I, when I'm talking about, traditional fires, if you can call um, that you have this, let's say rule of thumb, tenability criteria, uh, visibility of 10 meters is let's say acceptable. 00:38:16.427 --> 00:38:21.739 You know, what amount of suit that, is, you know, the soot yield of your source. 00:38:22.219 --> 00:38:23.210 can figure that out. 00:38:23.210 --> 00:38:45.445 You can find the plausible answer, if I want to do, electrical fire, One thing that I noticed is they will have a completely different, uh, heat release rate curve and correct me if I wrong, but it looks like not, exponential is like logarithmic is like very, very sharp. 00:38:45.474 --> 00:38:50.215 It's not a huge release and suddenly dresses by, by a factor of 10 or 20. 00:38:50.215 --> 00:38:52.204 That, that's what I saw, from the measurements. 00:38:52.204 --> 00:38:55.775 And that's what you see in videos when there's like nothing, nothing, nothing, and the huge flame. 00:38:56.188 --> 00:38:57.525 Uh, so we figured that out. 00:38:57.945 --> 00:39:22.192 And we can in a way account for that by, making a very quick, uh, heat release rate, in our simulations, if we traditionally gave four minutes of fire growth to reach a one and a half megawatts of a car simulate a car fire in the car park, traditionally, as we did in past on TNO experimental results from many years ago, for electric vehicle, okay, let's start the simulation with one megawatt initially. 00:39:22.222 --> 00:39:25.612 Like goes from zero to one megawatt immediately. 00:39:26.501 --> 00:39:27.702 course I'm making an error. 00:39:27.731 --> 00:39:32.315 Of course I'm far away a reality, but who in fire science is not. 00:39:32.505 --> 00:39:36.289 so, but yeah, but then that's a way to solve it. 00:39:36.289 --> 00:39:36.559 Yeah. 00:39:36.768 --> 00:39:40.318 But then again, emissions, like do I account what's my. 00:39:41.119 --> 00:39:46.539 What's my, I didn't, I can't even call it a soot yiel what's my smoke yield. 00:39:47.128 --> 00:39:48.778 yeah, I think that's important. 00:39:49.389 --> 00:39:50.949 And, and, how bad is that? 00:39:51.188 --> 00:39:52.168 Am I still Yes. 00:39:52.219 --> 00:39:57.681 10 meters visibility or, will I be very dead seeing for these 10 meters at this point? 00:39:58.119 --> 00:40:05.472 that so frightening because I, I don't even have a good idea how to make it up. 00:40:05.711 --> 00:40:09.222 Like it did with the you know, I love that. 00:40:09.655 --> 00:40:10.074 Work. 00:40:10.074 --> 00:40:15.898 That's been, the RISE folks have done in terms of the battery space and vehicle fire space. 00:40:16.168 --> 00:40:29.675 So when the shipboard fire just a curve, one of the things I wanted to talk to about to my class about was, um, well, let's look at the heat release rate from an ICE versus a, , battery electric vehicle. 00:40:30.155 --> 00:40:33.869 And when we looked at the data sets and I said, okay, let's here. 00:40:34.119 --> 00:40:36.088 I'm showing you the heat release rates. 00:40:36.429 --> 00:40:40.239 they were all between say five and seven megawatt peaks. 00:40:40.628 --> 00:40:44.467 And I said, okay, tell me which one you're more concerned about. 00:40:44.827 --> 00:40:55.050 And we looked at it and we looked at it and we looked at it and we thought, yeah, they look a hell of a lot of like, you know, it's very difficult to discern sort of the one that I'd be more afraid of. 00:40:55.440 --> 00:41:02.650 And so when you think about all the fuel involved in a vehicle, um, lot of stuff. 00:41:02.681 --> 00:41:09.641 That's not necessarily battery and there's lot of stuff to be afraid of that has nothing to do with the battery. 00:41:09.820 --> 00:41:13.090 So now the question in my mind then becomes, okay. 00:41:13.181 --> 00:41:14.951 And I like to think about it this way. 00:41:15.300 --> 00:41:17.190 , we all know that smoke is bad. 00:41:17.251 --> 00:41:22.081 Smoke is bad when fires occur, but are some smoke situation worse. 00:41:22.291 --> 00:41:30.931 So are there things that are being produced toxicity wise than might be worse because there is a battery involved and here's the thing. 00:41:31.081 --> 00:41:34.380 I don't know what the answer to that question is, but I'd like to know. 00:41:34.411 --> 00:41:50.327 And that's what I'd like to put effort into and it's, it impacts obviously, occupants, but it really dramatically also impacts the fire service because when they're fighting these fires, they are intimately involved. 00:41:50.387 --> 00:41:52.827 So while yes, but they're on S CBAs. 00:41:52.858 --> 00:41:53.577 They're on air. 00:41:54.057 --> 00:41:55.197 Yes they are. 00:41:55.347 --> 00:41:56.295 But when you go. 00:41:56.735 --> 00:42:07.956 less than a hundred meters away, you see all sorts of firefighters congregating around equipment and otherwise without air packs on what's happening to them. 00:42:08.226 --> 00:42:11.945 , are there issues in terms of the, over the, is there change? 00:42:11.976 --> 00:42:19.085 I don't, I'm not saying there is, is there a change in the overall toxicity of the smoke because of the amount of batteries that have been involved in it? 00:42:19.405 --> 00:42:33.570 In the U S we just saw an incident, we've seen a few incidents now, and we've seen it around the world where, there have been, evacuation orders that have been placed when fires that included large amounts of lithium-ion batteries were occurred. 00:42:33.869 --> 00:42:37.519 And all those required is it really just, is it essentially a regular. 00:42:38.614 --> 00:42:44.378 Or is there something much worse or different about those, plumes that we need to think about? 00:42:44.378 --> 00:42:58.382 So, there's so many different aspects of this, and again, we're not trying to say that no batteries intrinsically and just are such a bad technology and we should not be going in this direction, but it's a clarification. 00:42:58.382 --> 00:43:05.161 So we understand better when they can be used, how they can be used and how to improve it. 00:43:05.402 --> 00:43:07.521 And just talk about, just, you know, I'm rambling. 00:43:07.521 --> 00:43:10.237 I'm sorry, it's this that's the point of a podcast. 00:43:10.802 --> 00:43:11.041 yeah. 00:43:11.041 --> 00:43:17.588 We're, we're at a pub and, um, I'm drinking my coffee and just given an opportunity, ramble. 00:43:17.648 --> 00:43:28.494 Um, but you, you think about something you think about something else that I, I think that, there has been a lot of fear about which is a flame retardant chemistries. 00:43:28.885 --> 00:43:29.304 Okay. 00:43:29.664 --> 00:43:31.195 So flame retardant. 00:43:31.460 --> 00:43:40.380 have been, you know, in quotes, thrown under the bus as, and some of your guests on this podcast hate flame retards. 00:43:40.389 --> 00:43:41.670 I'm not going to name any names. 00:43:42.280 --> 00:43:44.829 but they say that they don't really do anything. 00:43:44.829 --> 00:43:50.730 And for the, the harm that they potentially have, that it's not worth putting them in place. 00:43:51.266 --> 00:44:05.090 Now, if you look at a airplane, I don't think anybody in terms of safety systems for planes in terms of, you know, the seats and et cetera, we'll say, oh, let's take out the flame retardant because we know that time is critical in those situations. 00:44:05.090 --> 00:44:06.440 And it's incredibly important. 00:44:06.949 --> 00:44:15.260 And then arguably, because of the complexity of flame tardy chemistries, they have gotten much, much better over the last 30, 40 years. 00:44:15.260 --> 00:44:19.010 It's enormous improvements in terms of their overall safety. 00:44:19.143 --> 00:44:19.413 So. 00:44:19.905 --> 00:44:25.485 Has research been important here in terms of identifying the potential issues and problems with it? 00:44:25.635 --> 00:44:26.565 Absolutely. 00:44:26.565 --> 00:44:31.574 I say, has the industry responded by making safer flame retardants? 00:44:31.844 --> 00:44:32.894 Absolutely. 00:44:33.045 --> 00:44:47.295 So I think that the same issue has to happen in terms of why we look at batteries that maybe the first few sort of ways that people put together, battery protection systems really inadequate, but something had to be done. 00:44:47.894 --> 00:44:54.195 And it's incumbent on researchers to understand what the limitations and issues associated with. 00:44:54.195 --> 00:45:07.378 The safety of these systems are point them out and allow industry and other organizations to respond, to require and improve the overall safety of these systems. 00:45:07.617 --> 00:45:12.898 So I think, I think that there were analogies and there are ways that we're going to move along this. 00:45:13.532 --> 00:45:14.603 Yeah, on them. 00:45:14.603 --> 00:45:27.597 What you said, that's the one thing that scares me, the longevity of this technology that, even if we figure out, if you go tomorrow and figure out your noble price, awards the technology to make batteries fireproof or something, Yeah. 00:45:27.632 --> 00:45:42.454 just going to be the new batteries while we have already millions of electric vehicles on the roads old batteries, you know, and from my perspective, people come to me and ask, we design a car parks for electric vehicles from now? 00:45:42.454 --> 00:45:46.833 And I tell them years ago, when you designed the car park, you designed it for electric vehicles. 00:45:46.833 --> 00:45:47.614 He just didn't know. 00:45:47.940 --> 00:45:49.500 and that's not the choice we make. 00:45:49.954 --> 00:46:10.568 so, have to deal uh, with this in a smart way, not only with the newly produced, well maybe if you're a manufacturer, you probably are responsible for what you're on the fracture, but us as a safety engineers, delivering safety to the we're also responsible about what's around and how to manage that. 00:46:10.568 --> 00:46:18.110 And I really wonder if there are ways we, manage that or do we just have to hope this, things replaced themselves. 00:46:18.351 --> 00:46:27.164 However, I also read somewhere lately that, the rates of fires in electric vehicles were remarkably low, uh, that there was some insurers claim. 00:46:27.614 --> 00:46:34.110 don't know if how much truth is in that, but it was very, if that is true, that would be very, very nice. 00:46:34.110 --> 00:46:39.599 Maybe you have some knowledge about the statistics of, vehicle battery fires in general. 00:46:40.639 --> 00:46:42.019 oh gosh, I wish I did. 00:46:42.170 --> 00:46:52.516 , uh, you know, every paper we write about that we, point to, other people's papers and it all sort of leads to one paper essentially about what failure rates look like. 00:46:52.637 --> 00:46:56.206 Uh, but like you said, I think insurers are increasingly getting information. 00:46:56.206 --> 00:46:59.836 I mean, we're just as the population and number of electric vehicles has come up. 00:47:00.166 --> 00:47:04.967 They seem to be much safer than, internal combustion engine vehicles in terms of fires. 00:47:04.967 --> 00:47:12.027 I mean, I think that's becoming quite clear that they are less prone to fires than, internal combustion engine vehicles. 00:47:12.356 --> 00:47:15.833 And so now it's like, okay, we're on the right path. 00:47:15.833 --> 00:47:16.914 And that's a good thing. 00:47:17.304 --> 00:47:20.034 There's something else that you said there was really, I thought it was really interesting. 00:47:20.034 --> 00:47:24.704 It's just, you everybody and their grandmother is looking at, what's the next battery technology. 00:47:24.704 --> 00:47:30.673 And so whenever I talked to, protection type companies, I said, well, what about solid state batteries? 00:47:30.673 --> 00:47:34.693 Aren't those supposed to get rid of sort of the safety problems associated? 00:47:35.114 --> 00:47:42.197 And I said, listen, we're increasingly getting higher energy density and higher power density in all these battery systems. 00:47:43.322 --> 00:47:50.402 When failure occurs and the failure does not have to be associated with the cell itself because of all the reasons that you and I've just talked about. 00:47:50.702 --> 00:47:57.632 If there's a fire and your battery is involved with it, how does it contribute or impact that fire evolution? 00:47:57.632 --> 00:47:58.831 So that's question number one. 00:47:59.342 --> 00:47:59.702 Okay. 00:48:00.152 --> 00:48:06.141 Even with solid state batteries, there are so many problems right now with all safety. 00:48:06.141 --> 00:48:09.059 I just read something recently about, there's an electric vehicle company. 00:48:09.059 --> 00:48:11.998 They said we have solid state batteries in our vehicle. 00:48:12.568 --> 00:48:13.739 The range is no different. 00:48:13.739 --> 00:48:19.382 In fact, it's less range than, uh, liquid solvent-based, electrolyte, batteries. 00:48:20.192 --> 00:48:27.119 And it still has the sort of standard electrolyte materials in it because the solid state electric. 00:48:27.838 --> 00:48:29.309 It's brittle it cracks. 00:48:29.338 --> 00:48:30.628 There are all sorts of problems with it. 00:48:30.628 --> 00:48:37.498 So it's really a mixture of the sort of conventional electrolytes and the solid state electrolyte, if you will. 00:48:37.768 --> 00:48:45.958 And so, there's probably a decade before really this just real implementation in this. 00:48:45.958 --> 00:49:01.592 When I talked to, the battery manufacturing people, and even then, as you said, the conventional batteries are commodity and are relatively inexpensive, and those will dominate in a lot of markets and in a lot of applications. 00:49:01.831 --> 00:49:17.989 So in some sense, we're going to be challenged with managing safety systems for new and evolving battery systems, as well as the old systems where, these large companies have dumped billions of dollars into manufacturing capability for these conventional systems. 00:49:17.989 --> 00:49:20.012 So we just have to keep working. 00:49:20.012 --> 00:49:20.101 Yes. 00:49:20.882 --> 00:49:46.829 but after this talk, I'm fascinated because now I see that, though the cell may be an old technology, it a new compartment, giving it a new battery management system, giving it, access to some new, uh, safety features, like active systems that, that could, uh, react it, it Yeah, improve their safety, despite it being, another technology from, uh, from ancient times, like 2013. 00:49:46.829 --> 00:49:47.068 Right. 00:49:48.239 --> 00:49:48.599 So. 00:49:49.898 --> 00:49:50.369 that's right. 00:49:50.798 --> 00:49:51.449 That's it? 00:49:51.628 --> 00:49:53.668 That is your spot on ancient times. 00:49:53.668 --> 00:49:54.119 Indeed. 00:49:55.139 --> 00:49:55.518 Yeah. 00:49:55.648 --> 00:49:57.018 And, and w one more thing. 00:49:57.594 --> 00:49:59.795 also mentioned this smoke, as a problem. 00:49:59.795 --> 00:50:04.784 And I often run into this issue discussing the problem with people. 00:50:05.324 --> 00:50:08.295 like, man, these fires are huge. 00:50:08.668 --> 00:50:10.289 their temperature is insane. 00:50:10.289 --> 00:50:11.909 Like, okay, that's, that's always nice. 00:50:12.389 --> 00:50:12.929 That's great. 00:50:13.628 --> 00:50:16.768 they, they will like destroy the concrete building. 00:50:16.768 --> 00:50:20.789 They burn so ferocious and they can burn for two days and I'm like, holy shit. 00:50:20.789 --> 00:50:28.931 That's like a, that's a noble price because you broke conservation of energy and mass, like, uh, so it's, either. 00:50:29.112 --> 00:50:38.422 And my experience with people who test the batteries is like, if it burns quickly and fiercefully, that's actually okay, because That's a good thing. 00:50:38.742 --> 00:50:44.532 that's, that's the best thing that's going to happen in the Oh, did gosh, you're saying you're so hot. 00:50:44.681 --> 00:50:45.192 It's funny. 00:50:45.192 --> 00:50:47.981 We just had a conversation with our local fire department. 00:50:47.981 --> 00:50:52.599 They were talking about electric vehicle fire and say, Hey, what you know is this really true? 00:50:52.599 --> 00:50:55.688 We need to apply in quotes, copious amounts of water. 00:50:55.719 --> 00:50:56.978 I said, Hey, you know what? 00:50:57.099 --> 00:51:01.608 I think, again, vehicle company X said this, and I really agree with it. 00:51:01.909 --> 00:51:03.978 if there's not an exposure that you're worrying about. 00:51:04.492 --> 00:51:14.101 Let the damn thing burn and let it burn quickly, let it burn quickly so that you don't have to babysit it forever so that you do get rid of all the stuff. 00:51:14.197 --> 00:51:14.766 stay in it. 00:51:14.811 --> 00:51:15.661 Yeah, that's true. 00:51:15.692 --> 00:51:16.021 That's right. 00:51:16.021 --> 00:51:16.382 You got it. 00:51:16.411 --> 00:51:29.358 You got it's exposures and those exposures, not just thermal exposures, it's thermal and emissions exposures, but it's really, it's managing exposures, but the way we might think about it as the safest batteries, a burnt battery. 00:51:29.509 --> 00:51:34.369 So if we can burn it, we're good. 00:51:35.208 --> 00:51:40.931 We no longer have a problem, you know, Hey, which I'm not even gonna speak to the fact that is one of the challenges. 00:51:40.931 --> 00:51:45.938 Is that when an electric vehicle or one of these appliances burn, there are a lot of cells in there dead. 00:51:46.414 --> 00:51:47.182 Go off. 00:51:47.472 --> 00:51:48.443 It's your point too? 00:51:48.443 --> 00:51:52.552 You said that she said, okay, if five cells go off, isn't that safe? 00:51:52.612 --> 00:52:00.083 Well, it's safe for somebody, but it might be safe, unsafe for somebody else who has to get those five cells out or manage that battery. 00:52:00.083 --> 00:52:04.012 Now that several cells have failed in it and others are compromised. 00:52:04.012 --> 00:52:08.182 So we don't know how compromised the other cells are. 00:52:08.182 --> 00:52:10.583 And that becomes a longer-term issue. 00:52:10.583 --> 00:52:14.827 But that's, there's going to be a whole industry that comes up to deal and manage with those issues. 00:52:15.467 --> 00:52:18.166 burns batteries is very difficult. 00:52:18.197 --> 00:52:19.146 Uh, Yeah. 00:52:19.547 --> 00:52:32.536 tell you how we do it, but I can just say that I would just, I can just say that, that having, having, uh, you know, fire resistance furnaces a lot in some things like, I like it. 00:52:32.597 --> 00:52:32.987 yeah. 00:52:32.987 --> 00:52:33.407 like it. 00:52:33.407 --> 00:52:34.067 I agree with you. 00:52:34.157 --> 00:52:34.817 I agree with you. 00:52:34.954 --> 00:52:37.733 when we, when you do this battery tests, like the rule is Yeah. 00:52:37.748 --> 00:52:39.007 leave them there for a week. 00:52:39.007 --> 00:52:52.275 And, uh, after a week there's, they're more or less, it would be very awkward if Uh, happened the week after and on the exact day, when you chose to pick it up, I would act, I would then consider it an act of God and I would just live with it. 00:52:54.014 --> 00:53:02.818 So that's, that's, the point of view, but, it should that, burns batteries, safer battery yeah, the unburned one. 00:53:03.628 --> 00:53:04.148 absolutely. 00:53:04.257 --> 00:53:06.871 discussed this with respondent, Yes. 00:53:06.992 --> 00:53:08.371 They need to know. 00:53:08.402 --> 00:53:10.291 There are two kinds of threads. 00:53:10.291 --> 00:53:17.041 They will be exposed to one being a huge fire to which they are used to word. 00:53:17.041 --> 00:53:18.041 The challenge Okay. 00:53:18.061 --> 00:53:21.211 toxicology because the fire will be there as they know it. 00:53:21.572 --> 00:53:28.442 It's just gonna to be a little different chemical composition of the smoke in which Yes, yes, anyway. 00:53:28.842 --> 00:53:29.862 yes, exactly. 00:53:30.108 --> 00:53:35.994 that's option a and option B if something weird is happening, it's, it's puffing, it's, Yes. 00:53:36.264 --> 00:53:40.692 smoking his gun that that's a completely different scenario. 00:53:41.112 --> 00:53:48.492 And then maybe I can imagine where you would have to isolate this vehicle or this battery, even four days. 00:53:49.052 --> 00:53:49.322 yeah. 00:53:49.382 --> 00:53:51.001 And let's say option C. 00:53:51.001 --> 00:53:53.882 And so, whether it's confined or unconfined becomes the issue. 00:53:53.882 --> 00:53:57.179 And so, we go to the surprise arson incident and other incidents. 00:53:57.179 --> 00:54:01.500 It's just that, I conventionally have dealt with non pre-mixed flames. 00:54:01.530 --> 00:54:04.146 I deal with, you know, natural burning systems. 00:54:04.329 --> 00:54:07.269 but in another life I did work on premixed lengths. 00:54:07.269 --> 00:54:11.199 And so the, the challenges becomes that explosions can occur. 00:54:11.199 --> 00:54:17.650 I mean, so we're not just, we're not just, so when does this thing becomes under ventilated, if it's confined, it's becomes under ventilated. 00:54:18.465 --> 00:54:24.925 The products are not just CEO that we might see in normal, under ventilated combustion systems. 00:54:25.105 --> 00:54:27.744 We had hydrogen and we have hydrocarbons in there. 00:54:28.135 --> 00:54:31.045 And so the explosion hazard is real. 00:54:31.045 --> 00:54:39.295 And so we have to start thinking about explosion protection in a serious way for our confined or partially confined battery systems. 00:54:40.023 --> 00:54:42.519 I know the last one we did blew up. 00:54:42.875 --> 00:54:44.494 Yes, yes, yes. 00:54:44.570 --> 00:54:46.677 Nah, but wow man. 00:54:46.719 --> 00:54:48.010 it's an hour already. 00:54:48.099 --> 00:54:49.344 I told you like Yeah. 00:54:49.389 --> 00:54:53.385 presentations are boring and long, but when I write, oh, this is great. 00:54:53.469 --> 00:54:54.416 like, it's good. 00:54:54.416 --> 00:54:55.197 So quickly. 00:54:55.681 --> 00:54:56.492 This is great. 00:54:56.907 --> 00:54:57.976 Any famous last words? 00:54:59.731 --> 00:55:00.722 This was a lot of fun. 00:55:00.916 --> 00:55:04.853 uh, no, but seriously, let's, let's close it up with some statements. 00:55:04.853 --> 00:55:07.853 So I think I share your mindsets. 00:55:07.943 --> 00:55:10.463 I'm not scared of this technology. 00:55:11.364 --> 00:55:25.570 It's a new technology, relatively new, we're on the front of making it safer, which does not mean it's unsafe and there's lots of smart people working on it and, trying to, make it better. 00:55:25.630 --> 00:55:26.079 Right. 00:55:26.304 --> 00:55:26.753 hopeful. 00:55:26.813 --> 00:55:27.414 I am. 00:55:27.414 --> 00:55:28.313 I'm very hopeful. 00:55:28.313 --> 00:55:31.324 I think that you, you summed it up perfectly. 00:55:31.777 --> 00:55:36.967 we're moving into, there's nothing we can do to change this trajectory. 00:55:36.967 --> 00:55:41.603 I don't think because it's incredibly required and, we're just trying to improve it. 00:55:41.634 --> 00:55:42.083 That's all. 00:55:42.083 --> 00:55:51.449 So I'm, I'm very hopeful that all of the effort that you and others and, we're all trying to collectively do in this space. 00:55:51.469 --> 00:55:53.329 we'll create safer systems. 00:55:53.679 --> 00:55:54.369 Yeah, man. 00:55:54.369 --> 00:55:54.789 Thanks. 00:55:54.860 --> 00:55:56.469 This was, this was excellent. 00:55:56.500 --> 00:55:57.519 I thought she was going to be excellent. 00:55:58.070 --> 00:56:02.893 He didn't believe that Ah, this is I really enjoyed it. 00:56:02.893 --> 00:56:12.043 It was a great pleasure having you in the fire sane show and I'm sure I'm going to see you here again, I hope to I hope so you in Austin as well. 00:56:12.463 --> 00:56:13.983 Uh, that would be wonderful. 00:56:14.014 --> 00:56:15.034 That would be wonderful. 00:56:15.072 --> 00:56:24.945 th there's supposedly some pickle challenge, posed was the better way to eat a pickle like Polish way, super sour or Texas way fried. 00:56:25.184 --> 00:56:28.244 So we were going to settle that in the battle. 00:56:29.409 --> 00:56:31.239 And it should be, it should be an Austin. 00:56:31.239 --> 00:56:32.679 We'll we'll do it in Austin. 00:56:32.679 --> 00:56:33.820 We'll do in Warsaw. 00:56:34.059 --> 00:56:34.849 We'll do it all over. 00:56:36.135 --> 00:56:36.974 Thank you so much. 00:56:37.545 --> 00:56:37.844 thanks. 00:56:37.960 --> 00:56:38.409 Absolutely. 00:56:38.409 --> 00:56:39.280 Thank you for doing this. 00:56:39.769 --> 00:56:40.960 See you around Take care. 00:56:41.199 --> 00:56:41.530 Goodbye. 00:56:42.422 --> 00:56:43.112 And that's it. 00:56:43.413 --> 00:56:44.373 Hope you've liked this. 00:56:44.822 --> 00:56:48.963 I've spent one hour talking to DK and he's my best friend now. 00:56:49.503 --> 00:56:50.822 It was an amazing episode. 00:56:50.882 --> 00:56:52.893 So enthusiastic, so happy about. 00:56:52.967 --> 00:56:56.864 The research he's doing and so optimistic towards the future. 00:56:56.954 --> 00:56:59.293 And I think that's what I really needed. 00:56:59.804 --> 00:57:02.744 And optimistic view towards the fire. 00:57:02.744 --> 00:57:05.563 See future of lithium-ion battery technology. 00:57:05.914 --> 00:57:08.884 Because it is a part of our future. 00:57:09.393 --> 00:57:10.773 Whether we like it or not. 00:57:10.893 --> 00:57:14.193 And, and it's great that smart people are working. 00:57:14.224 --> 00:57:17.088 To make this technology as safe as possible. 00:57:17.688 --> 00:57:21.797 And as we mentioned in the episode, It does not mean it's not safe. 00:57:22.458 --> 00:57:28.728 It means we are still seeking solutions, how to tackle problems better, how to identify problems better. 00:57:29.057 --> 00:57:33.318 How to apply solutions at many layers of the protection within the battery. 00:57:34.157 --> 00:57:35.447 And with all this. 00:57:35.867 --> 00:57:36.827 Just make it. 00:57:37.128 --> 00:57:38.507 Better more accessible. 00:57:38.958 --> 00:57:41.782 . 00:57:38.958 --> 00:57:42.952 Easier to replace, easier fire risk perspective. 00:57:43.431 --> 00:57:48.101 So I hope you've enjoyed this optimistic view on batteries. 00:57:48.132 --> 00:57:51.402 And you can share this with all of your friends who are. 00:57:51.577 --> 00:57:54.128 A little scared of the technology. 00:57:54.847 --> 00:57:58.177 And maybe they will give a little more enthusiastic about it. 00:57:58.688 --> 00:58:00.728 And with this optimistic. 00:58:00.998 --> 00:58:03.298 accent I would love to close this episode. 00:58:03.809 --> 00:58:06.059 Thank you so much for being here and listening. 00:58:06.628 --> 00:58:08.849 And I hope to see you next week. 00:58:08.909 --> 00:58:11.489 Another great interview coming your way next Wednesday. 00:58:11.969 --> 00:58:12.418 Cheers. 00:58:12.478 --> 00:58:12.748 Bye.