074 - Engineering not magic, intumescent coatings with Andrea Lucherini

Fire Science Show

Intumescent coatings are not magic. They are a product of amazing engineering, a theatre of thermophysical properties that create an insulative layer that sometimes is the only thing holding fire from destroying a structure. A chemical masterpiece in which the onset of swelling is chosen so that the paint layer is soft just when the chemical compound used to foam starts releasing gasses. Sharing many features with natural carbon-made materials, they char and oxidize. And once you start modelling them, you soon realize how crazy the solid heat transfer can become when you change not only the thermal conductivity but also the size of your body. Boy, what a complexity in a sub-millimetre layer of paint!

To learn all about them, I have invited dr Andrea Lucherini of FRISSBE  and Ghent University, who mastered them in his MSc and PhD. Andrea covers in detail all the mag... I mean engineering that goes into an intumescent coating and shares his own journey in this world.

In this episode, we have referenced episode 70 with Piotr Turkowski - fire resistance. If you have not heard it, it's a good moment to catch up.

Andrea has provided me links to his research, which I highly recommend:
- PhD thesis: https://doi.org/10.14264/uql.2020.1021
- modelling: https://doi.org/10.1016/j.ijthermalsci.2022.107922
- influence of heating conditions and thickness: https://doi.org/10.1016/j.firesaf.2020.103078
- influence of substrate: https://doi.org/10.1002/fam.2840
- application on timber: https://doi.org/10.1016/j.firesaf.2019.102887
- critical literature review: https://doi.org/10.1016/j.jcsr.2019.105712
- onset of swelling: https://doi.org/10.1016/j.firesaf.2019.03.014
- MSc thesis paper: https://doi.org/10.1016/j.firesaf.2017.10.004

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2022-11-02 51 min Transcript

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WEBVTT

00:00:00.408 --> 00:00:01.669
<v Wojciech Wegrzynski>Hello, and welcome to the fire sentence.

00:00:01.669 --> 00:00:02.629
<v Wojciech Wegrzynski>Show session 74.

00:00:03.033 --> 00:00:06.123
<v Wojciech Wegrzynski>After the last week solo episodes, we're back to the old interview format.

00:00:06.153 --> 00:00:10.743
<v Wojciech Wegrzynski>And I again have a nice rising star of the fire safety engineering profession.

00:00:11.416 --> 00:00:13.676
<v Wojciech Wegrzynski>So I have invited Dr Andrea Lucherini.

00:00:13.877 --> 00:00:17.187
<v Wojciech Wegrzynski>Who's with a FRISSBE it's an research institue to do that Slovenia.

00:00:17.547 --> 00:00:19.396
<v Wojciech Wegrzynski>and, uh, It's an interesting project.

00:00:19.396 --> 00:00:21.806
<v Wojciech Wegrzynski>I'm sure we are going to hear a lot more about it.

00:00:22.097 --> 00:00:23.007
<v Wojciech Wegrzynski>Hopefully also in the podcast.

00:00:23.806 --> 00:00:27.196
<v Wojciech Wegrzynski>And Andrea is also affiliated with Ghent university.

00:00:27.527 --> 00:00:27.977
<v Wojciech Wegrzynski>So.

00:00:28.004 --> 00:00:35.119
<v Wojciech Wegrzynski>Very prolific young scientists and doing lots of interesting, interesting research But they invited him to talk about his.

00:00:35.759 --> 00:00:40.719
<v Wojciech Wegrzynski>Research that carries from master thesis through his And university of Queensland.

00:00:41.375 --> 00:00:45.716
<v Wojciech Wegrzynski>And the subject of this work was on intumescent coatings or intumescent paints.

00:00:45.807 --> 00:00:48.856
<v Wojciech Wegrzynski>Very interesting, very useful topic.

00:00:49.296 --> 00:00:53.917
<v Wojciech Wegrzynski>, fire protection system that is used everywhere.

00:00:54.036 --> 00:00:55.536
<v Wojciech Wegrzynski>Like you see them everywhere.

00:00:56.006 --> 00:00:58.286
<v Wojciech Wegrzynski>From fire, protecting steel through timber.

00:00:58.334 --> 00:01:01.694
<v Wojciech Wegrzynski>Closing cavities, closing gaps, insulation joints.

00:01:02.746 --> 00:01:13.746
<v Wojciech Wegrzynski>Coatings are finding more and more using farsighted engineering, but it's interesting how they work, how they operate, how, what, what makes them differentiate between each other is very, very large subject, to be honest.

00:01:14.236 --> 00:01:15.496
<v Wojciech Wegrzynski>Very interesting subject.

00:01:15.496 --> 00:01:21.846
<v Wojciech Wegrzynski>And that's, that's exactly why Andrea is here to understand from a scientist who's really researching this term.

00:01:22.335 --> 00:01:32.590
<v Wojciech Wegrzynski>What are the things that make intumescent coating work or maybe things that make it not work, or maybe conditions in which they stopped working, or how do they differ from each other?

00:01:32.590 --> 00:01:38.323
<v Wojciech Wegrzynski>A  That's really a huge topic and I hope we've done well to cover at least a.

00:01:38.510 --> 00:01:40.189
<v Wojciech Wegrzynski>Fundamental principles of that.

00:01:40.549 --> 00:01:44.030
<v Wojciech Wegrzynski>Cause Th that that's definitely not a subject for a single podcast episode.

00:01:44.719 --> 00:01:45.980
<v Wojciech Wegrzynski>If you like it, let me know.

00:01:45.980 --> 00:01:52.329
<v Wojciech Wegrzynski>And I'll guess I'll I can invite Andrea to a follow-up where we can maybe talk a little more about modeling.

00:01:53.030 --> 00:01:58.689
<v Wojciech Wegrzynski>Or some practical, consequences of the physical properties that are being discussed here.

00:01:59.489 --> 00:02:04.170
<v Wojciech Wegrzynski>Anyway, no matter what your role in the fire safety engineering is one day you will meet intumescent coatings.

00:02:04.890 --> 00:02:08.129
<v Wojciech Wegrzynski>So yeah, better learn them and understand how they work.

00:02:08.490 --> 00:02:10.349
<v Wojciech Wegrzynski>So your job will be easier.

00:02:10.800 --> 00:02:14.280
<v Wojciech Wegrzynski>So without further ado that spins into and jump into the episode.

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<v Wojciech Węgrzyński>Hello everybody.

00:02:38.436 --> 00:02:41.265
<v Wojciech Węgrzyński>Welcome to the Fire Science Show.

00:02:41.545 --> 00:02:46.225
<v Wojciech Węgrzyński>Maybe based on the guest affiliation, I should call it Ghent University Show lately.

00:02:46.406 --> 00:02:47.026
<v Wojciech Węgrzyński>Hey, Andrea.

00:02:47.455 --> 00:02:48.346
<v Wojciech Węgrzyński>Good to have you.

00:02:48.554 --> 00:02:48.913
<v Andrea Lucherini>Hello?

00:02:48.913 --> 00:02:49.674
<v Andrea Lucherini>Hello, War Check.

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<v Wojciech Węgrzyński>today I'm having a nice talk with Dr.

00:02:52.193 --> 00:03:01.135
<v Wojciech Węgrzyński>Andrea Lucherini uh, FRISSBE Slovenia, which, uh, is under the ZAG  in Sloven and also, at Gant University.

00:03:01.135 --> 00:03:07.036
<v Wojciech Węgrzyński>That's my pun at the start, is you're like third in a row affiliated with Ghent in, in the podcast.

00:03:07.036 --> 00:03:11.075
<v Wojciech Węgrzyński>That, that makes me quite happy,. Good, good, good place to be.

00:03:11.575 --> 00:03:14.006
<v Wojciech Węgrzyński>So Andrea, great to have you in the show.

00:03:14.360 --> 00:03:22.545
<v Wojciech Węgrzyński>I brought you because, uh, there were some publications published lately that, my professional colleagues, uh, has claimed are interesting.

00:03:22.545 --> 00:03:23.545
<v Wojciech Węgrzyński>If not grow breaking.

00:03:23.545 --> 00:03:32.419
<v Wojciech Węgrzyński>So I thought okay, if he does your professional opinion, I've I'm gonna get the author on, my podcast and, uh, I've invited you to talk about, into mess pains.

00:03:32.419 --> 00:03:35.699
<v Wojciech Węgrzyński>Then you were really angry with me for using the word paint and

00:03:36.234 --> 00:03:37.373
<v Andrea Lucherini>No, not too angry.

00:03:37.378 --> 00:03:41.718
<v Wojciech Węgrzyński>and told me I should refer that I should call them into me coating.

00:03:42.163 --> 00:03:43.644
<v Wojciech Węgrzyński>let's start with that.

00:03:44.033 --> 00:03:49.443
<v Wojciech Węgrzyński>What's this technology of intumescent coating and, uh, why should we call it like that?

00:03:49.474 --> 00:03:52.318
<v Andrea Lucherini>first of all, the difference between paint and coating.

00:03:52.318 --> 00:03:55.647
<v Andrea Lucherini>I mean, I don't think that there is any significant difference.

00:03:55.677 --> 00:04:09.897
<v Andrea Lucherini>What I find, and also by reading a lot of literature, I usually see that quotings is a more professional term, so to describe something that protects, for example, load-bearing structure that we, the use of quotings paint.

00:04:09.897 --> 00:04:14.758
<v Andrea Lucherini>Sometimes it, to me, it sounds like I'm less professional and more simplistic.

00:04:15.147 --> 00:04:28.533
<v Andrea Lucherini>Because it's, quoting is, is a much more complex um, material And then hopefully during this episode I'll manage to explain you why it's complicated and also is what attracted me to this sort of field of our research

00:04:28.869 --> 00:04:30.269
<v Wojciech Węgrzyński>actually, let's go there directly.

00:04:30.795 --> 00:04:37.005
<v Wojciech Węgrzyński>it's not, um, a very obvious choice when you, when you pick from all the fancy stuff happening in fire.

00:04:37.005 --> 00:04:40.317
<v Wojciech Węgrzyński>So how, how did you enter the path of, researching intumescent coatings?

00:04:40.338 --> 00:04:42.019
<v Wojciech Węgrzyński>I don't think it's a very popular pathway.

00:04:42.396 --> 00:04:43.471
<v Andrea Lucherini>No it's not.

00:04:43.531 --> 00:04:51.081
<v Andrea Lucherini>Even though you can, if you're going into literature, if you can check like web science, there is a lot of research happening to that because it's a big.

00:04:51.420 --> 00:04:56.704
<v Andrea Lucherini>Topic and also is a the product is used worldwide, more or less everywhere.

00:04:57.213 --> 00:05:07.834
<v Andrea Lucherini>And it's a very, you know, modern way to protect, particularly everything started with steel structures, but is something that is spreading around the world and now is what's now applying to different materials.

00:05:08.250 --> 00:05:10.141
<v Andrea Lucherini>But in general, what are interes coatings?

00:05:10.201 --> 00:05:11.130
<v Andrea Lucherini>Interes coatings.

00:05:11.790 --> 00:05:22.754
<v Andrea Lucherini>It's a coating a paint, uh, which is usually applied in a very thin film that we discuss depending on the use, because usually we have two categories of interes coatings.

00:05:22.783 --> 00:05:26.249
<v Andrea Lucherini>We call it thin interes coatings or interes coatings.

00:05:26.894 --> 00:05:33.947
<v Andrea Lucherini>The thin interes coatings are the one that we usually use them for the so-called cell logic conditions.

00:05:34.367 --> 00:05:37.788
<v Andrea Lucherini>So it would be usually for the built environment where usually we.

00:05:38.463 --> 00:05:43.322
<v Andrea Lucherini>Something similar or the standard fire curve as a testing scenario

00:05:43.458 --> 00:05:43.947
<v Wojciech Węgrzyński>Okay,

00:05:44.055 --> 00:05:49.456
<v Andrea Lucherini>for the, far resistant test, we use that, far scenario to test the performance of that.

00:05:50.386 --> 00:05:57.886
<v Andrea Lucherini>So we, in, in the thin interes coatings, they're usually solvent based or water based, and they are usually applied in terms of a few millimeters.

00:05:58.137 --> 00:06:06.750
<v Andrea Lucherini>And, what is peculiar about, maybe I can explain later, but just to compare then we have the thick intermission coatings and the thick into medicine.

00:06:06.750 --> 00:06:09.120
<v Andrea Lucherini>Coatings instead are usually two parts.

00:06:09.211 --> 00:06:18.701
<v Andrea Lucherini>Quotings are usually for the majority epoxy based, so it's a more chunky, quoting that usually apply instead of millimeters, one order of magnitude higher.

00:06:18.730 --> 00:06:20.410
<v Andrea Lucherini>So in terms of thin centimeters,

00:06:20.584 --> 00:06:22.189
<v Wojciech Węgrzyński>Like a mass you would apply, not

00:06:22.199 --> 00:06:29.358
<v Andrea Lucherini>Yeah, it's a, it is a thicker coating and usually it's applied for conditions that are more demanding in terms of fire.

00:06:29.358 --> 00:06:38.168
<v Andrea Lucherini>So typically for the oil and gas industry for so-called either park carbon conditions is usually the market of these coatings.

00:06:38.428 --> 00:06:39.108
<v Wojciech Węgrzyński>Understood.

00:06:39.288 --> 00:06:41.593
<v Wojciech Węgrzyński>And how did you end up researching this?

00:06:42.283 --> 00:06:42.853
<v Andrea Lucherini>Uh, yeah.

00:06:42.853 --> 00:06:59.612
<v Andrea Lucherini>So what happened, as I mentioned in 2015, uh, when I was at the end of my masters in, construction engineering at the DTU the Tech University of Denmark in Copenhagen, I was looking to different, uh, master thesis, you know, and, uh, you're like master student.

00:06:59.612 --> 00:07:03.567
<v Andrea Lucherini>You're excited and it is the first sort of experience in research.

00:07:04.040 --> 00:07:18.290
<v Andrea Lucherini>I was asking around about people that could potentially, professor, could potentially offer a master thesis topic, and I ended up in this extremely interesting topic related to international quotings promoted by Professor Grunds.

00:07:18.935 --> 00:07:22.329
<v Andrea Lucherini>And, uh, Professor Luisa Giuliani at the, dtu.

00:07:22.492 --> 00:07:29.562
<v Andrea Lucherini>So I picked it because I found extremely interesting also because it's extremely complicated problem and also extremely fascinating.

00:07:30.312 --> 00:07:39.338
<v Andrea Lucherini>But what I did, I did this five, six month research Based on the outcomes, I decided even to do my PhD based on that.

00:07:39.369 --> 00:07:52.968
<v Andrea Lucherini>Because what we did is, the first question we want, we were trying to answer is that if we have two coatings for the same application, so we took two random commercial coatings for indoor applications.

00:07:52.968 --> 00:07:57.738
<v Andrea Lucherini>for cellulose conditions, as I mentioned earlier, one was water based, one was so solvent based.

00:07:58.069 --> 00:08:03.899
<v Andrea Lucherini>We applied on typically, One section of a steel, uh, beam.

00:08:04.139 --> 00:08:20.052
<v Andrea Lucherini>It was an ip, um, beam, and we exposed to different fire conditions and were trying to understand how would this coating behave if we exposed to different conditions, typically different heating rates, but we also, we always achieve the same high tempera.

00:08:20.802 --> 00:08:25.512
<v Andrea Lucherini>So mainly we we did the most critical condition was the standard fire curve.

00:08:25.783 --> 00:08:30.692
<v Andrea Lucherini>So very high heating rates, reaching, 1100 degrees in about, uh, one hour.

00:08:31.023 --> 00:08:40.594
<v Andrea Lucherini>And then we did the same test using electric oven but achieving that 11, 1100 degrees in, you know, half an hour, two hours, and so on.

00:08:40.773 --> 00:08:43.232
<v Andrea Lucherini>So it was a different heating rate, but still the same temperature.

00:08:43.923 --> 00:08:58.368
<v Andrea Lucherini>And what we found extremely interesting is, The quoting since it was designed for some more or less, the same fire resistance class, so it would achieve the, behavior of the quoting under the standard condition would've been more or less the same, the two cases.

00:08:59.118 --> 00:09:01.697
<v Andrea Lucherini>But what happened between the two quotings?

00:09:01.953 --> 00:09:08.043
<v Andrea Lucherini>uh, the scenario of the fire resistance test would represent the worst of the best scenario in the two coat.

00:09:08.676 --> 00:09:20.543
<v Andrea Lucherini>Because what happened is that what you imagine if you have a fire, that it grows slower, That you would sort of have, allow longer time to de quoting, to swell.

00:09:20.753 --> 00:09:26.102
<v Andrea Lucherini>So it can sort of build a sort of more better, foam that will protect it.

00:09:26.614 --> 00:09:36.957
<v Andrea Lucherini>Um, while in the other case, if you have like a very fast growing fire, then potentially would create some sort of weakness in terms of cracking or parts that the touch and everything.

00:09:37.288 --> 00:09:48.177
<v Andrea Lucherini>But what we found out, one coating add the best performance in terms of we sort of calculate inversely uh, the firmer resistance or the effective therma conductivity of this.

00:09:48.972 --> 00:10:00.265
<v Andrea Lucherini>By, taking the, temperature of the protective steel, and we found out then in one case, the standard fire would represent the worst scenario, so would've the highest ther conductivity.

00:10:00.416 --> 00:10:00.865
<v Andrea Lucherini>Let's say.

00:10:01.225 --> 00:10:07.225
<v Andrea Lucherini>In the other case, the interes coating would represent the lowest FEMA conductivity.

00:10:07.861 --> 00:10:13.066
<v Andrea Lucherini>Therefore is a matter of how do we understand the performance of these coatings?

00:10:13.426 --> 00:10:17.355
<v Andrea Lucherini>Is it the standard five representing the worst case scenario or the best case scenario?

00:10:17.836 --> 00:10:19.605
<v Andrea Lucherini>Because as you know, I also discussed with

00:10:20.760 --> 00:10:23.711
<v Wojciech Węgrzyński>As if someone has engineered a product to pass a test.

00:10:23.711 --> 00:10:24.071
<v Wojciech Węgrzyński>Huh?

00:10:24.360 --> 00:10:25.591
<v Andrea>no no not at all.

00:10:25.831 --> 00:10:26.591
<v Andrea>Not at all.

00:10:26.801 --> 00:10:27.750
<v Wojciech Węgrzyński>We never said that.

00:10:27.750 --> 00:10:27.990
<v Wojciech Węgrzyński>Okay.

00:10:27.990 --> 00:10:31.831
<v Wojciech Węgrzyński>Okay, . Well, it is like that Anyway.

00:10:31.907 --> 00:10:37.856
<v Wojciech Węgrzyński>to get to the bottom of, of why you've seen, uh, different performances in different condit.

00:10:38.298 --> 00:10:42.578
<v Wojciech Węgrzyński>Because that, that's also what I hear from my colleagues at laboratory.

00:10:42.578 --> 00:10:48.916
<v Wojciech Węgrzyński>That's why a slow heating, test was introduced because it's not, uh, secret knowledge anymore.

00:10:48.916 --> 00:10:53.078
<v Wojciech Węgrzyński>It's, it's recognized knowledge that, that they will behave differently at different, conditions.

00:10:53.408 --> 00:10:58.042
<v Wojciech Węgrzyński>So, to understand better why that happens, let, let's discuss how it works.

00:10:58.397 --> 00:11:00.427
<v Andrea Lucherini>So first of all, how will international coding.

00:11:02.131 --> 00:11:04.782
<v Andrea Lucherini>coatings I'm not a chemical engineer.

00:11:04.782 --> 00:11:05.772
<v Andrea Lucherini>I'm not a chemist.

00:11:05.802 --> 00:11:23.918
<v Andrea Lucherini>So what I usually take, I take the approach of a fire safety engineer or a structure of fire engineer that I take this magic formula I apply for my purpose keeping, for example, this, the temperature of, uh, protect of a steel column stay cooler than when it's unprotect.

00:11:24.176 --> 00:11:27.086
<v Andrea Lucherini>And then, take it and understand if does the job.

00:11:27.326 --> 00:11:30.147
<v Andrea Lucherini>That was my, the whole concept behind it.

00:11:30.986 --> 00:11:32.756
<v Andrea Lucherini>So what happens in the quoting itself?

00:11:32.756 --> 00:11:39.221
<v Andrea Lucherini>The quoting is made of different components, but usually you have three main components, which is an acid, an acid source.

00:11:39.431 --> 00:11:42.250
<v Andrea Lucherini>You have a carbon source, and then we have a blowing agent.

00:11:42.791 --> 00:11:48.821
<v Andrea Lucherini>So what happens typically, and now talking about, I did a bit of studies during my research experience.

00:11:48.821 --> 00:11:50.530
<v Andrea Lucherini>Now I've been working domestic quoting.

00:11:51.280 --> 00:11:53.441
<v Andrea Lucherini>For seven years, since 2015.

00:11:53.740 --> 00:11:57.551
<v Andrea Lucherini>So I've seen some INM coatings, but not all of them for sure.

00:11:57.760 --> 00:12:02.864
<v Andrea Lucherini>And uh, so around 200 degrees, let's say the acid starts sort of decomposing.

00:12:03.250 --> 00:12:06.820
<v Andrea Lucherini>and the coating where you can see the coating starts sort of melting or softening.

00:12:07.149 --> 00:12:09.460
<v Andrea Lucherini>So the viscosity of this distorting change.

00:12:10.000 --> 00:12:13.960
<v Andrea Lucherini>Then a certain temperature, usually 300 degrees or something like that.

00:12:14.259 --> 00:12:16.929
<v Andrea Lucherini>The blowing engine activates the blowing agent.

00:12:16.929 --> 00:12:19.210
<v Andrea Lucherini>What does releases, gases?

00:12:19.690 --> 00:12:21.879
<v Andrea Lucherini>These gases are released by the coating.

00:12:21.909 --> 00:12:28.299
<v Andrea Lucherini>And what happens since the coating is sort of melted or like a higher viscosity, what happens?

00:12:28.330 --> 00:12:34.539
<v Andrea Lucherini>The gas bubbles released by the blowing agent are trapped into this molten paint.

00:12:34.759 --> 00:12:40.573
<v Andrea Lucherini>So what happens is, Swelling by trapping these bubbles within its metrics.

00:12:40.783 --> 00:12:55.647
<v Andrea Lucherini>okay so this is at the base of it, and what happens is the quoting, something also I found during my PhD is, At the beginning, I didn't know how this work because what you see in a standard furnace test, you usually check the temperatures.

00:12:55.767 --> 00:12:56.187
<v Andrea Lucherini>Okay?

00:12:56.486 --> 00:13:03.927
<v Andrea Lucherini>A typically, you see this magic plateau that happens around 300, 350 degrees in your steel profile.

00:13:04.386 --> 00:13:13.716
<v Andrea Lucherini>And what happens is that decoding by that temperatures are mentioned, the blowing engine activates so the quoting starts swelling So what it does is start having a sort.

00:13:14.195 --> 00:13:22.261
<v Andrea Lucherini>We call it endothermic plateau, but it's not a proper endothermic reaction because endothermic reaction, it's usually, you know, a reaction that absorbs a lot of heat.

00:13:22.741 --> 00:13:29.534
<v Andrea Lucherini>But in this case, the reaction takes some heat and uses to make the coating swelling.

00:13:29.565 --> 00:13:35.121
<v Andrea Lucherini>And what this welding does brings the fire fire from whatever you want to.

00:13:36.022 --> 00:13:40.514
<v Andrea Lucherini>Then once you achieve these, temperature, the quoting start degrading.

00:13:40.934 --> 00:13:43.424
<v Andrea Lucherini>So it happens something similar to timber.

00:13:43.815 --> 00:13:46.065
<v Andrea Lucherini>So what you ever since is a high carbon.

00:13:46.094 --> 00:13:46.945
<v Andrea Lucherini>In the coating.

00:13:46.975 --> 00:13:51.985
<v Andrea Lucherini>So usually also this helps you in how it looks like as in color.

00:13:52.134 --> 00:13:54.414
<v Andrea Lucherini>Usually the coating, the classic one is white.

00:13:55.075 --> 00:13:57.355
<v Andrea Lucherini>Then when you're supposed to heat, becomes black.

00:13:57.595 --> 00:14:00.235
<v Andrea Lucherini>So it's a very high in carbon and there are certain points.

00:14:00.240 --> 00:14:03.235
<v Andrea Lucherini>Start again, becoming white and extremely brittle.

00:14:03.774 --> 00:14:06.921
<v Andrea Lucherini>What happens happens, the classic oxidation at the surface.

00:14:07.198 --> 00:14:07.619
<v Wojciech Węgrzyński>Hmm.

00:14:07.823 --> 00:14:18.559
<v Andrea Lucherini>Carbon is released, oxidizes is really through co2, but also carbon is what keeps the quoting together and therefore de quoting becomes, uh, you know, weaker.

00:14:18.710 --> 00:14:23.179
<v Andrea Lucherini>Some parts start the touching, But also as happens to timber, what happens?

00:14:23.179 --> 00:14:29.269
<v Andrea Lucherini>You have regression of the surface, So at the beginning it start as wells And then little beli start retracting as well.

00:14:29.955 --> 00:14:30.389
<v Wojciech Węgrzyński>Yeah.

00:14:30.438 --> 00:14:35.538
<v Wojciech Węgrzyński>this is a very, very visual, um, description and I, I like how the mechanism works.

00:14:35.538 --> 00:14:43.081
<v Wojciech Węgrzyński>Like if you have a, Heat transferred to a solid, you would have some sort of thermal conductivity, the difference of temperatures and, and the distance.

00:14:43.461 --> 00:14:49.802
<v Wojciech Węgrzyński>And here, uh, of course you probably modified the thermal conductivity to some extent, but the distance is the part where you act.

00:14:49.812 --> 00:15:02.375
<v Wojciech Węgrzyński>So suddenly instead of few millimeters of pain or, or coating, you have 20, 30, 50 millimeters of a foamed material with CAEs trapped inside, which are very good insulator that are the layer between you and the fire.

00:15:02.647 --> 00:15:27.422
<v Andrea Lucherini>So yeah, this is the tricky part of, you know, when you try to quantify, you know, the performance of interes coatings, because if you're trying to quantify the firm resistance, how it's defined, Thermal resistance is both, You have both thermal conductivity and thickness including to that, it's easy because you take a sort of bike, thermal resistance of thermal protecting property of the material to protect the substrate.

00:15:27.884 --> 00:15:38.351
<v Andrea Lucherini>Once you, instead you wanna define the thermal conductivity, then it becomes tricky because to define the the conductivity means you need to know the thickness all the time or otherwise.

00:15:38.351 --> 00:15:39.011
<v Andrea Lucherini>What people.

00:15:39.777 --> 00:15:46.990
<v Andrea Lucherini>Typically the methodology is also using the Euro code, um, for, e N 1 1 3 8, 1 part eight.

00:15:47.350 --> 00:15:57.326
<v Andrea Lucherini>So in, in one of the nex, you can quantify sort of implicitly effectively what is the conductivity by considering the initial thickness of the quoting.

00:15:57.417 --> 00:16:03.927
<v Andrea Lucherini>So you have this sort of fake ther conductivity because it takes into account everything that happens in the.

00:16:04.471 --> 00:16:10.559
<v Wojciech Węgrzyński>That's, uh, almost in particle physics, you cannot tell how quickly an election moves over where it is at the same time.

00:16:10.659 --> 00:16:16.200
<v Wojciech Węgrzyński>You either can measure the thermal conductivity or the, or all the length, not, not bow at the same time.

00:16:16.200 --> 00:16:17.433
<v Wojciech Węgrzyński>What's an interesting, twist?

00:16:17.529 --> 00:16:18.423
<v Wojciech Węgrzyński>to, to solve, uh,

00:16:18.787 --> 00:16:22.236
<v Andrea Lucherini>I mean, this is what I did during my PhD, was one of my goals.

00:16:22.700 --> 00:16:33.147
<v Andrea Lucherini>I mean, what happens within domestic quotings the problem also, what fascinate me is that such a complicated, uh, topic because of all, you know, people usually associate into messing code.

00:16:34.182 --> 00:16:35.682
<v Andrea Lucherini>Active fire protection.

00:16:35.741 --> 00:16:37.211
<v Andrea Lucherini>Passive fire protection.

00:16:37.302 --> 00:16:49.294
<v Andrea Lucherini>I usually like to define it as a reactive fire protection because it's not unactive because you don't have to activate, like, you know, a fire extinguisher is not a passive that is a a board that stays there all the time.

00:16:49.475 --> 00:16:54.815
<v Andrea Lucherini>It's something that reacts a, since it reacts, we should consider that.

00:16:54.875 --> 00:16:59.961
<v Andrea Lucherini>You know, there are many aspects that could be affected that could affect the reaction and.

00:17:00.409 --> 00:17:09.614
<v Andrea Lucherini>And what I found also doing at the beginning of my PhD doing a bit of literature review, I found out that there is a lot of things that, influence, the domestic coding behavior.

00:17:09.886 --> 00:17:11.686
<v Andrea Lucherini>Uh, I can make some examples.

00:17:11.747 --> 00:17:17.027
<v Andrea Lucherini>Uh, I dunno if you're interested in mo, most of them I can talk about domestic coding as much as you want,

00:17:17.356 --> 00:17:18.836
<v Wojciech Węgrzyński>Worst case, I'll cut them out.

00:17:19.029 --> 00:17:19.519
<v Andrea>Yeah.

00:17:20.914 --> 00:17:26.811
<v Andrea Lucherini>I mean, first of all, it is, I'm not an expert, but first, main thing that influences the whole story is the composition.

00:17:27.531 --> 00:17:28.491
<v Andrea Lucherini>Is the composition.

00:17:28.491 --> 00:17:41.481
<v Andrea Lucherini>But this is something that I didn't dig into detail because I took, as I said earlier, the approach of a fire safe engineer structure fire engineer, take a product, understand does this quoting work or not?

00:17:41.842 --> 00:17:42.501
<v Andrea Lucherini>That's the question.

00:17:42.517 --> 00:17:47.904
<v Andrea Lucherini>question Then, Start looking at what are the variables that could affect Theas coating behavior.

00:17:48.352 --> 00:17:52.011
<v Andrea Lucherini>The first one is the classic one you discussed also far is the heating conditions.

00:17:52.551 --> 00:17:53.511
<v Andrea Lucherini>Heating conditions.

00:17:53.541 --> 00:17:58.251
<v Andrea Lucherini>That is also considered, as you know, overall fire conditions or testing conditions.

00:17:58.747 --> 00:18:05.136
<v Andrea Lucherini>Because you can apply, uh, heat flux that is pure radiant using a cone or RA panel.

00:18:05.436 --> 00:18:09.884
<v Andrea Lucherini>You can apply, mix of radiative and convective in a a standard furnace.

00:18:10.222 --> 00:18:17.230
<v Andrea Lucherini>but also one of the key aspects also influences as many other aspects in far safety engineering is oxygen content.

00:18:17.569 --> 00:18:25.160
<v Andrea Lucherini>What people have seen that, you know, in, for example, during my PhD I used some radio panels, so very high oxygen content around the coat.

00:18:25.954 --> 00:18:31.595
<v Andrea Lucherini>It's completely different situation than having a fairness when you have relatively low oxygen content within that.

00:18:32.194 --> 00:18:43.825
<v Andrea Lucherini>and for example, you know, if you have a low oxygen content, what I was discussing earlier about oxidation and char regression and what happens, you have a much lower, uh, phenomena if you have a low oxygen.

00:18:44.265 --> 00:18:51.855
<v Andrea Lucherini>then, so as I mentioned, heat test methods in general, but also heating conditions, fast growing, fire temperature, heat flexes, and things like that.

00:18:52.275 --> 00:19:01.025
<v Andrea Lucherini>Then another main importance is the thickness, and, uh, mainly how much coating you apply because sort of defines the mass and the quantity of your coating.

00:19:01.595 --> 00:19:05.674
<v Andrea Lucherini>Then you have the substrate conditions that I also look into that a bit during my PhD.

00:19:06.114 --> 00:19:16.875
<v Andrea Lucherini>. and also we can discuss this, it was another very hot topic of interes coatings is that, you know, we always test interes coatings when they are perfect virgin and just applied.

00:19:17.305 --> 00:19:25.219
<v Andrea Lucherini>But what happens since it's a reactive material, what happened to the reaction in a 5, 10, 20 years time?

00:19:25.338 --> 00:19:28.669
<v Andrea Lucherini>Because usually design buildings for, I dunno, a design life of 50.

00:19:29.211 --> 00:19:35.359
<v Andrea Lucherini>We need to make sure that that reaction at that material works also in a 50 years time.

00:19:35.806 --> 00:19:40.960
<v Wojciech Węgrzyński>In our lab, when we do the tests, we do this artificial, aging of the coating.

00:19:41.210 --> 00:19:41.819
<v Andrea>Mm-hmm.

00:19:41.990 --> 00:19:51.140
<v Wojciech Węgrzyński>Uh, by exposing it to different, uh, conditions, salt, radiation, tra violet, uh, water, and so on.

00:19:51.150 --> 00:20:05.131
<v Wojciech Węgrzyński>So when they come, and the part that comes for, for the age testing doesn't look very white or  or nice to, to be honest, but it is always a question like, to what extent this, this, uh, gives us A feeling of what happens.

00:20:05.651 --> 00:20:07.023
<v Wojciech Węgrzyński>Actually, I, I'll tell you a funny story.

00:20:07.037 --> 00:20:10.967
<v Wojciech Węgrzyński>it's not about paint, but more like the oxycodine that you've mentioned before.

00:20:11.457 --> 00:20:22.990
<v Wojciech Węgrzyński>We had a client, um, they've purchased an old building in Warsaw, not super old, but let's say mid medium old, which had a steel structure protected by, uh, coatings.

00:20:23.420 --> 00:20:32.609
<v Wojciech Węgrzyński>And, uh, they wanted to see, uh, what is  how, how does it really look like, Is this, uh, steel structure underneath very healthy or unhealthy?

00:20:32.609 --> 00:20:33.849
<v Wojciech Węgrzyński>What stage is it in?

00:20:34.259 --> 00:20:37.210
<v Wojciech Węgrzyński>So they basically, um, went into the structures.

00:20:37.210 --> 00:20:39.170
<v Wojciech Węgrzyński>Some parts, they just cut out with the steel.

00:20:39.480 --> 00:20:45.569
<v Wojciech Węgrzyński>Some parts, they just open the hole in the coating just to change the, uh, what's the corrosion underneath.

00:20:45.569 --> 00:20:47.769
<v Wojciech Węgrzyński>So they've opened like a hundred samples under.

00:20:48.045 --> 00:20:51.444
<v Wojciech Węgrzyński>30 or 40 year old still structure protected with that coating.

00:20:51.944 --> 00:20:55.565
<v Wojciech Węgrzyński>And then they, they come to us and like, okay, and what do we do now?

00:20:56.065 --> 00:20:59.404
<v Wojciech Węgrzyński>How are we supposed to fill the gaps we just made?

00:20:59.694 --> 00:21:01.924
<v Wojciech Węgrzyński>Because the coating is not existent.

00:21:01.924 --> 00:21:11.174
<v Wojciech Węgrzyński>We have a 30 year old material on the building, so you cannot just plump, a, a spec of, of very fresh coating inside and, and, uh, expect the exact same behavior.

00:21:11.335 --> 00:21:13.974
<v Wojciech Węgrzyński>There is no paperwork that would allow it.

00:21:14.144 --> 00:21:22.340
<v Wojciech Węgrzyński>It was like, okay, I shouldn't laugh at it, but it, ended up as being quite a hilarious issue because the, the, the steel was very healthy, , no damage at all.

00:21:22.401 --> 00:21:28.300
<v Wojciech Węgrzyński>But now they ended up with, uh, with a structure with tons of holes in their fire protection.

00:21:28.884 --> 00:21:35.304
<v Andrea Lucherini>there is a bit of research related to that, that did the University of Naples in Italy, that they look into what happens.

00:21:35.394 --> 00:21:40.884
<v Andrea Lucherini>So they took like an existing structure they publish in construction building materials, very interesting research.

00:21:41.364 --> 00:21:45.400
<v Andrea Lucherini>And they look at how was reactive the quoting 30 years later.

00:21:45.508 --> 00:21:53.307
<v Andrea Lucherini>And what they saw is that, you know, the coating was not in the best state and you could never, you know, assume the same performance as a virgin quo.

00:21:53.646 --> 00:22:02.346
<v Andrea Lucherini>But also they showed that, you know, the quoting could be removed and reapplied, but also it could be also applied an additional layer on top of it and will still be

00:22:02.557 --> 00:22:03.076
<v Andrea>effective.

00:22:03.207 --> 00:22:04.616
<v Wojciech Węgrzyński>Okay, that's interesting.

00:22:05.007 --> 00:22:07.057
<v Wojciech Węgrzyński>Like, uh, you have an old one.

00:22:07.267 --> 00:22:10.537
<v Wojciech Węgrzyński>As long as you have adhesion for the new one, you can apply the new one.

00:22:10.557 --> 00:22:11.227
<v Andrea>exactly.

00:22:11.497 --> 00:22:11.987
<v Andrea>Yeah.

00:22:12.102 --> 00:22:17.481
<v Wojciech Węgrzyński>but you, you cannot like just apply a giant amount of it because it is quite fragile.

00:22:17.571 --> 00:22:18.979
<v Wojciech Węgrzyński>It, it, it will start falling.

00:22:19.325 --> 00:22:22.275
<v Wojciech Węgrzyński>there's a reason why they tell you like what's the, the layer.

00:22:22.275 --> 00:22:36.267
<v Wojciech Węgrzyński>It's not just the, about the minimum amount of, coding that you apply, but it's also in a way optimal because if you overshoot that, You will also, by force of gravity, it'll, it'll damage, to finish out the, the, um, chemistry and, and heat transfer part.

00:22:36.676 --> 00:22:44.656
<v Wojciech Węgrzyński>So you've mentioned that at around 200 degrees, uh, there would be the action of the acs that, um, makes it softer so the bubbles can actually.

00:22:45.085 --> 00:22:46.785
<v Wojciech Węgrzyński>alter the, material.

00:22:46.785 --> 00:22:56.384
<v Wojciech Węgrzyński>Then at 300 s you would have the blowing material go on, but what happens if it hits up to 200 and just stops for an hour, like traveling fire

00:22:57.150 --> 00:23:19.547
<v Andrea Lucherini>Yeah this is, uh, you know, an interesting topic and, I did a bit of research during my PhD because I was interested about that and, uh, because at the back of that, we had some research that was carried out by my PhD supervisor or Chris Maluk at the the University of Edinborough, that what they saw is that having a, potentially a, let's call it a low growing fire or a preheating.

00:23:20.148 --> 00:23:24.313
<v Andrea Lucherini>In Certain coatings might create specific weakness into that.

00:23:24.500 --> 00:23:31.339
<v Andrea Lucherini>And uh, what they saw is that, for example, that, uh, the coating if it was exposed to slow heating, it would, uh, laminate.

00:23:31.586 --> 00:23:39.242
<v Andrea Lucherini>because what happens, you start melting it and then once is melted, the blowing agent and the gases cannot be trapped.

00:23:39.333 --> 00:23:40.472
<v Andrea Lucherini>So you sort of break

00:23:40.532 --> 00:23:40.893
<v Andrea>the.

00:23:41.371 --> 00:23:41.765
<v Andrea>And

00:23:41.924 --> 00:23:44.015
<v Andrea Lucherini>a sort of process of, cooking off de coating.

00:23:44.204 --> 00:23:51.832
<v Andrea Lucherini>Like uh, when you cook something in your oven at the brown temperature, you know, and then for example, a cake doesn't grow, it works in the same concept.

00:23:52.568 --> 00:23:57.214
<v Andrea Lucherini>so I try to do a bit of tests and a bit of experiments even in life.

00:23:57.214 --> 00:24:03.035
<v Andrea Lucherini>It was like a qualitative and, uh, I was surprised because the quoting I used was working very well.

00:24:03.154 --> 00:24:10.397
<v Andrea Lucherini>Even if I cooked the, coating for about an hour at the heat flux that the would nots well was about 10 kilowatts.

00:24:10.397 --> 00:24:12.768
<v Andrea Lucherini>So usually it's like for low temperatures.

00:24:13.218 --> 00:24:30.307
<v Andrea Lucherini>Then the coating was keep swelling even after the preheating or pre-cooking face But this is again, what I found out is in, within my PhD I look into certain and a certain amount of my history, I've look into certain.

00:24:30.313 --> 00:24:30.847
<v Andrea Lucherini>product.

00:24:31.319 --> 00:24:41.549
<v Andrea Lucherini>Products are continuously optimized, created, commercialized that is very hard to keep up with all the coatings that are produced and sold in the world.

00:24:41.799 --> 00:24:46.232
<v Andrea Lucherini>This is one actually of the main shortcomings of my PhD that I mentioned I did.

00:24:46.623 --> 00:24:52.200
<v Andrea Lucherini>At the base of that, I took one quoting and I did experiments to understand the fundamental aspects of deco.

00:24:52.670 --> 00:25:18.359
<v Andrea Lucherini>But then the next step that has to be done is that to take the same concept and to see if this concept can be applied to also all the others, most likely for some, not for some, yes, but is tricky and challenging particularly because one of the problem we have with international coating research is that it's very hard and typically the name of the product are not closed.

00:25:18.666 --> 00:25:22.507
<v Andrea Lucherini>Because these magic formulations are usually hidden.

00:25:22.987 --> 00:25:30.626
<v Andrea Lucherini>And, manufacturers, they care a lot about protecting potentially their, you know, IP related to, the, the coating.

00:25:31.076 --> 00:25:34.737
<v Andrea Lucherini>And they can have, you know, good advertisement from successful tests.

00:25:34.737 --> 00:25:43.826
<v Andrea Lucherini>They can have bad advertisement, but usually you see, find a lot of tests, but usually you never know if they're connected to a product, another product or things like

00:25:43.886 --> 00:25:44.247
<v Andrea>like that.

00:25:44.471 --> 00:25:57.907
<v Andrea Lucherini>In a short, that's one of the hardest part of working in this field because you have, uh, you know, all these proprietary requirements that it's hard to compare or extend your study to other materials and,

00:25:57.998 --> 00:25:58.278
<v Andrea>uh,

00:25:58.490 --> 00:26:31.067
<v Wojciech Węgrzyński>when we talk about the behavior of steel or concrete, it's usually like you don't need very much to have quite well defined the material to have full reproducibility of the results in another laboratory when you talk about something, uh, so highly, uh, Protected, as you said, it's an i, there's a lot of chemistry inside, you know, so, so it's the IP of the manufacturer, of the paint, uh, or, or the coating, I guess It's these tiny details that, that might or break a certain application of the, of the coding.

00:26:31.218 --> 00:26:40.731
<v Wojciech Węgrzyński>Like you, you've mentioned with early in your master thesis research where you had like to change the one water base, one solvent base outcome.

00:26:40.731 --> 00:26:50.051
<v Wojciech Węgrzyński>So, so far from each other, uh, going forward with, uh, how this works in the buildings, I wondered what happens.

00:26:50.142 --> 00:26:50.382
<v Andrea>happens?

00:26:50.832 --> 00:26:52.271
<v Wojciech Węgrzyński>Swelling coating means an obstacle.

00:26:52.311 --> 00:27:04.912
<v Wojciech Węgrzyński>Let's say there's a concrete beam or something next to a steel column that blocks it in a way so you cannot expand to the certain thickness or, or, or someone puts an obstacle,

00:27:05.223 --> 00:27:18.182
<v Andrea Lucherini>Yeah, I mean this is a super interesting topic and uh, we also did a bit of studies at the Uq, University of Queensland in Australia during my PhD, because we are completely asked about this.

00:27:18.442 --> 00:27:30.771
<v Andrea Lucherini>What I can tell you is that first of all, manufacturers usually suggest potentially a minimum distance at which any obstacle can be applied in front of, into mass quo.

00:27:30.936 --> 00:27:31.623
<v Andrea Lucherini>element.

00:27:32.163 --> 00:27:38.757
<v Andrea Lucherini>And tho that also this is related to, for example, the, if we discuss about fin and thick into mass coatings.

00:27:39.267 --> 00:27:46.386
<v Andrea Lucherini>Cause fin interes coatings uh, literature says that can swell up to a hundred times their original thickness.

00:27:46.446 --> 00:27:50.436
<v Andrea Lucherini>So from few millimeters they go to 10 20 cent.

00:27:51.288 --> 00:27:55.758
<v Andrea Lucherini>While thin intermission coatings, they usually as well, you know, 15, 20 times their.

00:27:55.758 --> 00:27:56.268
<v Andrea Lucherini>thickness.

00:27:56.627 --> 00:28:11.867
<v Andrea Lucherini>So what people usually suggest manufacture to avoid this problem is they suggest that at least the 50 diameters they have to be left free In the case of thin interes coatings or 10 20 diameters in the case of thick domestic

00:28:12.387 --> 00:28:12.877
<v Andrea>what

00:28:13.182 --> 00:28:28.732
<v Andrea Lucherini>actually happens is that at the base of all that, and what I found during my PhD is that, domestic coatings, Their amazing characteristics and amazing protective, performance is based on the swelling, is based on the concept of taking the fire away from the

00:28:28.833 --> 00:28:29.369
<v Andrea>the substrate.

00:28:29.997 --> 00:28:33.500
<v Andrea Lucherini>If you stop this dwelling, then you immediately have a

00:28:33.579 --> 00:28:33.980
<v Andrea>a weakness.

00:28:34.215 --> 00:28:34.623
<v Andrea>And

00:28:34.702 --> 00:28:39.429
<v Andrea Lucherini>found this by doing some certain experiments at University of Queensland that we applied.

00:28:39.429 --> 00:28:41.583
<v Andrea Lucherini>sort of heat flux on the surface of the quoting.

00:28:41.583 --> 00:28:48.512
<v Andrea Lucherini>We used a mesh to sort of block the swelling, and we saw that mainly since the, also the obstacle heats up.

00:28:48.782 --> 00:28:56.230
<v Andrea Lucherini>so it also increases the conductive heat transfer for the coating then you you're ever, of course, a lower, performance.

00:28:56.740 --> 00:28:59.416
<v Andrea Lucherini>But then I also always wonder that.

00:28:59.416 --> 00:29:05.497
<v Andrea Lucherini>we should always, always think in engineer in terms in terms of if there is an obstacle, is gonna be the fire.

00:29:05.636 --> 00:29:11.156
<v Andrea Lucherini>Reaching the structure or the protected element because certain aspects can fall.

00:29:11.186 --> 00:29:32.896
<v Andrea Lucherini>You know, if you have a, a aluminum, uh, sheet on top in front of it, we know a aluminum would potentially melt at relatively low temperatures compared to, you know, a temperature where the steel structure can be So I think we have to also think a bit, you know, in engineering terms, solve the overall problem It potentially, you know, the obstacle can also block the fire, not just

00:29:32.906 --> 00:29:33.426
<v Andrea>just as well.

00:29:33.448 --> 00:29:35.317
<v Wojciech Węgrzyński>it will also shield from ation in a way.

00:29:35.317 --> 00:29:44.075
<v Wojciech Węgrzyński>It's, uh, it's a way more complicated, manner than just, it's present, but does the swelling, um, Like, is there a force in this swelling?

00:29:44.105 --> 00:29:46.795
<v Wojciech Węgrzyński>I dunno how to precisely tell it.

00:29:46.795 --> 00:29:51.835
<v Wojciech Węgrzyński>Like can it push an object away if I put a bottle of water next to a wall and it's

00:29:52.250 --> 00:30:00.017
<v Andrea Lucherini>like What I can tell you is that if we discuss about big numbers it's like feeding domestic coatings are applied in terms of millimeters Okay?

00:30:00.376 --> 00:30:09.616
<v Andrea Lucherini>So few millimeters about you know, depends on the coating, but 40, 50%, 60% are potentially made of volatile.

00:30:10.666 --> 00:30:13.576
<v Andrea Lucherini>are this blowing agent that will blow the gases.

00:30:13.576 --> 00:30:16.727
<v Andrea Lucherini>And so we discuss about densities.

00:30:17.086 --> 00:30:23.762
<v Andrea Lucherini>when, of this, wild coating of about 50, a hundred kilos per cubic meter.

00:30:24.663 --> 00:30:29.972
<v Andrea Lucherini>So it's not anything tough or robust that is pushing things away.

00:30:30.182 --> 00:30:30.512
<v Andrea Lucherini>No.

00:30:30.512 --> 00:30:32.584
<v Andrea Lucherini>The quoting is very fragile when actually ass

00:30:32.748 --> 00:30:34.097
<v Andrea>swells, and actually

00:30:34.133 --> 00:30:35.042
<v Andrea Lucherini>actually when it's oxidized, it's

00:30:35.178 --> 00:30:36.082
<v Andrea>even weaker.

00:30:36.451 --> 00:30:37.801
<v Andrea Lucherini>So sometime you can just

00:30:38.001 --> 00:30:39.122
<v Andrea>blow it and it

00:30:39.287 --> 00:30:41.287
<v Wojciech Węgrzyński>that, that, that was where I was going with it.

00:30:41.836 --> 00:30:50.751
<v Wojciech Węgrzyński>to what extent it's fragile in a real case of fire, like next to a fire plume, you can have seven, eight meters per second of airflow just because of the convective action.

00:30:50.751 --> 00:30:54.872
<v Wojciech Węgrzyński>But I see them being used like near jet fans in car parks.

00:30:55.886 --> 00:30:57.826
<v Wojciech Węgrzyński>Jet fund outlet 20 meters per second.

00:30:58.267 --> 00:30:58.386
<v Wojciech Węgrzyński>Hmm.

00:30:58.386 --> 00:30:59.646
<v Wojciech Węgrzyński>That's, that's a lot.

00:31:00.067 --> 00:31:04.086
<v Wojciech Węgrzyński>And it looks fragile to me if I, if I look at it.

00:31:04.086 --> 00:31:11.492
<v Wojciech Węgrzyński>I wondered, have you ever observed in your research, like, in a way, mechanical failure of, of a coating like being blown away from the protected element?

00:31:11.873 --> 00:31:17.063
<v Andrea Lucherini>I mean, what happens in in furnace, usually you don't have requirements in, you know, velocities.

00:31:17.339 --> 00:31:20.519
<v Andrea Lucherini>So it is something that you sort of implicitly see.

00:31:20.970 --> 00:31:26.549
<v Andrea Lucherini>Because when you open the furnace at the end of the test, you see some parts of the coating that are detached on the floor.

00:31:26.789 --> 00:31:29.369
<v Andrea Lucherini>You were even, like, sucked away from, uh,

00:31:29.400 --> 00:31:30.039
<v Andrea>uh, the exhaust.

00:31:30.603 --> 00:31:40.323
<v Andrea Lucherini>But an interesting study that I studied during my PhD was a study that I did in 2016 at the Rise, and there was, um, Robert Johnson

00:31:40.403 --> 00:31:41.202
<v Andrea>and McNair

00:31:41.643 --> 00:31:55.803
<v Andrea Lucherini>uh, that they sort of did a sort of bench skill test and they created some sort of, jet flame scenario and they expose some coatings, to, uh, far scenario and the so that, yeah, the quoting would touch pretty easily.

00:31:56.140 --> 00:31:57.519
<v Andrea Lucherini>so it's definitely a weakness.

00:31:58.089 --> 00:32:04.599
<v Andrea Lucherini>How to quantify what's the stent of this weakness is something that is, uh, extremely complicated and, uh, I

00:32:04.755 --> 00:32:05.994
<v Andrea>I haven't investigated during my.

00:32:06.460 --> 00:32:17.359
<v Wojciech Węgrzyński>Now what comes to my mind that there are interes materials would also be often used for cavity barriers, Ceiling in facades and in in, a cavity of facade you can have fairly high, um,

00:32:18.325 --> 00:32:18.815
<v Andrea>It's

00:32:18.920 --> 00:32:23.400
<v Wojciech Węgrzyński>of air just because of the, the convective airstream.

00:32:24.049 --> 00:32:32.349
<v Wojciech Węgrzyński>Wow, this is, this is going well, . I, I, I love the world of magical paint to be Okay, let's, let's go further.

00:32:32.759 --> 00:32:38.173
<v Wojciech Węgrzyński>Uh, next thing on my list, you, you mentioned you were testing them in a furnaces.

00:32:38.353 --> 00:32:45.532
<v Wojciech Węgrzyński>You were using h TRIS uh, I guesses, which is, uh, a radiant panel in front of, of this.

00:32:46.063 --> 00:32:50.269
<v Wojciech Węgrzyński>These are fairly small, uh, scale, uh, test, units.

00:32:51.039 --> 00:32:56.910
<v Wojciech Węgrzyński>Do you have an experience with the behavior of this in, uh, like a full scale in like a compartment setting?

00:32:57.980 --> 00:33:01.880
<v Wojciech Węgrzyński>I guess there are also like real case fires where this where this worked.

00:33:01.880 --> 00:33:05.440
<v Wojciech Węgrzyński>Basically, if it didn't work in the real fires, we would know already, I guess.

00:33:05.650 --> 00:33:06.166
<v Andrea Lucherini>Yeah.

00:33:06.166 --> 00:33:06.376
<v Andrea Lucherini>Okay.

00:33:06.376 --> 00:33:18.707
<v Andrea Lucherini>First of all, during my PhD, I tested in a bench scale set up because what I started as the idea is that I mentioned earlier that domestic coding behavior is affected by many different aspects.

00:33:19.369 --> 00:33:33.811
<v Andrea Lucherini>what I wanted to do, I wanted to take Quoting apply on a very well defined thermo boundary conditions, both at the surface but also the substrate, and to see as soon as I change certain aspects, how their quoting behave.

00:33:34.231 --> 00:33:47.698
<v Andrea Lucherini>So what I found out is that I was using, mainly using steel plates coated with different, thicknesses of interes coating, and I was changing the thermo boundary conditioner surface, the far scenario, and also the thermo boundary conditions at

00:33:47.837 --> 00:33:48.397
<v Andrea>the subs.

00:33:48.571 --> 00:33:49.109
<v Wojciech Węgrzyński>Mm-hmm.

00:33:49.305 --> 00:34:00.607
<v , Andrea Lucherini>I found out that first of all, their far scenario, the heating condition, what they control, they control the dwelling rate and also the dwelling rate means how fast this coatings wells.

00:34:00.968 --> 00:34:06.548
<v , Andrea Lucherini>But also, I also found out, and I try to define which are the condition to make the quotings.

00:34:07.373 --> 00:34:12.233
<v , Andrea Lucherini>Because there are some conditions that you know, below a certain temperature or below a certain heat flux.

00:34:12.322 --> 00:34:13.402
<v , Andrea Lucherini>the quoting does as well.

00:34:13.733 --> 00:34:19.822
<v , Andrea Lucherini>And I call it, I have a study and a paper related to that focus on onset as swelling of interes coatings.

00:34:20.019 --> 00:34:31.829
<v , Andrea Lucherini>Then I was looking at the thickness of the, the initial thickness of the quoting and what I found out, if you fix the thermal boundary condition the heating condition of the quoting, what the thickness.

00:34:32.516 --> 00:34:35.847
<v , Andrea Lucherini>Evaluate how much the quoting can, Well, potentially.

00:34:35.996 --> 00:34:40.766
<v , Andrea Lucherini>Well, because this is a sort of like, you know, mass balance, you have a certain amount of mass.

00:34:41.036 --> 00:34:42.777
<v , Andrea Lucherini>The quoting can, well, a certain amount.

00:34:43.016 --> 00:34:52.867
<v , Andrea Lucherini>Therefore the, I found that with a linear relationship within the range of the tested, that the maximums weld quoting thickness can be related to the initial.

00:34:53.452 --> 00:34:53.838
<v Andrea>Okay.

00:34:54.059 --> 00:35:10.139
<v Andrea Lucherini>And then also I did the last aspect about the thermal boundary condition, the substrate, because this came out and we can discuss later that now into messing coatings, they are pushed to be applied also to other, not just steel, but also other substrate materials, timber, concrete, things like that.

00:35:10.769 --> 00:35:13.523
<v Andrea Lucherini>What happens you change by changing the material.

00:35:13.523 --> 00:35:20.552
<v Andrea Lucherini>You change the thermal properties of how this material would behave, particularly would behave close to the surface of the mater.

00:35:21.023 --> 00:35:24.293
<v Andrea Lucherini>Therefore where the coating seats and where the coatings Well,

00:35:24.307 --> 00:35:24.547
<v Andrea>Well

00:35:24.717 --> 00:35:38.503
<v Andrea Lucherini>and what I found out that we can discuss in the case of high insulated material so heat doesn't penetrate through the material, then the coatings wells much faster because mainly all the heat is concentrated at a coating and this is the case, for example, of timber.

00:35:39.373 --> 00:35:43.623
<v Andrea Lucherini>Then if you have the case of a fixed steel plate, that this is a.

00:35:43.927 --> 00:35:52.567
<v Andrea Lucherini>lumped the heat because still as a high thermal inertia, so it has to heat up gradually, so therefore this violin behaves slower.

00:35:53.347 --> 00:35:58.210
<v Andrea Lucherini>Then if you have something we, we did, I did a study on a, on a heat sink.

00:35:58.269 --> 00:36:01.420
<v Andrea Lucherini>So there was a, a steel plate and at the back.

00:36:01.420 --> 00:36:03.639
<v Andrea Lucherini>I had a sort of radiator system.

00:36:03.940 --> 00:36:10.213
<v Andrea Lucherini>There was a steel plate that there was cooled with uh, water and it was taking heat away the other side and what I found.

00:36:10.887 --> 00:36:25.318
<v Andrea Lucherini>The quoting, all the heat I was receiving, the quoting was actually leaving the quoting because it was, there was like a, you know, it's a sort of energy balance at the quoting is the energy come that comes from the fire and the energy that leads from the substrate.

00:36:25.858 --> 00:36:29.137
<v Andrea Lucherini>So you have to do an energy balance of that and you can understand how the quotings

00:36:29.177 --> 00:36:29.257
<v Andrea>well.

00:36:30.277 --> 00:36:30.827
<v Wojciech Węgrzyński>Oh man.

00:36:31.237 --> 00:36:45.597
<v Wojciech Węgrzyński>I find, Biot number, annoying enough as it is, and if you add now, uh, to the problem, the, the fact that your dimension changes with time as this progresses and your Biot number most likely changes as well as it progresses.

00:36:46.126 --> 00:36:49.637
<v Wojciech Węgrzyński>Oh boy, that's, um, the complexity of fire.

00:36:49.822 --> 00:37:03.987
<v Andrea Lucherini>So that's that was a mention that all the different aspect that, changes it and this is the case of, one D heat transfer is a plate with a hot surface on one side and some sort of thermo band conditions, a substrate.

00:37:04.244 --> 00:37:05.534
<v Andrea Lucherini>Then going back to your question.

00:37:06.333 --> 00:37:07.862
<v Andrea Lucherini>What happens in large scale?

00:37:07.902 --> 00:37:11.023
<v Andrea Lucherini>In the large scale, you have another bunch of effect, uh, phenomena.

00:37:11.112 --> 00:37:15.782
<v Andrea Lucherini>Not just to mention, you know, in a compartment five, you might have convected gases, so you might

00:37:15.862 --> 00:37:16.623
<v Andrea>might have speeds.

00:37:17.043 --> 00:37:26.103
<v Andrea Lucherini>I mentioned about different level of oxygens, but also another aspects that the found is also some research related to that is the shape of the substrate.

00:37:26.251 --> 00:37:29.820
<v Andrea Lucherini>Because what you can imagine, if you have a concave or a

00:37:30.000 --> 00:37:31.079
<v Andrea>a convex angle

00:37:31.619 --> 00:37:37.650
<v Andrea Lucherini>with the coat, Then you can have, you know, in a concave angle, you have a much more coating than the surface

00:37:37.684 --> 00:37:38.394
<v Andrea>to protect.

00:37:39.090 --> 00:37:43.619
<v Andrea Lucherini>Therefore they have a much more coating and that angle will be nicely protected.

00:37:44.190 --> 00:37:48.000
<v Andrea Lucherini>Instead, if you have, for example, the top or the bottom fla

00:37:48.525 --> 00:37:48.994
<v Andrea>on a

00:37:49.059 --> 00:37:53.809
<v Andrea Lucherini>beam is a sort of very, rough, uh, acute angle.

00:37:54.469 --> 00:37:59.090
<v Andrea Lucherini>Then in that case you have very little coating, but a very big surface to.

00:37:59.885 --> 00:38:00.125
<v Andrea Lucherini>It's

00:38:00.414 --> 00:38:01.175
<v Andrea>geometry, you know?

00:38:01.445 --> 00:38:04.927
<v Wojciech Węgrzyński>Must be fun for, for circular, like, circular beam, uh, pipe.

00:38:04.927 --> 00:38:05.271
<v Wojciech Węgrzyński>Sorry.

00:38:05.271 --> 00:38:11.907
<v Andrea Lucherini>yeah that's also in circular pipes, it's a bit more homogenous geometry, so it's a sort of swells altogether.

00:38:12.208 --> 00:38:18.688
<v Andrea Lucherini>But when you have these sort of very sharp angles, then you might have, a sort of thermal bridge then heat can penetrate through that.

00:38:19.068 --> 00:38:21.688
<v Andrea Lucherini>So is, is such a complicated topic.

00:38:22.623 --> 00:38:22.742
<v Wojciech Węgrzyński>Hmm.

00:38:23.007 --> 00:38:26.367
<v Andrea Lucherini>try to solve one aspect and then you forgot another

00:38:27.023 --> 00:38:32.500
<v Wojciech Węgrzyński>However, The definition of failure is not, is also not very sharp in here.

00:38:32.500 --> 00:38:44.512
<v Wojciech Węgrzyński>Like I guess by experience you can have some of this fail, some of this not swell perfectly, and yet still achieve the expected performance, from the larger point of view.

00:38:44.512 --> 00:38:50.072
<v Wojciech Węgrzyński>That that's what I've been told in the laboratory, that you have like a certain amount of measurement points, you average them.

00:38:50.072 --> 00:39:01.291
<v Wojciech Węgrzyński>There's a criteria for some of them, You don't need, uh, the most perfect uniform action on all of the surfaces all at the same time to achieve the benefit of, of the fire protection, right?

00:39:01.291 --> 00:39:04.092
<v Wojciech Węgrzyński>This is how they're designing in minds, right?

00:39:04.128 --> 00:39:06.606
<v Andrea Lucherini>this the framework we have now.

00:39:06.637 --> 00:39:22.327
<v Andrea Lucherini>We have some strength, but also we have serious weaknesses because you know, still for if we apply interes coatings to protect a steel column, that would've, you know, free for exposure to a fire.

00:39:22.597 --> 00:39:24.186
<v Andrea Lucherini>Having a large scale experiment is.

00:39:24.585 --> 00:39:35.340
<v Andrea Lucherini>That must represent this scenario because in the end, for structural engineering purposes, you wanna keep the temperature of the steel low or below a certain critical temperature, whatever is defined.

00:39:35.788 --> 00:39:41.748
<v Andrea Lucherini>The important is also something that Piotr lightness in this, uh, episode is, are we.

00:39:41.748 --> 00:39:51.057
<v Andrea Lucherini>Aware that certain key parameters of the this framework can strongly affect the performance of these materials?

00:39:51.293 --> 00:40:02.201
<v Andrea Lucherini>What Piotr mentioned that at the beginning, in the first 10 minutes of the standard furnace test, anything can happen, and in that period of time is when the quoting

00:40:02.280 --> 00:40:02.710
<v Andrea>swell.

00:40:03.268 --> 00:40:08.967
<v Andrea Lucherini>For example, the quoting has been designed to have to be very reactive to a very fast thermal shock.

00:40:09.507 --> 00:40:15.014
<v Andrea Lucherini>The classic, very fast growing fire of a very fast growing fire or standard temperature time curve.

00:40:15.523 --> 00:40:17.204
<v Andrea Lucherini>So it works very well in that scenario.

00:40:17.434 --> 00:40:25.134
<v Andrea Lucherini>So maybe an international manufacturer would prefer to have a, you know, a very big push in the temperature at the beginning because the sort of activates.

00:40:25.657 --> 00:40:29.989
<v Andrea Lucherini>Foster the reactivity and the, the performance of this quoting.

00:40:30.469 --> 00:40:34.003
<v Andrea Lucherini>But then you know, that thermal boundary condition controls the whole

00:40:34.032 --> 00:40:34.472
<v Andrea>whole story.

00:40:34.637 --> 00:40:39.329
<v Wojciech Węgrzyński>I would say what makes the pain, the coating, uh, really work in fire.

00:40:39.626 --> 00:40:45.436
<v Wojciech Węgrzyński>I mean, once it swells, it's basically down to Forueir problem.

00:40:46.320 --> 00:40:47.570
<v Wojciech Węgrzyński>Heat transfer problem.

00:40:47.940 --> 00:40:52.800
<v Wojciech Węgrzyński>If it has this depth and this thermal conductivity, it'll achieve this performance.

00:40:52.800 --> 00:40:56.764
<v Wojciech Węgrzyński>It's simple physics if the, the thermal boundary condition is known.

00:40:57.293 --> 00:41:08.697
<v Wojciech Węgrzyński>So from 10th minute of the test, you basically, like, you could stop the test at that point because if you know the external temperature and basic, parameters of the perfectly swollen, coat.

00:41:09.152 --> 00:41:12.402
<v Wojciech Węgrzyński>It's a heat transfer problem, but what, what makes it or breaks it?

00:41:12.402 --> 00:41:16.358
<v Wojciech Węgrzyński>Like does this achieve this level of swelling in the first minutes?

00:41:16.382 --> 00:41:20.561
<v Wojciech Węgrzyński>was it capable of reaching this point where it's activated?

00:41:20.724 --> 00:41:29.817
<v Andrea Lucherini>The process of swelling takes time, and it's not something, particularly the more coating you put the thicker thickness, the longer it's gonna take.

00:41:30.206 --> 00:41:34.467
<v Andrea Lucherini>Then how long does it take when you start degrading the quoting and everything?

00:41:34.467 --> 00:41:37.016
<v Andrea Lucherini>That is something that depends the test by test.

00:41:37.175 --> 00:41:46.387
<v Andrea Lucherini>But for me is that since at the base of everything, the motivation of my research is that we assume that the scenario we're testing so fast, grow.

00:41:47.331 --> 00:41:48.351
<v Andrea Lucherini>Very high temperature.

00:41:48.351 --> 00:41:51.561
<v Andrea Lucherini>Fire is the most critical scenario for a

00:41:51.581 --> 00:41:52.112
<v Andrea>a structure,

00:41:52.422 --> 00:41:57.371
<v Andrea Lucherini>but is it the most critical scenario for the performance of an interm coating?

00:41:57.708 --> 00:41:58.548
<v Andrea Lucherini>That's another story.

00:41:58.842 --> 00:41:59.284
<v Wojciech Węgrzyński>Yeah,

00:41:59.545 --> 00:42:11.208
<v Andrea Lucherini>And uh, and as you know, as we discussed, chemical engineers, manufacturers there are smart enough to optimize their products for all the scenario that are required to be.

00:42:11.603 --> 00:42:13.858
<v Andrea Lucherini>So it's, it's not a viable anymore.

00:42:14.248 --> 00:42:18.588
<v Andrea Lucherini>They take, that the fire scenario is defined and then they have to play with all the rest.

00:42:18.829 --> 00:42:19.849
<v Andrea Lucherini>They can look at, you know,

00:42:19.878 --> 00:42:19.998
<v Andrea>know,

00:42:20.119 --> 00:42:22.478
<v Andrea Lucherini>char strength swelling

00:42:22.498 --> 00:42:22.898
<v Andrea>rate

00:42:23.291 --> 00:42:25.768
<v Andrea Lucherini>so it is, an extremely complicated topic and very

00:42:26.219 --> 00:42:27.298
<v Andrea>challenging to work with that

00:42:27.664 --> 00:42:29.184
<v Wojciech Węgrzyński>We're entering dangerous grounds.

00:42:29.184 --> 00:42:37.367
<v Wojciech Węgrzyński>I must stop you there . I like my knees like they are on shot , so Yeah.

00:42:37.547 --> 00:42:39.039
<v Wojciech Węgrzyński>But yeah, you, you are correct.

00:42:39.257 --> 00:42:46.429
<v Wojciech Węgrzyński>that's the battle we have like optimizing for test standard and not understanding the, performance in the, in the real building.

00:42:46.489 --> 00:42:58.056
<v Wojciech Węgrzyński>And there is nothing like standards are used to rank materials, to classify materials, to safely put materials on the market to assure that materials do have a, characteristics they claim to have.

00:42:58.646 --> 00:43:07.076
<v Wojciech Węgrzyński>It's, Very important part and, and something that worked very well for the last hundred years in, in providing safety for people, for masses.

00:43:07.259 --> 00:43:09.679
<v Wojciech Węgrzyński>The practical performance is something else.

00:43:09.679 --> 00:43:09.971
<v Wojciech Węgrzyński>Right.

00:43:09.985 --> 00:43:15.985
<v Andrea Lucherini>what I can say is that there is a bit of movement into these because with a big push of performance

00:43:16.130 --> 00:43:16.811
<v Andrea>based design,

00:43:17.050 --> 00:43:24.322
<v Andrea Lucherini>you know, the big assumption that usually fire safety engineers do is that they assume the performance of any intumescent coating in any other scenario.

00:43:24.922 --> 00:43:28.762
<v Andrea Lucherini>Which is the biggest assumption and most dangerous one for me.

00:43:29.152 --> 00:43:34.882
<v Andrea Lucherini>But now there is a bit of push in having a better and deeper understanding on how this material would behaves in different

00:43:35.072 --> 00:43:35.552
<v Andrea>conditions.

00:43:35.804 --> 00:43:37.568
<v Andrea Lucherini>And, uh, manufacturers are aware.

00:43:37.856 --> 00:43:53.365
<v Andrea Lucherini>also I think there should be something I've been trying to push with my research, try to push for more understanding and more conditions to understand if this quoting would behave in the dangerous situations or the for structure.

00:43:53.905 --> 00:44:00.596
<v Andrea Lucherini>And there are some manufacturer that are pushing for this change and are pushing for optimizing the product not only for one condition, but also

00:44:00.726 --> 00:44:01.126
<v Andrea>others.

00:44:01.394 --> 00:44:05.615
<v Andrea Lucherini>and they should get credit for that because they produce a product which is reliable.

00:44:05.856 --> 00:44:15.766
<v Andrea Lucherini>And since it's also intumescent coatings are expensive product for when you consider the different fire protection of various structures.

00:44:15.795 --> 00:44:22.365
<v Andrea Lucherini>So it's something that we should, uh, reward for people that trying to really understand if, uh, the product is

00:44:22.501 --> 00:44:23.021
<v Andrea>robust.

00:44:23.429 --> 00:44:26.099
<v Wojciech Węgrzyński>Absolutely Amen to that a hundred percent.

00:44:26.208 --> 00:44:26.648
<v Wojciech Węgrzyński>Okay.

00:44:26.648 --> 00:44:34.661
<v Wojciech Węgrzyński>So, we are, um, nearing the end of the episode, but I, I really wanted to ask you about, your future.

00:44:35.041 --> 00:44:35.601
<v Wojciech Węgrzyński>Plans.

00:44:35.782 --> 00:44:40.442
<v Wojciech Węgrzyński>But, uh, there, there's a question for insent pains that, that really connects to that very well.

00:44:40.512 --> 00:44:44.681
<v Wojciech Węgrzyński>Like to what extent we can protect, like timber with this type of solutions.

00:44:44.992 --> 00:44:46.641
<v Wojciech Węgrzyński>I saw that, uh, happening lately.

00:44:46.891 --> 00:44:48.322
<v Wojciech Węgrzyński>It was very interesting to me.

00:44:48.521 --> 00:44:51.514
<v Andrea Lucherini>I mean the, the concept is, Of course it can.

00:44:51.574 --> 00:45:13.893
<v Andrea Lucherini>We have to make sure, and we saw already application, it's not just concrete, it's not just a timber, but people have been also applying to machine coatings on concrete to improve, for example, to reduce the temperature within, uh, the rebars in concrete, for example, in, you know, historical buildings where you cannot change the section of an element, but you have to increase the fire protection.

00:45:14.193 --> 00:45:16.353
<v Andrea Lucherini>So you just apply a fin coating.

00:45:16.744 --> 00:45:21.853
<v Andrea Lucherini>You get like the class that you're required to improve but also to mitigate spalling.

00:45:21.873 --> 00:45:24.213
<v Andrea Lucherini>Sometimes we have been seeing like some research

00:45:24.333 --> 00:45:25.974
<v Andrea>that has been used for

00:45:26.139 --> 00:45:26.643
<v Andrea Lucherini>purpose.

00:45:27.023 --> 00:45:37.494
<v Andrea Lucherini>For Timba, the story is slightly different because uh I seen, and I worked also during my PhD on successful products international coatings applied on timber.

00:45:37.853 --> 00:45:40.153
<v Andrea Lucherini>And there are certain aspects to consider.

00:45:40.233 --> 00:45:43.313
<v Andrea Lucherini>First of all is the de between the two subs.

00:45:43.775 --> 00:45:55.130
<v Andrea Lucherini>So for some aspects, the coating might be much, I have a much better addition to the substrate because what happens, timber is hydroscopic so what happens absorbs, what is the surface?

00:45:55.460 --> 00:46:02.900
<v Andrea Lucherini>So some part of the quoting can be absorbed within the matrix of the timber, the surface, and also in, and therefore ensure

00:46:03.021 --> 00:46:04.141
<v Andrea>adhesion at the surface

00:46:04.213 --> 00:46:05.708
<v Wojciech Węgrzyński>Is that a good thing or a bad thing?

00:46:06.094 --> 00:46:06.724
<v Andrea>is a good.

00:46:07.159 --> 00:46:07.648
<v Wojciech Węgrzyński>Okay.

00:46:07.909 --> 00:46:09.108
<v Andrea Lucherini>Because it gets, and you have

00:46:09.188 --> 00:46:09.628
<v Andrea>have a better

00:46:09.909 --> 00:46:10.068
<v Andrea Lucherini>addition.

00:46:10.181 --> 00:46:27.335
<v Andrea Lucherini>Then the other aspects is The difference between critical temperatures, let's go like that in the two substrates, steel and timber, still the you know, you have critical temperatures above, you know, five, 600 degrees, but then the substrate stays more or less in the same way during, uh, the fire timber.

00:46:27.335 --> 00:46:27.936
<v Andrea Lucherini>What happens?

00:46:28.385 --> 00:46:33.445
<v Andrea Lucherini>Around, you know, 200, 300 degrees, the paralysis and charing process starts.

00:46:33.925 --> 00:46:41.695
<v Andrea Lucherini>So what you could have and what I mentioned earlier, into messing quotings, they typically, well for temperature for 300, 400 degrees.

00:46:41.798 --> 00:46:46.985
<v Andrea Lucherini>So what you see is that when the quoting starts welling, the surface of the team start

00:46:46.985 --> 00:46:48.106
<v Andrea>start charring as well.

00:46:48.815 --> 00:46:53.945
<v Andrea Lucherini>And this could be tricky for the addition not of the quoting on the timber, but the addition of the

00:46:53.945 --> 00:46:54.865
<v Andrea>of the char on the.

00:46:55.382 --> 00:47:04.021
<v Andrea Lucherini>But then again, if the coating starts welling, you have your Deion, what Mainly you have, you have, again, a bit endothermic process that mainly plateaus the surface.

00:47:04.291 --> 00:47:09.242
<v Andrea Lucherini>And what happens if you make sure that the coating is stays at the surface?

00:47:09.541 --> 00:47:14.581
<v Andrea Lucherini>You can mainly postpone the onset of swelling because you have like a delay.

00:47:14.791 --> 00:47:18.152
<v Andrea Lucherini>Plus if the quoting stays there, you have something that protects.

00:47:18.181 --> 00:47:21.512
<v Andrea Lucherini>So potentially the charter rate of the timber can be also.

00:47:22.536 --> 00:47:24.385
<v Wojciech Węgrzyński>That's, uh, that's so complicated.

00:47:24.686 --> 00:47:25.123
<v Andrea>amazing

00:47:25.226 --> 00:47:27.596
<v Andrea Lucherini>In theory sounds amazing, in theory.

00:47:27.596 --> 00:47:32.666
<v Andrea Lucherini>Sounds amazing In practice, we need to see experiments and tests better to that.

00:47:32.958 --> 00:47:37.385
<v Wojciech Węgrzyński>I find it like we're living in two different worlds in one  painting A Surface.

00:47:37.574 --> 00:47:39.905
<v Wojciech Węgrzyński>Such an easy task, and it's such an easy solution.

00:47:39.905 --> 00:47:44.510
<v Wojciech Węgrzyński>It just, Painted, like, do the primer, do the colting, do the external layer.

00:47:44.699 --> 00:47:45.550
<v Wojciech Węgrzyński>You're done.

00:47:45.639 --> 00:47:49.150
<v Wojciech Węgrzyński>Uh, the bucket says it's 60 minutes, you're very happy.

00:47:49.530 --> 00:47:58.510
<v Wojciech Węgrzyński>But the chemistry, the physics that goes inside the, the beautiful complication of a heat transfer that is suddenly changing in time and space at the same time.

00:47:58.925 --> 00:47:59.512
<v Andrea>mm-hmm.

00:47:59.688 --> 00:48:08.927
<v Wojciech Węgrzyński>I understand why this, uh, subject was so attractive to you because it's such a complicated manner and, uh, very, very interesting one.

00:48:09.246 --> 00:48:23.163
<v Andrea Lucherini>Just last thing I wanted to mention is that, what I try to do during my PhD, during my research is that to understand what are the fundamental factor that affect these, the behavior, these materials, because only in that way we can design

00:48:23.784 --> 00:48:24.394
<v Andrea>a test,

00:48:24.505 --> 00:48:32.135
<v Andrea Lucherini>uh, no experiment, whatever you wanna call it, that allows us to understand if the product will do the

00:48:32.155 --> 00:48:32.635
<v Andrea>the purpose.

00:48:33.050 --> 00:48:34.760
<v Andrea Lucherini>That what we have to, and we don't know at the

00:48:34.965 --> 00:48:35.166
<v Andrea>the moment.

00:48:35.186 --> 00:48:36.039
<v Andrea>Unfortunately,

00:48:36.077 --> 00:48:37.307
<v Andrea Lucherini>we spend a lot of money,

00:48:37.382 --> 00:48:38.563
<v Andrea>but, uh, we don't know

00:48:38.628 --> 00:48:40.038
<v Wojciech Węgrzyński>Well, we know a bit more.

00:48:40.038 --> 00:48:43.277
<v Wojciech Węgrzyński>You've successfully, uh, made modeling attempts.

00:48:43.277 --> 00:48:45.557
<v Wojciech Węgrzyński>You've described many of the phenomena in there.

00:48:45.557 --> 00:48:50.478
<v Wojciech Węgrzyński>So certainly thanks to your, And they, we are much richer in knowledge in this regard.

00:48:51.188 --> 00:48:57.277
<v Wojciech Węgrzyński>I will definitely link all I found, uh, with your name on it about inter pains in the show notes.

00:48:58.407 --> 00:48:58.568
<v Andrea Lucherini>things.

00:48:58.637 --> 00:49:00.217
<v Wojciech Węgrzyński>And, uh, yeah.

00:49:00.217 --> 00:49:01.938
<v Wojciech Węgrzyński>Andrea, thank, thank you very much.

00:49:02.027 --> 00:49:03.057
<v Wojciech Węgrzyński>Uh, brilliant.

00:49:03.148 --> 00:49:06.460
<v Wojciech Węgrzyński>Ya a scientist, developing So quickly.

00:49:07.300 --> 00:49:08.630
<v Wojciech Węgrzyński>Watch this space, guys.

00:49:08.630 --> 00:49:09.731
<v Wojciech Węgrzyński>uh, this space is good.

00:49:09.960 --> 00:49:14.335
<v Wojciech Węgrzyński>It's interesting to see, see you grow and see your, uh, future findings.

00:49:14.664 --> 00:49:18.201
<v Andrea Lucherini>Thank you very much Wojciech was my pleasure to be here particularly.

00:49:18.891 --> 00:49:27.568
<v Andrea Lucherini>After the big names that, uh, I've been listening and, that I've been ad admiring and study from over the last, uh, you know, 10 years of, uh, fire safety engineering.

00:49:27.572 --> 00:49:27.898
<v Andrea Lucherini>So

00:49:28.057 --> 00:49:28.648
<v Andrea>my pleasure.

00:49:28.873 --> 00:49:30.815
<v Wojciech Węgrzyński>Thank you very much and, and see you around.

00:49:30.815 --> 00:49:31.456
<v Wojciech Węgrzyński>Cheers, man.

00:49:31.690 --> 00:49:32.081
<v Andrea>Cheers.

00:49:33.525 --> 00:49:33.945
<v Wojciech Wegrzynski>And that's it.

00:49:33.974 --> 00:49:34.784
<v Wojciech Wegrzynski>Thank you for listening.

00:49:35.144 --> 00:49:36.735
<v Wojciech Wegrzynski>Hope you've enjoyed this conversation.

00:49:36.764 --> 00:49:40.813
<v Wojciech Wegrzynski>There are things that I wanted to cover, but we haven't had the chance to touch them.

00:49:40.813 --> 00:49:41.425
<v Wojciech Wegrzynski>One being modeling.

00:49:41.585 --> 00:49:41.945
<v Wojciech Wegrzynski>To muslin.

00:49:41.945 --> 00:49:45.525
<v Wojciech Wegrzynski>Coatings says very interesting subject that Andrea has actually done in his PhD.

00:49:46.175 --> 00:49:49.505
<v Wojciech Wegrzynski>It's it's lingered in the papers on the shownotes of the episode.

00:49:49.505 --> 00:49:50.376
<v Wojciech Wegrzynski>It wants to read about it.

00:49:50.826 --> 00:49:53.525
<v Wojciech Wegrzynski>But it's something definitely that could be covered on the podcast episode.

00:49:53.965 --> 00:49:55.583
<v Wojciech Wegrzynski>So maybe a topic for a future ads.

00:49:56.063 --> 00:49:59.422
<v Wojciech Wegrzynski>One thing we didn't touch is debunking myths of.

00:49:59.432 --> 00:50:02.163
<v Wojciech Wegrzynski>Some magical pains that are on the market.

00:50:02.538 --> 00:50:05.057
<v Wojciech Wegrzynski>Actually that call is for a podcast episode on its own as well.

00:50:05.731 --> 00:50:08.862
<v Wojciech Wegrzynski>On the way, precisely these magical beans that withstand.

00:50:09.541 --> 00:50:10.362
<v Wojciech Wegrzynski>The little blowers.

00:50:11.101 --> 00:50:11.862
<v Wojciech Wegrzynski>Like heroes.

00:50:12.126 --> 00:50:13.476
<v Wojciech Wegrzynski>Do those really provide you?

00:50:13.615 --> 00:50:15.775
<v Wojciech Wegrzynski>Good protection against through the fires in the world.

00:50:16.068 --> 00:50:16.278
<v Wojciech Wegrzynski>Wow.

00:50:16.668 --> 00:50:20.239
<v Wojciech Wegrzynski>Hopefully that will be covered one day and I'm very.

00:50:20.838 --> 00:50:26.989
<v Wojciech Wegrzynski>Maybe, maybe for some sort of celebrate every episode, that would be a topic I would enjoy demolishing on.

00:50:27.028 --> 00:50:29.398
<v Wojciech Wegrzynski>So Certainly something for the future.

00:50:30.028 --> 00:50:34.289
<v Wojciech Wegrzynski>Anyway, thank you, Andrea, for coming through the forest and show, it was a pleasure to have you.

00:50:34.289 --> 00:50:36.778
<v Wojciech Wegrzynski>Thank you all for listening to this podcast.

00:50:37.126 --> 00:50:44.025
<v Wojciech Wegrzynski>If you have something to share about intimacy and coatings, or if you want me to cover some other aspects of the subject brought in here.

00:50:44.385 --> 00:50:47.085
<v Wojciech Wegrzynski>Or maybe bring more fire safety engineering.

00:50:47.686 --> 00:50:51.735
<v Wojciech Wegrzynski>In terms of solutions applied to, to provide safety in buildings.

00:50:51.735 --> 00:50:54.349
<v Wojciech Wegrzynski>Let me know in the comments, So I know.

00:50:54.349 --> 00:50:56.929
<v Wojciech Wegrzynski>Well, Daya topics excites you most and looking at.

00:50:57.349 --> 00:50:58.579
<v Wojciech Wegrzynski>Uh, just the raw numbers.

00:50:58.608 --> 00:51:02.119
<v Wojciech Wegrzynski>It's not always the best indicator of what's being popular in here.

00:51:02.208 --> 00:51:04.579
<v Wojciech Wegrzynski>However, I think you may enjoy.

00:51:05.088 --> 00:51:16.556
<v Wojciech Wegrzynski>Those that cover technologies because that's something we always And not only philosophical or very Ivory tower and topics, but down to earth engineering and why stuff works.

00:51:16.556 --> 00:51:19.286
<v Wojciech Wegrzynski>And when it stops, I think that's fundamental to understand.

00:51:19.675 --> 00:51:20.996
<v Wojciech Wegrzynski>As a fire safety engineer.

00:51:21.356 --> 00:51:23.876
<v Wojciech Wegrzynski>So thank you for being here and next week.

00:51:23.876 --> 00:51:26.791
<v Wojciech Wegrzynski>Well, actually next week, there's going to super exciting sprint.

00:51:27.552 --> 00:51:34.481
<v Wojciech Wegrzynski>Uh, topic notes, very practical today, but absolutely exciting for any fire safety engineer.

00:51:34.902 --> 00:51:35.802
<v Wojciech Wegrzynski>I'm not going to spoil you.

00:51:35.802 --> 00:51:36.942
<v Wojciech Wegrzynski>You're going to see next Wednesday.

00:51:37.271 --> 00:51:37.492
<v Wojciech Wegrzynski>So.

00:51:37.692 --> 00:51:39.012
<v Wojciech Wegrzynski>I See there by

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